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Contamination on AMS Sample Targets by Modern Carbon is Inevitable

Published online by Cambridge University Press:  17 February 2016

Dipayan Paul ,
Henk A Been ,
Anita Th Aerts-Bijma  and
Harro A J Meijer
Dipayan Paul
Affiliation:
Centre for Isotope Research (CIO), Energy and Sustainability Research Institute Groningen (ESRIG), University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.
Henk A Been
Affiliation:
Centre for Isotope Research (CIO), Energy and Sustainability Research Institute Groningen (ESRIG), University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.
Anita Th Aerts-Bijma
Affiliation:
Centre for Isotope Research (CIO), Energy and Sustainability Research Institute Groningen (ESRIG), University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.
Harro A J Meijer*
Affiliation:
Centre for Isotope Research (CIO), Energy and Sustainability Research Institute Groningen (ESRIG), University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.
*
*Corresponding author. Email: h.a.j.meijer@rug.nl.
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Abstract

Accelerator mass spectrometry (AMS) measurements of the radiocarbon content in very old samples are often challenging and carry large relative uncertainties due to possible contaminations acquired during the preparation and storage steps. In case of such old samples, the natural surrounding levels of 14C from gases in the atmosphere, which may well be the source of contamination among others, are 2–3 orders of magnitude higher than the samples themselves. Hence, serious efforts are taken during the preparation steps to have the samples pristine until measurements are performed. As samples often have to be temporarily stored until AMS measurements can be performed, storage conditions also become extremely crucial. Here we describe an assessment of this process of contamination in background AMS samples. Samples, both as pressed graphite (on AMS targets) and graphite powder, were stored in various storage conditions (CO2-spiked air) to investigate the extent of contamination. The experiments clearly show that the pressed targets are more vulnerable to contamination than the unpressed graphite. Experiments conducted with enriched CO2-spiked laboratory air also reveal that the contaminating carbon is not only limited to the target surface but also penetrates into the matrix. A combination of measurements on understanding the chemical nature of the graphitization product, combined with long-available knowledge on “adventitious carbon” from the surface science community, brought us to the conclusion that contamination is to a certain extent inevitable. However, it can be minimized, and should be dealt with by sputter-cleaning the samples individually before the actual measurement.

Keywords

radiocarbonaccelerator mass spectrometrycontaminationadventitious carbon
Type
Research Article
Information
Radiocarbon , Volume 58 , Issue 2 , June 2016 , pp. 407 - 418
Copyright
© 2016 by the Arizona Board of Regents on behalf of the University of Arizona 

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References

REFERENCES

Aerts-Bijma, AT, Meijer, HAJ, van der Plicht, J. 1997. AMS sample handling in Groningen. Nuclear Instruments and Methods in Physics Research B 123(1–4):221–225.CrossRefGoogle Scholar
Barr, TL, Seal, S. 1995. Nature of the use of adventitious carbon as a binding-energy standard. Journal of Vacuum Science & Technology a-Vacuum Surfaces and Films 13(3):1239–1246.CrossRefGoogle Scholar
Brown, TA, Southon, JR. 1997. Corrections for contamination background in AMS 14C measurements. Nuclear Instruments and Methods in Physics Research B 123(1–4):208–213.CrossRefGoogle Scholar
de Rooij, M, van der Plicht, J, Meijer, HAJ. 2010. Porous iron pellets for AMS 14C analysis of small samples down to ultra-microscale size (10–25 μgC). Nuclear Instruments and Methods in Physics Research B 268(7–8):947–951.CrossRefGoogle Scholar
Downs, RT, Hall-Wallace, M. 2003. The American Mineralogist Crystal Structure Database. American Mineralogist 88:247–250.Google Scholar
Kern, W, Puotinen, DA. 1970. Cleaning solutions based on hydrogen peroxide for use in silicon semiconductor technology. RCA Review 31(2):187–205.Google Scholar
Kim, S-H, Kelly, PB, Ortalan, V, Browning, ND, Clifford, AJ. 2010. Quality of graphite target for biological/biomedical/environmental applications of 14C-accelerator mass spectrometry. Analytical Chemistry 82(6):2243–2252.CrossRefGoogle ScholarPubMed
Kirner, DL, Taylor, RE, Southon, JR. 1995. Reduction in backgrounds of microsamples for AMS 14C dating. Radiocarbon 37(2):697–704.CrossRefGoogle Scholar
Kock, A, De Bokx, PK, Boellaard, E, Klop, W, Geus, JW. 1985. The formation of filamentous carbon on iron and nickel catalysts: II. Mechanism. Journal of Catalysis 96(2):468–480.CrossRefGoogle Scholar
Mangolini, F, McClimon, JB, Rose, F, Carpick, RW. 2014. Accounting for nanometer-thick adventitious carbon contamination in X-ray absorption spectra of carbon-based materials. Analytical Chemistry 86(24):12,258–65.CrossRefGoogle ScholarPubMed
Miller, DJ, Biesinger, MC, McIntyre, NS. 2002. Interactions of CO2 and CO at fractional atmosphere pressures with iron and iron oxide surfaces: one possible mechanism for surface contamination? Surface and Interface Analysis 33(4):299–305.CrossRefGoogle Scholar
Nemec, M, Wacker, L, Gaggeler, H. 2010. Optimization of the graphitization process at AGE-1. Radiocarbon 52(3):1380–1393.CrossRefGoogle Scholar
Paul, D, Meijer, HAJ. 2015. IntraCavity OptoGalvanic Spectroscopy not suitable for ambient level radiocarbon detection. Analytical Chemistry 87(17):9025–9032.CrossRefGoogle Scholar
Piao, H, McIntyre, NS. 2002. Adventitious carbon growth on aluminium and gold-aluminium alloy surfaces. Surface and Interface Analysis 33(7):591–594.CrossRefGoogle Scholar
Ruff, M, Szidat, S, Gaggeler, HW, Suter, M, Synal, H-A, Wacker, L. 2010. Gaseous radiocarbon measurements of small samples. Nuclear Instruments and Methods in Physics Research B 268(7–8):790–794.CrossRefGoogle Scholar
Santos, GM, Southon, JR, Griffin, S, Beaupre, SR, Druffel, ERM. 2007. Ultra small-mass AMS 14C sample preparation and analyses at KCCAMS/UCI Facility. Nuclear Instruments and Methods in Physics Research B 259(1):293–302.CrossRefGoogle Scholar