Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-10T06:32:15.306Z Has data issue: false hasContentIssue false

Persistence and Movement of Diuron and 3,4-Dichloroaniline in an Orchard Soil

Published online by Cambridge University Press:  12 June 2017

S. U. Khan
Affiliation:
Res. Sci. Chem. and Biol. Res. Inst. Agric. Canada, Ottawa, Ontario K1A 0C6
P. B. Marriage
Affiliation:
Res. Sci. Res. Sta., Agric. Canada, Harrow, Ontario NOR 1G0
W. J. Saidak
Affiliation:
Res. Coord. Res. Branch, Agric. Canada, Ottawa, Ontario K1A 0C6

Abstract

The movement and persistence of diuron [3-(3,4-dichlorophenyl)-1,1-dimethylurea] and its degradation product, 3,4-DCA (3,4-dichloraniline) were studied in an orchard soil which had received diuron annually at the rate of 4.5 kg/ha for 7 yr. Accumulation of residues was not observed at significant levels although carry-over of the herbicide occurred between years. The bulk of the herbicide residue was confined to the upper 15 cm of soil. The degradation rate of diuron generally followed first-order kinetics and the residual levels of diuron in the soil were highly phytotoxic to oat (Avena sativa L.) plants during the 3 yr after the last application. The levels of 3,4-DCA were low in all soil samples (< 21 ppb) and its relative distribution in the soil profile was similar to that of diuron.

Type
Research Article
Copyright
Copyright © 1977 by the Weed Science Society of America 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature Cited

1. Bartha, R., Linke, H.A.B., and Pramer, D. 1968. Pesticide transformations: production of chloroazobenzenes from chloroanilines. Science 161:582583.CrossRefGoogle ScholarPubMed
2. Belasco, I.J. and Pease, H.L. 1969. Investigation of diuron- and linuron-treated soils for 3,3′,4,4′-tetrachloroazobenzene. J. Agric. Food chem. 17:14141417.Google Scholar
3. Bowmer, K.H. 1972. Long-term use of herbicides: measurement of residues of diuron and simazine in an orchard soil. Aust. J. Exp. Agric. Anim. Husb. 12:535539.CrossRefGoogle Scholar
4. Dalton, R.L., Evans, A.W., and Rhodes, R.C. 1966. Disappearance of diuron from cotton field soils. Weeds 14:3133.Google Scholar
5. Damanakis, M., Drennan, D.S.H., Fryer, J.D., and Holly, K. 1970. The adsorption and mobility of paraquat on different soils and soil constituents. Weed Res. 10:264277.Google Scholar
6. Dawson, J.H., Bruns, V.F., and Clore, W.J. 1968. Residual monuron, diuron, and simazine in a vineyard soil. Weed Sci. 16:6365.Google Scholar
7. Hance, R.J. and McKone, C.E. 1971. Effect of concentration on the decomposition rates in soil of atrazine, linuron and picloram. Pestic. Sci. 2:3134.Google Scholar
8. Hill, G.D., McGahen, J.W., Baker, H.M., Finnerty, D.W., and Bingeman, C.W. 1955. The fate of substituted urea herbicides in agricultural soils. Agron. J. 47:93104.CrossRefGoogle Scholar
9. Horowitz, M., Blumenfeld, T., Herzlinger, G., and Hulin, N. 1974. Effects of repeated applications of ten soil-active herbicides on weed population, residue accumulation and nitrification. Weed Res. 14:97109.Google Scholar
10. Horowitz, M. and Herzlinger, G. 1974. Soil conditions affecting the dissipation of diuron, fluometuron and propham from the soil surface. Weed Res. 14:257259.Google Scholar
11. Kilgore, W.W. and Li, M. 1973. The carcinogenicity of pesticides. Resid. Rev. 48:141161.Google Scholar
12. Leonard, O.A., McHenry, W.B., and Lider, L.A. 1974. Herbicide residues in soil of the vine row 21 months following 9 successive annual applications. Proc. Ann. Calif. Weed Conf. 26:115122.Google Scholar
13. Saidak, W.J. 1971. Herbicide mixtures for weed control in young peach orchards. Abstr. Weed Sci. Soc. Amer., p. 58.Google Scholar
14. Sheets, T.J. 1964. Review of disappearance of substituted urea herbicides from soil. J. Agric. Food chem. 12:3033.CrossRefGoogle Scholar
15. Upchurch, R.P., Corbin, F.T., and Selman, F.L. 1969. Persistence pattern for diuron and linuron in Norfolk and Dublin sandy loam soils. Weed Sci. 17:6977.Google Scholar