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Determination of Bio Content in Polymers used in the Packaging of food Products

Published online by Cambridge University Press:  05 December 2019

C Telloli Open the ORCID record for C Telloli [Opens in a new window] ,
A Rizzo Open the ORCID record for A Rizzo [Opens in a new window] ,
C Canducci  and
P Bartolomei
C Telloli*
Affiliation:
ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development Fusion and Technology for Nuclear Safety and Security Department Nuclear Safety, Security and Sustainability Division - via Martiri di Monte Sole 4, 40129, Bologna, Italy
A Rizzo
Affiliation:
ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development Fusion and Technology for Nuclear Safety and Security Department Nuclear Safety, Security and Sustainability Division - via Martiri di Monte Sole 4, 40129, Bologna, Italy
C Canducci
Affiliation:
U-Series srl - via Ferrarese 131, 40128, Bologna, Italy
P Bartolomei
Affiliation:
ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development Fusion and Technology for Nuclear Safety and Security Department Nuclear Safety, Security and Sustainability Division - via Martiri di Monte Sole 4, 40129, Bologna, Italy
*
*Corresponding author. Email: chiara.telloli@enea.it
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Abstract

The ENEA Radiocarbon Laboratory (Bologna, Italy) has been operating since 1985; it is the oldest among such laboratories operating in Italy and has been active for about 30 years in the field of dating of different types of samples with the radiocarbon (14C) liquid scintillation method. This study shows the detailed procedure for radiocarbon analysis on bioplastic materials by means of the synthesis of benzene, which includes CO2 production and purification, synthesis of acetylene, and synthesis and collection of benzene. The changes made to the original design of the synthesis procedures and the operational parameters adopted to optimize the combustion of the plastic materials are described. The measurement of 14C activity was performed using the liquid scintillation counting technique by a QuantulusTM 1220 low-background counter. The δ13C content was compared with the percentage of 14C concentration for the characterization of the bio content in plastic used in the food packaging.

Keywords

bioplasticfood packagingradiocarbon
Type
Conference Paper
Information
Radiocarbon , Volume 61 , Issue 6: Radiocarbon 2018 Conference Proceedings Trondheim, Norway, June 17–22, 2018 Part 2 of 2 , December 2019 , pp. 1973 - 1981
Copyright
© 2019 by the Arizona Board of Regents on behalf of the University of Arizona 

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Footnotes

Selected Papers from the 23rd International Radiocarbon Conference, Trondheim, Norway, 17–22 June, 2018

References

REFERENCES

Andjelkovic, DD, Culkin, DA, Loza, R. 2009. Unsaturated polyester resins derived from renewable resources. In: Composites & Polycon. Tampa, FL: American Composite Manufacturers Association. p. 1–9.Google Scholar
ASTM D6866-18. 2018. Standard test methods for determining the biobased content of solid, liquid, and gaseous samples using radiocarbon analysis. ASTM International, West Conshohocken, PA.Google Scholar
Berto, D, Rampazzo, F, Gion, C, Noventa, S, Ronchi, F, Traldi, U, Giorgi, G, Cicero, AM, Giovanardi, O. 2017. Preliminary study to characterize plastic polymers using elemental analyser/isotope ratio mass spectrometry (EA/IRMS). Chemosphere 176:47–56.CrossRefGoogle Scholar
Calcagnile, L, Quarta, G, D’Elia, M, Ciceri, G, Martinotti, V. 2011. Radiocarbon AMS determination of the biogenic component in CO2 emitted from waste incineration. Nuclear Instruments and Methods in Physics Research B 269:3158–3162.CrossRefGoogle Scholar
Dijs, IJ, van der Windt, E, Kaihola, L, van der Borg, K. 2006. Quantitative determination by 14C analysis of the biological component in fuels. Radiocarbon 48:315–323.CrossRefGoogle Scholar
EN 13432. 2000. Packaging—Requirements for packaging recoverable through composting and biodegradation—Test scheme and evaluation criteria for the final acceptance of packaging.Google Scholar
EN 14995. 2006. Plastics—Evaluation of compostability—Test scheme and specification.Google Scholar
Environmental Communication Guide. 2012. European Bioplastics, Berlin, Germany.Google Scholar
European Commission. 2008. Ad-hoc Advisory Group for Bio-based Products. Available at http://ec.europa.eu/enterprise/policies/innovation/policy/lead-market-initiative/biobased-products/.Google Scholar
European Commission. 2017. Review of the 2012 European Bioeconomy Strategy. European Commission B-1049. Brussels. p. 1–88.Google Scholar
Li, Z, He, Y, Chen, Q. 2018. Radiocarbon dating of aquatic gastropod shells and its significance in reconstructing Quaternary environmental changes in the Alashan Plateau of northwestern China. Geomorphology 318:18–25.CrossRefGoogle Scholar
Libby, WF. 1960. Radiocarbon dating. Nobel lectures: chemistry 1942–1962. Amsterdam: Elsevier. p 593–610.Google Scholar
Libes, SM. 1992. Introduction to marine biogeochemistry. New York: Wiley.Google Scholar
Martinelli, L, Ometto, J, Ferraz, E. 2009. Uncovering environmental issues with stable isotopes [Desvendando questões ambientais com isótopos estáveis]. Oficina de texto, São Paulo.Google Scholar
Onishia, T, Ninomiya, F, Kunioka, M, Funabashi, M, Ohara, K. 2010. Biomass carbon ratio of polymer composites included biomass or petroleum origin resources. Polymer Degradation and Stability 95:1276–1283.CrossRefGoogle Scholar
Pais, C, Franco-Duarte, R, Sampaiop, Wildner J, Carolas, A, Figueira, D, Ferreira, BS. 2016. Chapter 9, Production of dicarboxylic acid platform chemicals using yeasts: focus on succinic acid. In: Poltronieri, P, D’Urso, OF, editors. Biotransformation of agricultural waste and by-products: Food, feed, fiber, fuel (4F) economy. Elsevier. p. 237–269.CrossRefGoogle Scholar
Polach, HA, Stipp, JJ. 1967. Improved synthesis techniques for methane and benzene radiocarbon dating. The International Journal of Applied Radiation and Isotopes 18:359–364.CrossRefGoogle Scholar
Popa, VI. 2018. Biomass for fuels and biomaterials. Biomass as renewable raw material to obtain bioproducts of high-tech value. p. 1–37.CrossRefGoogle Scholar
Quarta, G, Calcagnile, L, Giffoni, M, Braione, E, D’Elia, M. 2013. Determination of the biobased content in plastics by radiocarbon. Radiocarbon 55:1834–1844.CrossRefGoogle Scholar
Santos, FP, Macario, KD, Jou, RM, Oliveira, FM, Cardoso, RP, Diaz, M, Anjos, RM, Alves, EQ. 2019. Monitoring the biogenic fraction of sugarcane-based plastic bags. Journal of Cleaner Production 233:348–352.CrossRefGoogle Scholar
Shen, L, Haufe, J, Patel, MK. 2009. Product overview and market projection of emerging bio-based plastics: PRO-BIP 2009. Final Report. Utrecht, The Netherlands. p. 1–245.Google Scholar
Suzuki, Y, Kobe, R, Nakashita, R. 2010. A novel method to discriminate between natural and synthetic fibers by stable carbon, nitrogen, and oxygen isotope analyses. Chemistry Letters 41:242–243.CrossRefGoogle Scholar
UNI CEN/TS 16137:2011. Plastics—Determination of bio-based carbon content.Google Scholar
UNI CEN/TR 15932. 2010. Plastics—Recommendation for terminology and characterization of biopolymers and bioplastics.Google Scholar
UNI EN ISO 14067. 2018. Carbon footprint of products—Requirements and guidelines for quantification and communication.Google Scholar