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Mobility of Herbicides in Soil Columns Under Saturated- and Unsaturated-Flow Conditions

Published online by Cambridge University Press:  12 June 2017

Jerome B. Weber  and
David M. Whitacre
Jerome B. Weber
Affiliation:
Dep. Crop Sci., North Carolina State Univ., Raleigh, NC 27650
David M. Whitacre
Affiliation:
Environ. Sci., Velsicol Chem. Corp Chicago, IL 60641
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Abstract

Under unsaturated-flow conditions, bromacil (5-bromo-3-sec-butyl-6-methyluracil) was considerably more mobile than buthidazole {3-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-4-hydroxyl-1-methyl-2-imidazolidinone}. Because of their high water solubilities, both herbicides were much more mobile than atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine), prometon [2,4-bis (isopropylamino)-6-methoxy-s-triazine], or diuron [3-(3,4-dichlorophenyl)-1,1-dimethylurea]. Under saturated-flow conditions, buthidazole was leached through Lakeland loamy sand in slightly greater amounts than tebuthiuron {N-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-N,N′-dimethylurea} or CN-10-3510 (formerly VEL 3510) {1-β,β-dimethoxyl-1-methyl-3-[5-(1,1-dimethylethyl)-1,3, 4-thiadiazol-2-yl] urea}. Distribution of the three herbicides in the leached soil was similar and relatively uniform. In Lakeland loamy sand, 30 times as much tebuthiuron was leached under saturated-flow conditions as under unsaturated-flow conditions. Intermittent saturated-unsaturated-flow conditions resulted in four times as much leaching of tebuthiuron as unsaturated flow alone. Only one-tenth as much tebuthiuron leached under intermittent saturated-unsaturated-flow conditions as under saturated-flow conditions. Tebuthiuron added to Lakeland soil and oven-dried was retained in significantly greater amounts than when added to moist Lakeland soil. Low amounts of tebuthiuron leached through Lakeland loamy sand, Portsmouth sandy loam, and Rains silt loam, but high amounts leached through Davidson clay. Greater amounts of the herbicide were retained in the surface zones of the three former soils, but the inverse was the case for the Davidson soil.

Keywords

Leachingmass flowbuthidazoletebuthiuronCN-10-3510atrazinebromacildiuronprometon
Type
Research Article
Information
Weed Science , Volume 30 , Issue 6 , November 1982 , pp. 579 - 584
Copyright
Copyright © 1982 by the Weed Science Society of America 

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