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Hydrotalcite-Like Minerals (M2Al(OH)6(CO3)0.5.XH2O, Where M = Mg, Zn, Co, Ni) in the Environment: Synthesis, Characterization and Thermodynamic Stability

Published online by Cambridge University Press:  01 January 2024

C. A. Johnson  and
F. P. Glasser
C. A. Johnson*
Affiliation:
Swiss Federal Institute of Environmental Science and Technology (EAWAG), Postfach 611, CH-8600 Dübendorf, Switzerland
F. P. Glasser
Affiliation:
Chemistry Department, University of Aberdeen, Meston Walk, Old Aberdeen AB24 3UE, UK
*
*E-mail address of corresponding author: johnson@eawag.ch
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Abstract

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Hydrotalcite-like layered double hydroxides (LDH), of the formulation M2Al(OH)6(CO3)0.5.H2O, where M = Mg, Zn, Co, Ni, have been prepared, the products characterized and their solubility products measured at ionic strengths of 0.0065 and 0.0128 M and at 25°C. Steady-state solubility was reached after 100 days. The solubility products have been formulated according to the following reaction: M2Al(OH)60.5CO3⋅H2O+6H+→2M2++Al3++0.5CO32−+H2O where

KSO=[M2+]2[Al3+][CO32−]0.5[H]6

Average values of Kso for I = 0, estimated using the Davies equation, are 25.43, 20.80, 22.88 and 20.03 for Mg, Zn, Co and Ni, respectively. Model calculations reveal that the thermodynamic stability of the LDHs is greater than that of the corresponding divalent hydroxides for Zn, Co and Ni below a pH of ∼10, 9 and 8, respectively, and at least up to pH 12 for Mg.

Keywords

CobaltHydrotalciteMagnesiumNickelSolubilityZinc
Type
Research Article
Information
Clays and Clay Minerals , Volume 51 , Issue 1 , February 2003 , pp. 1 - 8
Copyright
Copyright © 2003, The Clay Minerals Society

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