Most theoretical descriptions of stresses induced by freezing are rooted in the (generalized) Clapeyron equation, which predicts the pressure that a solid can exert as it cools below its melting temperature. This equation is central for topics ranging beyond glaciology to geomorphology, civil engineering, food storage and cryopreservation. However, it has inherent limitations, requiring isotropic solid stresses and conditions near bulk equilibrium. Here, we examine when the Clapeyron equation is applicable by providing a rigorous derivation that details all assumptions. We demonstrate the natural extension for anisotropic stress states, and we show how the temperature and pressure ranges for validity depend on well-defined material properties. Finally, we demonstrate how the range of applicability of the (linear) Clapeyron equation can be extended by adding higher-order terms, yielding results that are in good agreement with experimental data for the pressure melting of ice.

Raman spectra (532 nm diode laser) of gypsum, syngenite and görgeyite powders were studied from 273 to 83 K every −10 K. Although it was found that not all the Raman peaks are temperature-sensitive, the effect of temperature on the Raman signal of some bands was modelled. It was observed that the main bands of the three sulfates shift toward higher wavenumbers as temperature decreases. The strengthening of the bonds causes an increase in energy and, consequently, higher wavenumbers. However, –OH bands shift depending on the crystal structure they acquire as the temperature decreases, so not all –OH bands behave in the same way. Finally, the gypsum –OH bands change to more ordered crystalline structures with decreasing temperature, so their bandwidths become narrower and sharper.

The Late Pleistocene surface paleohydrography of the New Jersey Pine Barrens consisted of a series of broad braided alluvial surfaces with meandering paleochannels. This drainage is best explained in terms of impermeable (i.e. frozen) substrate, high sediment load, variable or decreasing discharge, and eolian sedimentary dynamics. Evidence for eolian activity is provided by wind-abraded sand grains, coversand, dunes, ventifacts, deflation hollows and wind-polished boulders. In several places stream avulsion occurred due to channel infilling by locally-derived wind-blown sediment. The braided and meandering river systems that characterise the tundra and polar semi-desert lowlands of the Western Canadian Arctic are described as modern analogs.