Coal and hydrocarbons have been exploited from the Carboniferous rocks of the Midland Valley for over 200 years. This work characterises organic matter from the Mississippian black shales of the Midland Valley from Wardie, Scotland. Biomarker analysis allowed the estimation of the degree of microbial transformation of organic matter, type of kerogen and thermal maturity during hydrocarbon generation. Parameters based on the biomarker indicators confirm a generally mixed type II/III kerogen. However, some samples contain mostly terrestrial organic matter, whilst others contain predominantly marine organic matter, which shows that the sedimentary environment varied greatly throughout the basin. The presence of gammacerane suggests water column stratification and anoxic conditions. Organic matter was much better protected from post-depositional alteration within the concretions, where higher TOC (total organic carbon) and TS (total sulphur) contents occur, than in the surrounding sediments. This can be induced by very early diagenetic formation of these concretions which protected organic matter from late diagenetic degradation.

Estimated values of vitrinite reflectance (Rc, Rcs) show that the sedimentary rocks reached the catagenesis stage. Most samples exhibit maximum organic matter maturation temperatures of around c60–90°C. However, stable isomers of phenyldibenzo[b,d]thiophene detected in some samples indicate that in some cases post-depositional hydrothermal activity affected maturation of organic matter increasing temperatures to as high as c174°C.

The development of the Midland Valley of Scotland from Silurian times is re-examined. Earlier (Cambro-Ordovician) terrane accretion of the Midland Valley Terrane to the Laurentian continent by sinistral strike-slip continued to control basin development, sedimentary facies distribution and deformation from Llandovery through to at least early Devonian times. A widespread Mid- to Late-Wenlock strike-slip event has been recognised. This event is variable in its effect, but may indicate a direct link between the Midland Valley, Southern Uplands and Grampian terranes, suggesting that the terranes were juxtaposed by Mid-Wenlock times. In the Midland Valley this event was followed by a renewed phase of basin development with the deposition of ?Pridoli-Lower Devonian clastic sediments which was interrupted by the Lower Devonian volcanic event. There was a shift northwards in the focus of Lower Devonian basin development which was accompanied by a diachronous deformation event across the Midland Valley which resulted in inversion/uplift from early to middle Devonian times. This phase of deformation, uplift and erosion may be related to end-Caledonian transpression.

In the early Carboniferous, the portion of continental crust that now constitutes Scotland lay within the hinterland of a large continent that extended westwards to what is now the western parts of North America, eastwards to what is now the Urals and northwards towards what is now Arctic Canada, Greenland, Scandinavia and Russia. Open ocean probably lay at between 600 and 1000 km to the south. Whereas mountainous terrane lay to the north of the Highland Boundary fault, the Scottish Midland Valley, like the Northumberland Trough further south, was a region of low relief subject to periodic marine incursions.

A period of block faulting and concomitant basaltic volcanism commenced at the beginning of the Carboniferous at c. 350 Ma. This had manifestations in various regions of the British Isles from the south-west of England to the west of Ireland and as far north as the Midland Valley (Francis 1978, 1991; Upton 1982; Cameron and Stephenson 1985).

The southern Bathgate Hills, in the eastern part of the Midland Valley basin of Scotland, were the site of a volcanic rise during late Dinantian to early Silesian times and a sequence of basaltic lavas and tuffs up to 600 m thick accumulated. The volcanic pile interrupted the regional sedimentary deposition, which involved a cyclical sequence of marine limestones and mudstones followed by estuarine, lagoonal and deltaic clastic deposits. During the Brigantian Stage of the Dinantian, freshwater terrestrial environments developed locally on the volcanic rise between eruptive phases, but later in the Brigantian the rise was transgressed by marine limestones. Intermittent basaltic eruptions continued into the Amsbergian Stage of the Silesian, accompanied by intrusion of high-level alkaline doleritic sills and associated with strata-bound Zn—Pb mineralisation. Folding later in the Silesian was followed by the intrusion of a suite of quartz-dolerite sills and dykes. These latter were commonly intruded along penecontemporaneous E—W trending faults. The intrusion of the quartz-dolerites may have resulted in remobilisation of earlier strata-bound mineralisation into epigenetic veins.

The Notre Dame and Exploits subzones of Newfoundland's Dunnage Zone are correlated with the Midland Valley and Southern Uplands of Scotland, using detailed comparisons of two key Lower Palaeozoic successions which record similar histories of extension and compression. It follows that the Baie Verte Line, Red Indian Line and Dover Fault are equivalent to the Highland Boundary Fault, Southern Upland Fault and Solway Line, respectively.

The Betts Cove Complex and overlying Snooks Arm Group of the Notre Dame Subzone are analogous to the Ballantrae Complex of the Midland Valley, both recording the Arenig evolution and subsequent obduction of an arc and back-arc system. The Early Ordovician to Silurian sequence unconformably overlying the Ballantrae Complex is poorly represented in the Notre Dame Subzone but important similarities can still be detected suggesting corresponding histories of continental margin subsidence and marine transgression.

In the Exploits Subzone, Early Ordovician back-arc volcanic rocks are overlain by Llandeilo mudstones and Late Ordovician to Early Silurian turbidites. A similar stratigraphy occurs in the Northern and Central Belts of the Southern Uplands and both areas have matching transpressive structural histories. Deeper erosion in the Exploits Subzone reveals Cambrian and Early Ordovician volcano-sedimentary sequences structurally emplaced on the Gander Zone, and such rocks are probably present beneath the Southern Uplands. Combined data from the Notre Dame Subzone and Midland Valley suggest an Arenig southeast-dipping subduction zone. Early Ordovician volcanic rocks in the Exploits Subzone and Southern Uplands have back-arc basin geochemistry and support the model of the Southern Uplands as a transition from back-arc to foreland basin. Preferential emergence of the Dunnage Zone and contrasts between Exploits Subzone and Southern Uplands turbidite basins are attributed to collision of Newfoundland with a Laurentian promontory and Scotland with a re-entrant. This hypothesis also explains the transpressive structural regime common to both areas.

The sediments on the floors of nine reservoirs in the Midland Valley of Scotland have been examined to establish rates of sedimentation and catchment sediment yields. Information from Cullaloe, Drumain, Harperleas and Lambieletham Reservoirs (Fife), is compared with data from Glenfarg and Glenquey Reservoirs (Tayside) and earlier studies on Hopes, N Esk (Lothian) and Kelly (Strathclyde) Reservoirs. The earth-fill dams were constructed between 1850 and 1935 below catchments ranging from 1·53 to 23·5 km2 in area. They are situated on sedimentary, volcanic or intrusive igneous rocks mainly of Devonian or Carboniferous age. In most areas bedrock is obscured by mantles of drift. Six of the catchments are dominated by moorland terrain with local afforestation. Mixed arable farming and woodland characterise the remainder. The higher basins receive on average over 1400 mm of precipitation per annum, while in the lower basins some 800 mm falls.

Measurements of thickness variations of the deposits have enabled the construction of isopachyte maps from which the volumes of entrapped materials have been derived. The computed catchment sediment yields vary from 2·l t km−2 yr−1 (Lambieletham) to 52·0 t km−2 yr−1 (Glenfarg). Sediments incorporate both mineral and organic matter, of which combustible material commonly forms 15–20% by weight. Siliceous tests of diatoms are also an important component of the deposits. The sediment yields computed are about an order of magnitude greater than those reported from rivers draining similar sizes of catchment within the Forth basin. There is a direct relationship between mean annual inflow to the reservoirs and sediment yield.

A diverse, but sparsely distributed silicified fauna of over 30 taxa has been recovered from 7·5 tonnes of acid-etched Lower Ordovician Dounans Limestone from the Highland Border Complex, near Aberfoyle. The 13 trilobite taxa obtained include 3 new formally named species: Distazeris adoceta, Punka aetholiciocorus and Ischyrotoma stubblefieldi. Other elements, representing Carolinites, Illaenus, Goniotelina, Sycophantia, Kawina, Heliomeroides, Strotactinus, Ectenonotus, Ceratocephala and an indeterminate bathyurelline are described under open nomenclature although at least 4 are also probably new and 2 more may be conspecific with previously described species. The brachiopods include representatives of Archaeorthis, Nothorthis, Orthidium, ?Camerella, Idiostrophia, Orthambonites and 4 other indeterminate stocks. Gastropods tentatively assigned to Murchisonia, Subulites, Straparollina, Maclurites and Cyrtodiscus are described, as are bryozoans, an orthocone, crinoids, and Incertae sedis.

This profoundly North American fauna is Late Canadian ( = mid Arenig) in age and equates with the Cassinian Stage: it is key evidence in showing that the Highland Border rocks are not part of the Dalradian Supergroup whose earliest deformations and metamorphism predate the Ordovician. The field relationships of the limestone, together with evidence from derived clasts in Middle Ordovician and Devonian sequences near Girvan in SW Scotland and at Stonehaven in eastern Scotland suggest that it forms part of a widespread sub-Old Red Sandstone carbonate sequence of Early Ordovician age beneath the northern Midland Valley.

Old Red Sandstone sediments from Arran in western Scotland yield an array of Pb isotope compositions whose slope corresponds to an age of 1830 ± 400 Ma. These compositions are not consistent with a significant contribution of material from the Southern Highlands, Midland Valley, or Southern Uplands, but are similar to the Torridonian sandstones of NW Scotland. Bearing in mind the probable Laxfordian provenance of the Torridonian assemblage, this points to a source for the Old Red Sandstone in a crustal block of early Proterozoic age corresponding to the age of the Laxfordian episode. Since such a source is not presently in a position to yield the Old Red Sandstone, strike-slip movement along the Highland Boundary fault is a strong possibility.