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Published online by Cambridge University Press: 27 February 2023
Coalescence of binary neutron stars gives rise to kilonova, thermal emission powered by radioactive decays of newly synthesized r-process nuclei. Observational properties of kilonova are largely affected by bound-bound opacities of r-process elements. It is, thus, important to understand atomic properties of heavy elements to link the observed signals with nucleosynthesis of neutron star mergers. In this paper, we introduce the latest status of kilonova modeling by focusing on the aspects of atomic physics. We perform systematic atomic structure calculations of r-process elements to understand element-to-element variation in the opacities. We demonstrate that the properties of the atomic structure of heavy elements are imprinted in the opacities of the neutron star merger ejecta and consequently in the kilonova light curves and spectra. Using this latest opacity dataset, we briefly discuss implications for GW170817, expected diversity of kilonova emission, and prospects for element identification in kilonova spectra.