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Influence of Prior Pesticide Treatments on EPTC and Butylate Degradation

Published online by Cambridge University Press:  12 June 2017

Brent W. Bean
Affiliation:
Dep. Agron., Univ. Nebraska, Lincoln, 68583
Fred W. Roeth
Affiliation:
South Central Res. and Ext. Ctr., Clay Center, 68933
Alex R. Martin
Affiliation:
Dep. Agron., Lincoln, 68583
Robert G. Wilson
Affiliation:
Panhandle Res. and Ext. Ctr., Scottsbluff, 69361

Abstract

Field and laboratory studies were conducted to examine the influence of previous pesticide use, number of prior EPTC (S-ethyl dipropyl carbamothioate) and butylate [S-ethyl bis(2-methylpropyl)carbamothioate] applications, and pretreatment of soil with EPTC and butylate metabolites on EPTC and butylate degradation. EPTC degradation was enhanced in Clay Center and Scottsbluff soils following three annual EPTC, butylate, or vernolate (S-propyl dipropylcarbamothioate) applications, but was not affected in soils following three annual atrazine [6-chloro-N-ethyl-N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine], cyanazine {2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl] amino]-2-methylpropanenitrile}, metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide], alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide], or cycloate (S-ethyl cyclohexylethylcarbamothioate) applications. EPTC degradation rate was not affected in a Scottsbluff soil following three annual carbofuran (2,3-dihydro-2,2-dimethyl-7-benzofuranyl methylcarbamate) applications, but was partially enhanced in a Clay Center soil. Self- and cross-enhanced degradation of EPTC and butylate did not change regardless of the number of prior annual applications of each herbicide. The degradation rates of EPTC and butylate were not affected by soil pretreated with butylate sulfone, but the degradation rates-were fully enhanced by pretreatment with the respective sulfoxides of each herbicide. In cross-enhancement testing, EPTC and butylate degradation was partially enhanced in Clay Center soil pretreated with the sulfoxides of each.

Type
Soil, Air, and Water
Copyright
Copyright © 1988 by the Weed Science Society of America 

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References

Literature Cited

1. Ahmad, N., Walgenbach, D. D., and Sutter, G. R. 1979. Degradation rates of technical carbofuran and a granular formulation in four soils with known insecticide use history. Bull. Environ. Contam. Toxicol. 23:572574.Google Scholar
2. Alexander, M. 1977. Introduction to soil microbiology. Page 22. John Wiley & Sons, New York.Google Scholar
3. Casida, J. E., Kimmel, E. C., Lay, M., Ohkawa, H., Rodebush, J. E., Gray, R. A., Tseng, C. K., and Tilles, H. 1974. Thiocarbamate sulfoxide herbicides. Environ. Qual. Saf. 3:675679.Google Scholar
4. Felsot, A., Maddox, J. V., and Bruce, W. 1981. Enhanced microbial degradation of carbofuran in soils with histories of Furadan use. Bull. Environ. Contam. Toxicol. 26:781788.Google Scholar
5. Gray, R. A. and Joo, G. K. 1985. Reduction in weed control after repeat applications of thiocarbamate and other herbicides. Weed Sci. 33:698702.CrossRefGoogle Scholar
5. Harvey, R. G. and Schuman, D. B. 1981. Accelerated degradation of thiocarbamate herbicides with repeated use. Abstr. Weed Sci. Soc. Am. 21:124.Google Scholar
7. Menkveld, B. and Dekker, J. H. 1984. Accelerated breakdown of butylate+ in soils with a history of its use. Abstr. Weed Sci. Soc. Am. 24:99.Google Scholar
8. Menkveld, J. W. and Dekker, J. H. 1985. Soil acclimatization to butylate+ in Ontario: comparison of degradation rates in history soils and adjacent fields. Abstr. Weed Sci. Soc. Am. 25:91.Google Scholar
9. Obrigawitch, T., Wilson, R. G., Martin, A. R., and Roeth, F. W. 1982. The influence of temperature, moisture, and prior EPTC application on the degradation of EPTC in soils. Weed Sci. 30: 175181.Google Scholar
10. Obrigawitch, T., Martin, A. R., and Roeth, F. W. 1983. Degradation of thiocarbamate herbicides in soils exhibiting rapid EPTC breakdown. Weed Sci. 31:187192.CrossRefGoogle Scholar
11. Rahman, A., Atkinson, G. C., and Douglas, J. A. 1979. Eradicane causes problems. N. Z. J. Agric. 139:4749.Google Scholar
12. Rahman, A. and James, T. K. 1983. Decrease of EPTC + R-25788 following repeated use in some New Zealand soils. Weed Sci. 31:783789.CrossRefGoogle Scholar
13. Read, D. C. 1983. Enhanced microbial degradation of carbofuran and fensulfothion after repeated applications to acid mineral soil. Agric. Ecosystems Environ. 10:3746.CrossRefGoogle Scholar
14. Read, D. C. 1986. Accelerated microbial breakdown of carbofuran in soil from previously treated fields. Agric. Ecosystems Environ. 15:5161.CrossRefGoogle Scholar
15. Rudyanski, W. J., Fawcett, R. S., and McAllister, R. S. 1987. Effect of prior pesticide use on thiocarbamate herbicide persistence and giant foxtail (Setaria faberi) control. Weed Sci. 35:6874.Google Scholar
16. Schuman, D. B. and Harvey, R. G. 1982. Accelerated degradation of thiocarbamate herbicides on predisposed soil. Abstr. Weed Sci. Am 22:106.Google Scholar
17. Skipper, H. D., Gooden, D. T., Zublena, J. P., Amakiri, M. A., and Struble, J. E. 1985. Fate of butylate history and EPTC in butylate-history soils. Abstr. Weed Sci. Soc. Am. 25:91.Google Scholar
18. Tuxhorn, G. L., Roeth, F. W., Martin, A. R., and Wilson, R. G. 1986. Butylate persistence and activity in soils previously treated with thiocarbamates. Weed Sci. 34:961965.Google Scholar
19. Wilson, R. G. 1984. Accelerated degradation of thiocarbamate herbicides with prior thiocarbamate herbicide exposure. Weed Sci. 32:264268.CrossRefGoogle Scholar