Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-28T18:38:59.205Z Has data issue: false hasContentIssue false

Protection of Corn (Zea mays) from Acetanilide Herbicidal Injury with the Antidote R-25788

Published online by Cambridge University Press:  12 June 2017

J. R. C. Leavitt
Affiliation:
Pestic. Res. Center, Dep. Crop Soil Sci., Michigan State Univ., East Lansing, MI 48824
Donald Penner
Affiliation:
Pestic. Res. Center, Dep. Crop Soil Sci., Michigan State Univ., East Lansing, MI 48824

Abstract

The antidote R-25788 (N,N-diallyl-2,2-dichloroacetamide) protected corn (Zea mays L. ‘DeKalb 315A’) seedlings from injury caused by the acetanilide herbicides, alachlor [2-chloro-2′,6′-diethyl-N-(methoxymethyl)acetanilide], metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide], H-22234 [N-chloroacetyl-N-(2,6-diethylphenyl)glycine ethyl ester], and H-26910 [N-chloroacetyl-N-(2-methyl-6-ethylphenyl)glycine isopropyl ester] in a greenhouse study. R-25788, however, did not protect four weed species tested. R-25788 only partially protected corn from injury caused by acetochlor [2-chloro-N-(ethoxymethyl)-6′-ethyl-o-acetotoluidide]. R-25788 was an effective antidote whether applied preemergence, preplant-incorporated, or as a tank mix. Injury symptoms caused by EPTC (S-ethyl dipropylthiocarbamate) and the acetanilide herbicides were similar; both caused leaf twisting and rolling, and at high rates leaves failed to emerge through the coleoptile.

Type
Research Article
Copyright
Copyright © 1978 by the Weed Science Society of America 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature Cited

1. Casida, J. F., Gray, R. A., and Tilles, H. 1974. Thiocarbamate sulfoxides: potent, selective, and biodegradable herbicides. Science 184:573574.Google Scholar
2. Chang, F. Y., Bandeen, J. D., and Stephenson, G. R. 1972. A selective antidote for prevention of EPTC injury in corn. Can. J. Plant Sci. 52:704714.Google Scholar
3. Chang, F. Y., Bandeen, J. D., and Stephenson, G. R. 1973. N,N-diallyl-α,α-dichloroacetamide as an antidote for EPTC and other herbicides in corn. Weed Res. 13:399406.Google Scholar
4. Frear, D. S. and Swanson, H. R. 1970. Biosynthesis of S-(4-ethylamino-6-isopropylamine-2-s-triazine) glutathione: partial purification and properties of a glutathione-S-transferase from corn. Phytochemistry 9:2123.CrossRefGoogle Scholar
5. Hubbell, J. P. and Casida, J. E. 1977. Metabolic fate of the N,N-dialkyl-carbamoyl moiety of thiocarbamate herbicides in rats and corn. Agric. Food Chem. 25:404413.Google Scholar
6. Lamoureaux, G. L., Stafford, L. E., Tanaka, F. S. 1971. Metabolism of 2-chloro-N-isopropylacetamide (propachlor) in the leaves of corn, sorghum, sugarcane and barley. J. Agric. Food Chem. 19:346350.CrossRefGoogle Scholar
7. Lay, M. M. and Casida, J. E. 1976. Dichloroacetamide antidotes enhance thiocarbamate sulfoxide detoxification by elevating corn root glutathione content and glutathione-S-transferase activity. Pestic. Biochem. Physiol. 6:442456.Google Scholar
8. Lay, M. M., Hubbell, J. P., and Casida, J. E. 1975. Dichloroacetamide antidotes for thiocarbamate herbicides: mode of action. Science 189:287289.Google Scholar
9. Meggitt, W. F., Kern, A. D., and Armstrong, T. F. 1972. Crop prorectants and the use of thiocarbamates in corn. Proc. North Cent. Weed Control Conf. 27:22.Google Scholar
10. Rains, L. J. and Fletchall, O. H. 1971. The use of chemicals to protect crops from herbicide injury. Proc. North Cent. Weed Control Conf. 26:42.Google Scholar
11. Stephenson, G. R., Bunce, N. J., Makowski, R. I., and Currie, J. C. 1978. Structure activity relationships for S-ethyl-N,N-dipropylthiocarbamate (EPTC) antidotes in corn. J. Agric. Food Chem. 26:137140.Google Scholar
12. Stephenson, G. R. and Chang, F. Y. 1978. Comparative activity, selectivity and field applications of herbicide antidotes. Pages 3561 in Casida, J. E. and Pallos, F. M., eds. Chemistry and Action of Herbicide Antidotes. Academic Press, New York.Google Scholar