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Radiocarbon Analysis of Methane at the NERC Radiocarbon Facility (East Kilbride)

Published online by Cambridge University Press:  24 April 2019

M H Garnett*
Affiliation:
NERC Radiocarbon Facility, East Kilbride, UK
C Murray
Affiliation:
NERC Radiocarbon Facility, East Kilbride, UK
P Gulliver
Affiliation:
NERC Radiocarbon Facility, East Kilbride, UK Scottish Universities Environmental Research Centre Accelerator Mass Spectrometry Facility, East Kilbride, UK
P L Ascough
Affiliation:
NERC Radiocarbon Facility, East Kilbride, UK
*
*Corresponding author. Email: mark.garnett@glasgow.ac.uk.

Abstract

Methane is the second most important anthropogenically produced greenhouse gas, and radiocarbon (14C) analysis is extremely valuable in identifying its age and source in the environment. At the NERC Radiocarbon Facility (East Kilbride, UK) we have developed expertise in analysis of methane 14C concentration and methodological approaches to field sampling over the past 20 years. This has opened a wide range of applications, which have mainly focused on (1) the age and source of methane emitted by peatlands and organic soils (e.g. to quantify the release of ancient carbon), (2) the source of aquatic emissions of methane, and (3) the age of methane generated by amenity and illegal landfill. Many of these scientifically important applications involve challenging sampling and measurement considerations, which our development program has continually aimed to overcome. Here, we describe our current methods, and recent improvements to aid field collection of samples in remote locations. We present the results of tests which (1) show the effectiveness of our methods to remove contaminants, especially CO2, (2) quantify the 14C background contribution, and (3) demonstrate the reliability of metal gas storage canisters for sample storage.

Type
Conference Paper
Copyright
© 2019 by the Arizona Board of Regents on behalf of the University of Arizona 

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Footnotes

Selected Papers from the 23rd International Radiocarbon Conference, Trondheim, Norway, 17–22 June, 2018

References

REFERENCES

Clymo, RS, Bryant, CL. 2008. Diffusion and mass flow of dissolved carbon dioxide, methane, and dissolved organic carbon in a 7-m deep raised peat bog. Geochimica et Cosmochimica Acta 72:20482066.10.1016/j.gca.2008.01.032CrossRefGoogle Scholar
Cooper, MDA, Estop-Aragones, C, Fisher, JP, Thierry, A, Garnett, MH, Charman, DJ, Murton, JB, Phoenix, GK, Treharne, R, Kokelj, SV, Wolfe, SA, Lewkowicz, AG, Williams, M, Hartley, IP. 2017. Limited contribution of permafrost carbon to methane release from thawing peatlands. Nature Climate Change 7:507511.CrossRefGoogle Scholar
Dean, JF, Billett, MF, Murray, C, Garnett, MH. 2017. Ancient dissolved methane in inland waters revealed by a new collection method at low field concentrations for radiocarbon (14C) analysis. Water Research 115:236244.10.1016/j.watres.2017.03.009CrossRefGoogle ScholarPubMed
Elder, CD, Xu, X, Walker, J, Schnell, JL, Hinkel, KM, Townsend-Small, A, Arp, CD, Pohlman, JW, Gaglioti, BV, Czimczik, CI. 2018. Greenhouse gas emissions from diverse Arctic Alaskan lakes are dominated by young carbon. Nature Climate Change 8:166171.10.1038/s41558-017-0066-9CrossRefGoogle Scholar
Garnett, MH, Gulliver, P, Billett, MF. 2016. A rapid method to collect methane from peatland streams for radiocarbon analysis. Ecohydrology 9:113121.10.1002/eco.1617CrossRefGoogle Scholar
Garnett, MH, Hardie, SML, Murray, C. 2011. Radiocarbon and stable carbon analysis of dissolved methane and carbon dioxide from the profile of a raised peat bog. Radiocarbon 53(1):7183.CrossRefGoogle Scholar
Garnett, MH, Hardie, SML, Murray, C. 2012. Radiocarbon analysis of methane emitted from the surface of a raised peat bog. Soil Biology & Biochemistry 50:158163.10.1016/j.soilbio.2012.03.018CrossRefGoogle Scholar
Garnett, MH, Murray, C. 2013. Processing of CO2 samples collected using zeolite molecular sieve for 14C analysis at the NERC Radiocarbon Facility (East Kilbride, UK). Radiocarbon 55(2):410415.CrossRefGoogle Scholar
Kessler, J, Reeburgh, W. 2005. Preparation of natural methane samples for stable isotope and radiocarbon analysis. Limnology and Oceanography—Methods 3:408418.10.4319/lom.2005.3.408CrossRefGoogle Scholar
Kirschke, S, Bousquet, P, Ciais, P, Saunois, M, Canadell, JG, Dlugokencky, EJ, Bergamaschi, P, Bergmann, D, Blake, DR, Bruhwiler, L, Cameron-Smith, P. 2013. Three decades of global methane sources and sinks. Nature Geoscience 6:813.CrossRefGoogle Scholar
Lassey, K, Lowe, DJ, Smith, A. 2007. The atmospheric cycling of radiomethane and the “fossil fraction” of the methane source. Atmospheric Chemistry and Physics 7:21412149.CrossRefGoogle Scholar
Pack, MA, Xu, X, Lupascu, M, Kessler, JD, Czimczik, CI. 2015. A rapid method for preparing low volume CH4 and CO2 gas samples for 14C AMS analysis. Organic Geochemistry 78:8998.10.1016/j.orggeochem.2014.10.010CrossRefGoogle Scholar
Palonen, V, Uusitalo, J, Seppälä, E, Oinonen, M. 2017. A portable methane sampling system for radiocarbon-based bioportion measurements and environmental CH4 sourcing studies. Review of Scientific Instruments 88:075102.10.1063/1.4993920CrossRefGoogle ScholarPubMed
Rege, SU, Yang, RT, Buzanowski, MA. 2000. Sorbents for air prepurification in air separation. Chemical Engineering Science 55:48274838.10.1016/S0009-2509(00)00122-6CrossRefGoogle Scholar
Sparrow, KJ, Kessler, JD. 2017. Efficient collection and preparation of methane from low concentration waters for natural abundance radiocarbon analysis. Limnology and Oceanography: Methods 15:601617.Google Scholar
Sparrow, KJ, Kessler, JD, Southon, JR, Garcia-Tigreros, F, Schreiner, KM, Ruppel, CD, Miller, JB, Lehman, SJ, Xu, X. 2018. Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf. Science Advances 4:eaao4842.CrossRefGoogle ScholarPubMed
Slota, P, Jull, AJT, Linick, T, Toolin, LJ. 1987. Preparation of small samples for 14C accelerator targets by catalytic reduction of CO. Radiocarbon 29(2):303306.10.1017/S0033822200056988CrossRefGoogle Scholar
Stuiver, M, Polach, HA. 1977. Reporting of 14C data. Radiocarbon 19(3):355363.CrossRefGoogle Scholar
Turner, AJ, Frankenberg, C, Wennberg, PO, Jacob, DJ. 2017. Ambiguity in the causes for decadal trends in atmospheric methane and hydroxyl. Proceedings of the National Academy of Sciences 114:53675372.CrossRefGoogle ScholarPubMed