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Adjuvant Effects on Absorption, Translocation, and Metabolism of Haloxyfop-Methyl in Corn (Zea mays)

Published online by Cambridge University Press:  12 June 2017

S. Kent Harrison  and
Loyd M. Wax
S. Kent Harrison
Affiliation:
Dep. Agron., Univ. Illinois
Loyd M. Wax
Affiliation:
Agric. Res. Serv., U.S. Dep. Agric., Urbana, IL 61801
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Abstract

The effects of adjuvants and relative humidity (RH) on absorption, translocation, and metabolism of the methyl ester of 14C-haloxyfop {2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy] propanoic acid} in corn (Zea mays L. ‘B73 X Mo17’ hybrid) were evaluated. Addition of 1.0% (v/v) petroleum oil concentrate (POC) to the treatment solution resulted in greater foliar absorption and translocation of 14C than addition of 1.0% (v/v) soybean oil concentrate (SBOC), 0.1% (v/v) oxysorbic (20 POE) (polyoxyethylene sorbitan monolaurate) (OXY), or no adjuvant (NONE). The least amount of 14C absorption occurred in the treatment containing OXY. Absorption and translocation of radioactivity were significantly greater at 70% RH than at 30% RH. Thin-layer chromatography revealed that most of the 14C recovered from treated plants was in haloxyfop-methyl 5 h after treatment (HAT). The remaining 14C recovered was haloxyfop and an unidentified polar metabolite. The average percentage of 14C-haloxyfop in the nonabsorbed fraction was 5, 39, 7, and 7% for treatments containing NONE, OXY, POC, and SBOC, respectively. The ratio of haloxyfop-methyl to haloxyfop and the percentage of polar metabolite in the absorbed 14C fraction was not different among adjuvant treatments or between levels of RH.

Keywords

Herbiciderelative humiditysurfactantsoybean oil
Type
Physiology, Chemistry, and Biochemistry
Information
Weed Science , Volume 34 , Issue 2 , March 1986 , pp. 185 - 195
Copyright
Copyright © 1986 by the Weed Science Society of America 

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References

Literature Cited

1. Barrentine, W. L. and McWhorter, C. G. 1985. Oil carriers for herbicides applied postemergence to Johnsongrass. Abstr. Weed Sci. Soc. Am. Page 4.Google Scholar
2. Boldt, P. F. and Putnam, A. R. 1980. Selectivity mechanisms for foliar applications of diclofop-methyl. I. Retention, absorption, translocation, and volatility. Weed Sci. 28:474–477.CrossRefGoogle Scholar
3. Boldt, P. F. and Putnam, A. R. 1981. Selectivity mechanisms for foliar applications of diclofop-methyl. II. Metabolism. Weed Sci. 29:237–241.CrossRefGoogle Scholar
4. Buhler, D. D., Swisher, B. A., and Burnside, O. C. 1985. Behavior of 14C-haloxyfop-methyl in intact plants and cell cultures. Weed Sci. 33:291–299.CrossRefGoogle Scholar
5. Chen, Yong-Zheng and Penner, D. 1985. Combination effects of acifluorfen with crop oil concentrates and postemergence grass herbicides. Weed Sci. 33:91–95.CrossRefGoogle Scholar
6. Coats, G. E. and Foy, C. L. 1974. Effects of atrazine-phytobland oil combinations on 14CO2-fixation and transpiration. Weed Sci. 22:215–220.CrossRefGoogle Scholar
7. Coats, G. E. and Foy, C. L. 1974. Effect of petroleum oils on the uptake of atrazine-14C by corn. Weed Sci. 22:220–226.CrossRefGoogle Scholar
8. Coffman, C. B. and Gentner, W. A. 1984. Soybean oil concentrate applications on selected plant species. Abstr. Weed Sci. Soc. Am. Page 12.Google Scholar
9. Dow Chemical Company. 1984. Technical information bulletin. Agric. Products Dep., Dow Chemical Co., Midland, MI. 11 pp.Google Scholar
10. Harrison, S. K. and Wax, L. M. 1983. Soybean and petroleum oil concentrates as adjuvants for postemergence herbicides. Proc. North Cent. Weed Control Conf. 38:11–12.Google Scholar
11. Hatzios, K. K. and Penner, D. 1982. Metabolism of herbicides in higher plants. Burgess Publishing Co., Minneapolis. 142 pp.Google Scholar
12. Jain, R. and Vanden Born, W. H. 1983. Morphological and histological effects of sethoxydim, fluazifop-butyl, and Dowco 453 on wild oats (Avena fatua). Abstr. Weed Sci. Soc. Am. Page 73.Google Scholar
13. Hendley, P., Dicks, J. W., Monaco, T. J., Slyfield, S. M., Tummon, O. J., and Barrett, J. C. 1985. Translocation and metabolism of pyridinyloxyphenoxypropionate herbicides in rhizomatous quackgrass (Agropyron repens). Weed Sci. 33:11–24.CrossRefGoogle Scholar
14. Kells, J. J., Meggitt, W. F., and Penner, D. 1984. Absorption, translocation, and activity of fluazifop-butyl as influenced by plant growth stage and environment. Weed Sci. 32:143–149.CrossRefGoogle Scholar
15. McWhorter, C. G. 1979. The effect of surfactant and environment on the toxicity of metriflufen to soybeans (Glycine max) and johnsongrass (Sorghum halepense). Weed Sci. 27:675–679.CrossRefGoogle Scholar
16. McWhorter, C. G. 1981. Effect of temperature and relative humidity on translocation of 14C-metriflufen in johnsongrass (Sorghum halepense) and soybean (Glycine max). Weed Sci. 29:87–93.CrossRefGoogle Scholar
17. Nalewaja, J. D., Pudelko, J., and Adamczewski, K. A. 1975. Influence of climate and additives on bentazon. Weed Sci. 23:504–407.CrossRefGoogle Scholar
18. Nalewaja, J. D. and Adamczewski, K. A. 1977. Uptake and translocation of bentazon with additives. Weed Sci. 25:309–315.CrossRefGoogle Scholar
19. Oliver, L. R., Banks, V. E., and Walker, J. T. 1984. Soybean oil as a carrier for postemergence herbicides. Abstr. Weed Sci. Soc. Am. Page 12.Google Scholar
20. Smith, A. E. 1976. Esterification of the hydrolysis product of the herbicide diclofop-methyl in methanol. J. Agric. Food Chem. 24:1077–1078.CrossRefGoogle ScholarPubMed
21. Steel, R.G.D. and Torrie, J. H. 1980. Principles and Procedures of Statistics – A Biometrical Approach. 2nd ed. McGraw-Hill Book Co., New York. 633 pp.Google Scholar
22. Velovitch, J. J. and Slife, F. W. 1983. Uptake, translocation, and metabolism of fluazifop-butyl in foxtail millet [Setaria italica (L.) Beauv.] and common cocklebur (Xanthium pensylvanicum Wallr.). Abstr, Weed Sci. Soc. Am. Page 74.Google Scholar
23. Wills, G. D. 1984. Toxicity and translocation of sethoxydim in bermudagrass (Cynodon dactylon) as affected by environment. Weed Sci. 32:20–24.CrossRefGoogle Scholar