In this paper, our main aim is to discuss the properties of harmonic mappings in the unit ball 𝔹n. First, we characterize the harmonic Bloch spaces and the little harmonic Bloch spaces from 𝔹n to ℂ in terms of weighted Lipschitz functions. Then we prove the existence of a Landau–Bloch constant for a class of vector-valued harmonic Bloch mappings from 𝔹n to ℂn.