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Using noble gas ratios to determine the origin of ground ice

Published online by Cambridge University Press:  20 January 2017

Nicholas Utting ,
Bernard Lauriol ,
Denis Lacelle  and
Ian Clark
Nicholas Utting*
Affiliation:
Department of Earth Science, University of Ottawa, 25 Templeton Street, Ottawa, ON K2N 1N5, Canada Faculty of Science, Concordia University of Edmonton, 7128 Ada Boulevard, Edmonton AB T5B 4E4, Canada
Bernard Lauriol
Affiliation:
Department of Geography, University of Ottawa, 60 University, Ottawa, ON K1N 6N5, Canada
Denis Lacelle
Affiliation:
Department of Geography, University of Ottawa, 60 University, Ottawa, ON K1N 6N5, Canada
Ian Clark
Affiliation:
Department of Earth Science, University of Ottawa, 25 Templeton Street, Ottawa, ON K2N 1N5, Canada
*
⁎Corresponding author at: Faculty of Science, Concordia University of Edmonton, 7128 Ada Boulevard, Edmonton Alberta T5B 4E4, Canada. E-mail address:Nicholas.utting@gmail.com (N. Utting).
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Abstract

Argon, krypton and xenon have different solubilities in water, meaning their ratios in water are different from those in atmospheric air. This characteristic is used in a novel method to distinguish between ice bodies which originate from the compaction of snow (i.e. buried snow banks, glacial ice) vs. ice which forms from the freezing of groundwater (i.e. pingo ice). Ice which forms from the compaction of snow has gas ratios similar to atmospheric air, while ice which forms from the freezing of liquid water is expected to have gas ratios similar to air-equilibrated water. This analysis has been conducted using a spike dilution noble gas line with gas extraction conducted on-line. Samples were mixed with an aliquot of rare noble gases while being melted, then extracted gases are purified and cryogenically separated. Samples have been analysed from glacial ice, buried snow bank ice, intrusive ice, wedge ice, cave ice and two unknown ice bodies. Ice bodies which have formed from different processes have different gas ratios relative to their formation processes.

Keywords

Noble gasGlacier iceMassive ground icePermafrostCanadian Arctic
Type
Original Articles
Information
Quaternary Research , Volume 85 , Issue 1 , January 2016 , pp. 177 - 184
Copyright
University of Washington

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References

Ahn, J., Headly, M., Wahlen, M., Brook, E., Mayewski, P., and Taylor, K. (2008). CO2 diffusion in polar ice: observations from naturally formed CO2 spikes in the Siple Dome (Antarctica) ice core. Journal of Glaciology 54, 685–695.Google Scholar
Andrews, J.N. (1992). Mechanisms for noble gas dissolution by groundwaters. Isotopes of Noble Gases as Tracers in Environmental Studies International Atomic Energy Agency, Vienna.87–109.Google Scholar
Astakhov, V., and Isayeva, L. (1988). The ‘Ice Hill’: an example of ‘retarded deglaciation’ in Siberia. Quaternary Science Reviews 7, 29–40.CrossRefGoogle Scholar
Barnola, J.M., Pimienta, P., Raynaud, D., and Korotkevich, Y.S. (1991). CO2 climate relationship as deducted from the Vostok ice core: a reexamination based on new measurements and on reevaluation of the air dating. Tellus 43, 83–90.Google Scholar
Burn, C., and Lewkowicz, A. (1990). Retrogressive thaw slumps. The Canadian Geographer 34, 273–276.CrossRefGoogle Scholar
Cardyn, R., Clark, I.D., Lacelle, D., Lauriol, B., Zdanowicz, C., and Camels, F. (2007). Molar gas ratios of air entrapped in ice: a new tool to determine the origin of relict massive ground ice bodies in permafrost. Quaternary Research 68, 239–248.CrossRefGoogle Scholar
Clark, I.D., Henderson, L., Chappelaz, J., Fisher, D., Koerner, R., Worthy, D.E.J., Kotzer, T., Norman, A.L., and Barnola, J.M. (2007). CO2 isotopes as tracers of firn air diffusion and age in an Arctic ice cap with summer melting, Devon Island, Canada. Journal of Geophysical Research 112, 1–13.Google Scholar
Clever, H.L. (1979). IUPAC Solubilities: Krypton, Xenon, Radon. Pergamon Press, Oxford.Google Scholar
Craig, H. (1961). Isotopic variations in meteoric waters. Science 133, 1833–1834.CrossRefGoogle ScholarPubMed
Craig, H., Horibe, Y., and Sowers, T. (1988). Gravitational separation of gases and isotopes in polar ice caps. Science 242, 1675–1678.Google Scholar
Duk-Rodkin, A. (1999). Glacial limits map of Yukon Territory (Open File 3694). Geological Survey of Canada, Google Scholar
Duk-Rodkin, A., and Hughes, O.L. (1992). Fort McPherson — Bell River Surficial Geology Map 1742A. Geological Survey of Canada, Google Scholar
Environment Canada, (2010). National Climate Data and Information Archive Google Scholar
Fisher, D., Koerner, R., and Reeh, N. (1995). Holocene climatic records from Agassiz Ice Cap, Ellesmere Island, NWT, Canada. The Holocene 5, (195-24)Google Scholar
Fisher, D., Koerner, R., Bourgeois, J., Zielinski, G., Wake, C., Hammer, C., Clausen, H., Gundestrup, N., Johnson, S., Gota-Azuma, K., Hondoh, T., Blake, E., and Gerasinoff, M. (1998). Penny Ice Cap Cores, Baffin Island, Canada, and the Wisconsinan Foxe Dome Connection: two states of Hudson Bay Ice Cover. Science 279, 692–695.Google Scholar
French, H. (1996). The Periglacial Environment. Addison Wesley Longman Limited, Canada.Google Scholar
Froese, D., Westgate, J., Reyes, A., Enkin, R., and Preece, S. (2008). Ancient permafrost and a future, warmer arctic. Science 321, 1648 CrossRefGoogle Scholar
Grew, K.E., and Ibbs, T.L. (1952). Thermal Diffusion Of Gases. Cambridge University Press, New York.Google Scholar
Harry, D., French, H., and Pollard, W. (1988). Massive ground ice and ice-cored terrain near Sabine Point, Yukon coastal Plain. Canadian Journal of Earth Science 25, 1846–1856.Google Scholar
Headly, M., Ahn, J., and Severinghaus, J. (2005). Using Kr/Ar and Xe/Ar ratios to identify melt layers in ice cores. American Geophysical Union: Fall Meeting 2005 American Geophysical Union, San Francisco.Google Scholar
Huber, C., Beyerle, U., Leuenberger, M., Schwander, J., Kipfer, R., Spahni, R., Severinghaus, J.P., and Weiler, K. (2006). Evidence for molecular size dependent gas fractionation in firn air derived from noble gases, oxygen, and nitrogen measurements. Earth and Planetary Science Letters 243, 61–73.Google Scholar
Hughes, O. (1972). Surficial Geology Of The Northern Yukon Territory And Northwestern District Of The Mackenzie, Northwest Territories. Geological Survey of Canada, Google Scholar
Jouzel, J., and Souchez, R. (1982). Melting–refreezing at the glacier sole and isotopic composition of the ice. Journal of Glaciology 28, 35–41.Google Scholar
Kaplyanskaya, F., and Tarnogradskiy, V. (1986). Remnants of the Pleistocene ice sheets in the permafrost zone as an object for paleoglaciological research. Polar Geography and Geology 10, 65–72.Google Scholar
Kennedy, K., Froese, D., Zazula, G., and Lauriol, B. (2010). Last Glacial Maximum age for the northwest Laurentide maximum from the Eagle River spillway and delta complex, northern Yukon. Quaternary Science Reviews 29, 1288–1300.Google Scholar
Killawee, J., Fairchild, J., Tison, J., Janssens, L., and Lorrain, R. (1998). Segregation of solutes and gases in experimental freezing of dilute solutions: implications for natural glacial systems. Geochimica et Cosmochimica Acta 62, 3637–3655.Google Scholar
Kipfer, R., Aeschbach-Hertig, W., Peeters, F., and Stute, M. (2002). Noble gases in lakes and groundwaters.Porcelli, D., Ballentine, C.J., Wieler, R. Noble Gases in Geochemistry and Cosmochemistry. Mineralogical Society of America, Washington D.C..642 Google Scholar
Klassen, R., and Shilts, W. (1987). Bylot Island, Eastern Canada Arctic XII INQUA Congress Field Excursion A.I. Guidebook. National Research Council of Canada, Ottawa.Google Scholar
Lacelle, D., and Clark, I.D. (2011). On the δ18O, δD and D-excess relations in meteoric precipitation and during equilibrium freezing: theoretical approach and field examples. Permafrost and Periglacial Processes 22, 13–25.Google Scholar
Lacelle, D., L., B., Clark, I.D., Cardyn, R., and Zdanowicz, C. (2007). Nature and origin of a Pleistocene-age massive ground-ice body exposed in the Chapman Lake moraine complex, central Yukon Territory. Quaternary Research 68, 249–260.Google Scholar
Lacelle, D., St-Jean, M., Lauriol, B., Clark, I.D., Lewkowicz, A., Froese, D., Kuehn, S., and Zazula, G. (2009). Burial and preservation of a 30,000 year old perennial snowbank in Red Creek valley, Ogilvie Mountains, central Yukon, Canada. Quaternary Research Reviews 28, 3401–3413.Google Scholar
Lacelle, D., Lauriol, B., Zazula, G., Ghaled, B., Utting, N., and Clark, I.D. (2013). Timing of advance and basal conditions of the Laurentide Ice Sheet during the last glacial maximum in the Richardson Mountains, NWT. Quaternary Research 80, 274–283.CrossRefGoogle Scholar
Lacelle, D., Radtke, K., Clark, I.D., Fisher, D., Lauriol, B., Utting, N., and Whyte, L.G. (2011). Geomicrobiology and occluded O2-CO2-Ar analyses provide evidence of microbial respiration in ancient terrestrial ground ice bodies.. Earth and Planetary Science Letters 306, 46–54.Google Scholar
Lauriol, B., Carrier, L., and Thibaudeau, P. (1988). Topoclimatic zones and ice dynamics in the caves of the northern Yukon, Canada. Arctic 41, 215–220.CrossRefGoogle Scholar
Lauriol, B., Ford, D., Cinq-Mars, J., and Morris, W. (1997). The chronology of speleothem deposition in northern Yukon and its relationships to permafrost. Canadian Journal of Earth Sciences 34, 902–911.CrossRefGoogle Scholar
Lauriol, B., Lacelle, D., St-Jean, M., Clark, I.D., and Zazula, G. (2010). Late Quaternary paleoenvironments and growth of intrusive ice revealved by a thaw slump in the Eagle River Valley, northern Yukon, Canada. Canadian Journal of Earth Sciences 47, 941–955.Google Scholar
Lewkowicz, A. (1987). Nature and importance of thermokarst processes, Sandhills moraine, Banks Island, Canada. Geografiska Annaler 67A, 1077–1085.Google Scholar
Mackay, J. (1966). Segregated epigenetic ice and slumps in permafrost, Mackenzie Delta area, N.W.T.. Geographical Bulletin 8, 59–80.Google Scholar
Mackay, J. (1971). The origin of massive icy beds in permafrost, western Arctic coast, Canada. Canadian Journal of Earth Sciences 8, 397–422.Google Scholar
Mackay, J., and Dallimore, R. (1992). Massive ice of the Tuktoyaktuk area, western Arctic coast, Canada. Canadian Journal of Earth Sciences 29, 1235–1249.Google Scholar
Malone, J.L., Castro, M.C., Hall, C.M., Doran, P.T., Kenig, F., and McKay, C.P. (2010). New insights into the origin and evolution of Lake Vida, McMurdo Dry Valleys, Antarctica — a noble gas study in ice and brines. Earth and Planetary Science Letters 289, 112–122.Google Scholar
Murton, J., Whiteman, C., Waller, R., Pollard, W., Clark, I., and Dallimore, S. (2005). Basal ice facies and supraglacial melt-out till of the Laurentide Ice Sheet, Tuktoyaktuk Coastlands, western Arctic Canada. Quaternary Science Reviews 24, 681–708.Google Scholar
Norris, D.K. (1974). Geology Fort McPherson (1520A). Geological Survey of Canada, Google Scholar
Norris, D.K. (1985). Geology Of The Northern Yukon And Northwestern District Of Mackenzie (1581a). Geological Survey of Canada, Google Scholar
NRCan, (2003). The Atlas of Canada: Permafrost, Natural Resources Canada, Government of Canada.Google Scholar
Orsi, A.J., Fegyveresi, J., Kawamura, K., Headly, M.A., Alley, R.B., and Severinghaus, J.P. (2015). Differentiating bubble-free layers from melt layers in ice cores using noble gases. Journal of Glaciology 61, 585–594.10.3189/2015JoG14J237Google Scholar
Paterson, W. (1994). The Physics of Glaciers 3rd Edition. Pergamon, Oxford.Google Scholar
Pollard, W., and French, H. (1985). The internal structure and ice crystallography of seasonal frost mounds. Journal of Glaciology 31, 157–162.Google Scholar
Poole, J.C., McNeill, G.W., Langman, S.R., and Dennis, F. (1997). Analysis of noble gases in water using a quadrapole mass spectrometer in static mode. Applied Geochemistry 12, 707–714.CrossRefGoogle Scholar
Price, P., and Sowers, T. (2004). Temperature dependence of metabolic rates for microbial growth, maintenance, and survival. Proceedings of the National Academy of Sciences of the United States of America 101, 4631–4636.Google Scholar
Rampton, V. (1982). Quaternary geology of the Yukon Coastal Plain Geological Survey of Canada.Google Scholar
Schumskii, P. (1964). Principles of Structural Glaciology. Dover Publications, New York.Google Scholar
Schwander, J. (1989). The transformation of snow to ice and the occlusion of gases.Oeschger, H., Langway, C.C. The Environmental Record In Glaciers And Ice Sheets. John Wiley, New York.53–67.Google Scholar
Severinghaus, J., and Battle, M. (2006). Fractionation of gases in polar ice during bubble close-off: new constraints from firn air Ne, Kr and Xe observations. Earth and Planetary Science Letters 244, 474–500.Google Scholar
Severinghaus, J., Grachev, A., Luz, B., and Caillon, N. (2003). A method for precise measurement of argon 40/36 and krypton/argon ratios in trapped air in polar ice with applications to past firn thickness and abrupt climate change in Greenland and at Siple Dome, Antarctica. Geochimica et Cosmochimica Acta 67, 325–343.Google Scholar
Sowers, T. (2001). N2O record spanning the penultimate deglaciation from the Vostok ice core. Journal of Geophysical Research, D: Atmospheres 106, 31903–31914.Google Scholar
St-Jean, M., Lauriol, B., Clark, I., Lacelle, D., and Zdanowicz, C. (2011). Investigation of ice-wedge infilling processes using stable oxygen and hydrogen isotopes, crystallography and occluded gases (O2, N2, Ar). Permafrost and Periglacial Processes 22, 49–64.CrossRefGoogle Scholar
St-Onge, D., and McMartin, I. (1999). The Bluenose Lake Moraine, a moraine with a glacier ice core. Géographie Physique et Quaternaire 53, 287–295.Google Scholar
Top, Z., Martin, S., and Becker, P. (1988). A laboratory study of dissolved noble gas anomaly due to ice formation. Geophysical Research Letters 15, 8 796–799.Google Scholar
Tung, H., Bramall, N., and Price, P. (2005). Microbial origin of excess methane in glacial ice and implications for life on Mars. Proceedings of the National Academy of Sciences of the United States of America 102, 18292–18296.Google Scholar
Waller, R., Murton, J., and Knight, P. (2009). Basal glacier ice and massive ground ice: different scientists, same science?. Geological Society Special Publication: Glaciology & Permafrost 320, 57–69.CrossRefGoogle Scholar
Weiss, R. (1970). The solubility of nitrogen, oxygen and argon in water and seawater. Deep-Sea Research 17, 721–735.Google Scholar
Weiss, R. (1978). Solubility of krypton in water and sea water. Journal of Chemical and Engineering Data 23, 69–72.Google Scholar
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