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Sorption of Simazine and S-Metolachlor to Soils from a Chronosequence of Turfgrass Systems

Published online by Cambridge University Press:  20 January 2017

Travis W. Gannon ,
Adam C. Hixson ,
Jerome B. Weber ,
Wei Shi ,
Fred H. Yelverton  and
Thomas W. Rufty
Travis W. Gannon*
Affiliation:
Crop Science Department, North Carolina State University, Raleigh, NC 27695
Adam C. Hixson
Affiliation:
BASF Corporation, Lubbock, TX 79424
Jerome B. Weber
Affiliation:
Crop Science Department, North Carolina State University, Raleigh, NC 27695
Wei Shi
Affiliation:
Soil Science Department, North Carolina State University, Raleigh, NC 27695
Fred H. Yelverton
Affiliation:
Crop Science Department, North Carolina State University, Raleigh, NC 27695
Thomas W. Rufty
Affiliation:
Crop Science Department, North Carolina State University, Raleigh, NC 27695
*
Corresponding author's E-mail: travis_gannon@ncsu.edu
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Abstract

Pesticide sorption by soil is among the most sensitive input parameters in many pesticide-leaching models. For many pesticides, organic matter is the most important soil constituent influencing pesticide sorption. Increased fertility, irrigation, and mowing associated with highly maintained turfgrass areas result in constant deposition of organic material, creating a soil system that can change drastically with time. Changes in soil characteristics could affect the environmental fate of pesticides applied to turfgrass systems of varying ages. Sorption characteristics of simazine and S-metolachlor were determined on five soils from bermudagrass systems of increasing ages (1, 4, 10, 21, and 99 yr) and compared to adjacent native pine and bare-ground areas. Surface soil (0 to 5 cm) and subsurface soil (5 to 15 cm) from all sites were air-dried and passed through a 4-mm sieve for separation from plant material. Using a batch-equilibrium method, sorption isotherms were determined for each soil. Data were fit to the Freundlich equation, and K d (soil sorption coefficient) and K oc (organic carbon sorption coefficient) values were determined. Sorption and soil system age were directly related to organic matter content in the soil. Sorption of both herbicides increased with age of the soil system and was greatest on the surface soil from the oldest bermudagrass soil system. Herbicide sorption decreased at greater soil depths with lower organic matter. Greater amount of 14C–simazine sorbed to subsurface soil of the oldest turfgrass system compared to 14C–S-metolachlor. Results indicate that as bermudagrass systems age and accumulate higher organic matter levels increased herbicide sorption may decrease the leaching potential and bioavailability of simazine and S-metolachlor.

Keywords

SimazineS-metolachlorbermudagrassCynodon dactylon [(L.) Pers.]BioavailabilityK dK ocorganic mattersoil sorption coefficient
Type
Soil, Air, and Water
Information
Weed Science , Volume 61 , Issue 3 , September 2013 , pp. 508 - 514
Copyright
Copyright © Weed Science Society of America 

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