We explore the feasibility of accelerating electron beams up to energies much beyond 1 TeV in a realistic scale and evolution of the beam qualities such as emittance and energy spread at the final beam energy on the order of 100 TeV, using the newly formulated coupled equations describing the beam dynamics and radiative damping of electrons. As an example, we present a design for a 100 TeV laser-plasma accelerator in the operating plasma density np = 1015 cm−3 and numerical solutions for evolution of the normalized emittance as well as their analytical solutions. We show that the betatron radiative damping causes very small normalized emittance that promises future applications for the high-energy frontier physics.