The beneficial effect of B on the hot ductility of 20CrMnTi steel with 0.05% Sn wasinvestigated. The results show that there is a trough in the hot ductility-temperaturecurve. With the increase in the B content, the trough shifts to a lower temperature andbecomes shallow, and the hot brittle range becomes narrow. In addition, B greatlyenhancing the hot ductility was due mainly to its suppressing the Sn segregation,retarding the austenite/ferrite deformation, accelerating the onset of dynamicrecrystallization (DRX) and promoting the intragranular nucleation of ferrite. Moreover,in the present case, adding 92 ppm B can nucleation of ferrite. Moreover, in the presentcase, adding 92 ppm B can obtain the best effect in improving the hot ductility of20CrMnTi steel with 0.05% Sn.