Zircon separates from the contact aureole of the syn-tectonic Dawros–Currywongaun–Doughruagh Complex, western Ireland, are studied to constrain the nature and timing of magmatism associated with the early stages of the Grampian Orogeny. The samples analysed come from the uppermost part of the Dalradian Supergroup in northern Connemara (the Ben Levy Grit Formation), where a laterally extensive (>10 km) package of metamorphosed siliciclastic sedimentary rocks containing heavy mineral seams crops out. The seams mainly comprise magnetite, but zircon is also present in greater than accessory quantities. The seams have been locally reworked at granulite-facies metamorphic conditions during intrusion of the Dawros–Currywongaun–Doughruagh Complex magmas. Here we combine in situ mineral chemical and U–Pb geochronological analyses of zircons from samples of these heavy mineral seams collected at different locations in the Dawros–Currywongaun–Doughruagh Complex thermal aureole. An important finding is that the zircons studied have magmatic trace-element compositions, interpreted here as a function of their growth during contact metamorphic-induced partial melting. The zircons yield a range of U–Pb spot ages whose uncertainties suggest a maximum duration of zircon growth of ˜11 Ma, between 477.1 and 466.1 Ma, though it is likely that zircon growth occurred much more quickly than this. The age constraints revealed here match well with the range of 475 to 463 Ma previously proposed for the Grampian Orogeny overall in Connemara and lend useful support to models that argue for high-intensity, relatively short-lived Grampian orogenesis in the Connemara Caledonides.

Microprobe analyses of the halogen contents of apatites from two samples of amphibolite-facies schist from Connemara, Ireland, have been used to calculate the fugacity ratios fHCl/fH2O and fHF/fH2O using the experimental data of Korzhinskiy. The results imply fugacities for both acids in the range 0.03 to 0.1 bars, but whereas for the lower grade rock fHF > fHCl, the migmatitic sample gives fHF⋍fHCl. An independent estimate of fHF/fH2O from the biotite composition in one sample is in acceptable agreement with the result obtained from apatite.

Högbomite occurs in two contrasting mineral assemblages within the Currywongaun-Dough-ruagh intrusion of north Connemara: a cordierite-rich pelitic xenolith and an orthopyroxenite. In the latter, högbomite and green spinel form blebs within magnetite-ilmenite grains. The högbomite displays significant compositional variation from grain to grain: TiO2 (3.0–6.3%), FeO (21.6–21.3%), MgO (10.0–7.5%), ZnO (3.6–2.4%). This chemical heterogeneity appears to represent variable degrees of partial substitution of Mg and Zn by Ti, in the replacement of spinel by högbomite. By contrast, in the cordierite-hornfels, the högbomite compositions are more notably enriched in iron: TiO2 (4.7–7.0%), FeO (29.6–24.3%), MgO (4.2–6.2%), ZnO (2.7–2.1%). This iron-rich högbomite appears to have formed primarily by interaction between opaque ore and adjacent cordierite, rather than by replacement of spinel.

Two high-grade metamorphic episodes appear to be necessary for högbomite growth, one determining chemical composition and the other appropriate physical parameters. In the Connemara occurrences thermal metamorphism and partial melting, coupled with contamination of the surrounding magma, controlled the formation of mineral assemblages rich in Fe, Mg, Al, Ti, and Zn. Emplacement of the intrusion was accompanied by amphibolite facies regional metamorphism and it is to this metamorphic event that the growth of högbomite may be attributed.

In the aureole of the late Caledonian Omey granite corundum develops in the Dalradian country rocks in a zone up to 250 m from the granite contact. The distribution of andalusite and K-feldspar in pelites and calcite+wollastonite+grossularite in marbles is consistent with inner-aureole metamorphic conditions of 615±25°C at 2.5±0.25 kbar, and ⋍ 0.85. Corundum develops from the reaction muscovite → corundum + K-feldspar+H2O and first appears over 100 m further from the granite than the assemblage wollastonite + grossularite + anorthite. Experimentally determined equilibria can be satisfied only if for the corundum-producing reaction was less than 0.6 and perhaps as low as 0.4. Corundum always grows within large muscovite crystals;fH2O within the crystal lattice is unrelated to that in the grain-boundary fluid of the surrounding rock.

Although whole-rock oxidation ratios are irregularly distributed within the aureole they are uniformly low in corundum-bearing rocks. Reducing conditions probably resulted from localized flow of H2O-rich fluid away from the granite in a diffuse channelway that contains most of the corundum localities and also a distinctive skarn. Although corundum growth within muscovite is sealed off from the external water vapour conditions, it is suggested that movement of H2O down a thermal gradient (and hence down an fH2O gradient at constant pressure) promotes the escape of (OH)− from the muscovite lattice and so allows the corundum reaction to proceed.

New Re–Os age determinations from the Galway Granite (samples: KMG = 402.2 ± 1.1 Ma, LLG = 399.5 ± 1.7 Ma and GBM = 383.3 ± 1.1 Ma) show that in south Connemara, late Caledonian granite-related molybdenite mineralization extended from c. 423 Ma to c. 380 Ma. These events overlap and are in excellent agreement with the published granite emplacement history determined by U–Pb zircon geochronology. The spatial distribution of the late-Caledonian Connemara granites indicates that initial emplacement and molybdenite mineralization occurred at c. 420 Ma (that is, the Omey Granite and probably the Inish, Leterfrack and Roundstone granites) to the N and NW of the Skird Rocks Fault, an extension of the orogen-parallel Southern Uplands Fault in western Ireland. A generally southern and eastward progression of granite emplacement (and molybdenite mineralization) sited along the Skird Rocks Fault then followed, at c. 410 Ma (Roundstone Murvey and Carna granites), at c. 400 Ma (Errisbeg Townland Granite, Megacrystic Granite, Mingling Mixing Zone Granodiorite, Lough Lurgan Granite and Kilkieran Murvey Granite) and at c. 380 Ma (Costelloe Murvey Granite, Shannapheasteen and Knock granites). The duration of granite magmatism and mineralization in Connemara is similar to other sectors of the Appalachian–Caledonian orogeny and several tectonic processes (e.g. slab-breakoff, asthenospheric flow, transtension and decompression) may account for the duration and variety of granite magmatism of the western Irish Caledonides.

The Rosroe Formation comprises a series of Lower Ordovician (Llanvirn) conglomerates and sandstones, that lies on the southern limb of the South Mayo Trough, within the Iapetus Suture Zone of western Ireland. Trace element chemistry of granite boulders within the formation indicates a continental, rather than a volcanic arc character that can be correlated to latest Precambrian granites within the Dalradian Metamorphic Block, part of the deformed Laurentian margin. A minority of the clasts may correlate with syn-collisional granites, similar to, but older than, the Oughterard Granite of Connemara. Pb isotope compositions of K-feldspar grains within the sandstones, measured by both ion microprobe and conventional mass spectrometry, show a clear Laurentian affinity, albeit with greater source variability in the sand grains compared to a limited range in the proximal boulders. Palaeo-current indicators demonstrate dominant derivation from the NE, with a significant axial E–W flow. We propose that the Rosroe Formation records unroofing of a rapidly exhuming Dalradian metamorphic belt in North Mayo, following extensional collapse of the Grampian Orogen starting at ˜468 Ma, with minor input from a southerly arc source. The lack of metamorphic input from the S until deposition of the Derryeeny Conglomerate argues that the Connemara terrane was not positioned S of South Mayo Trough through strike-slip faulting until after the end of Rosroe sedimentation (460–443 Ma).

The causes of hydrothermal alteration in dolerite dykes intruding Caledonian rocks of W Connacht are investigated using stable isotope, water content and K–Ar data for whole rocks and mineral separates. Using an isochron approach the Logmór dyke in the north is re-dated to 308±4 Ma; previously determined older whole-rock ages reflect excess 40Ar. The ∼ 305 Ma age previously proposed for the Teach Dóite suite in the south is reinforced by a 305 Ma age on a pyroxene separate, although the severe resetting of most samples is emphasised by other pyroxene and plagioclase ages of ∼210 Ma. Pyroxene δ18O values for these Upper Carboniferous dykes are mostly 5·5 to 6·1%, indicating negligible crustal contamination. Logmór whole-rock samples have water contents of 1·7–2·1 wt.%, δ5D= 59 to –47‰ and δ18O = 9·4 to 9·6‰; plagioclase shows little mineralogical alteration but its δ18O is 9·7‰. Hydrothermal alteration involving a local formation or metamorphic water took place at high fluid/rock ratios and high temperature during cooling after intrusion, most probably in a thermally-driven convection system. Teach Dóite dykes have water contents of 2·0–4·2 wt.%. δD= –58 to –38‰ and δ18O = 3·6 to 9·2‰, and were mostly altered in two stages; hydration upon intrusion to ∼ 2 wt.% water by contemporaneous meteoric water at low fluid/rock ratios was followed by extensive chemical and isotopic alteration at ∼210 Ma (Upper Triassic) by surface waters. This latter event could also have caused the extensive alteration observed in the host rocks.

The Dalradian terrane of Connemara was thrust southsoutheastwards about 460 Ma ago (Rb–Sr and K–Ar ages). It rides on a major thrust of post-D age over mylonitised acidic volcanic rocks of putative lower Ordovician age and contains a number of thrusts of similar age. Several major S- to SE-directed thrusts also limit the southeastern margin of the Dalradian rocks in Mayo and Tyrone. It is suggested by analogy with Ireland that during mid-Ordovician times the Highland Boundary fault in Scotland could have been a thrust zone which carried the Scottish Dalradian rocks over a lower Ordovician basement now represented only as fragments in the Highland Border Complex.