The interaction of focused high power laser beam with solid targets leads to acceleration of charged particles among other by non-linear effects in the plasma. In this experiment, the hot electrons are characterized from the interaction of sub-nanosecond and kilo-joule class laser pulse with thin metal foil targets (Cu, Ta, Ti, Sn, Pb). The energy distribution functions of electrons were measured by angularly resolved multichannel electron spectrometer. The hot electron temperatures were observed in range from 30 to 80 keV for laser intensities between ${\sim}10^{15}$ and $3 \times 10^{16}\ \mathrm{W\,cm^{-2}}$. The measured energy distribution and electron temperature were compared with published results and known scaling laws at higher laser intensities. For foil targets of different materials, the temperature and flux of hot electrons were scaled with target thickness in the range of 1–100 $\unicode{x03BC}\mathrm{m}$ from low Z to high Z materials where Z is the atomic number. The profile of conversion efficiency from laser energy to hot electrons is discussed in the energy range from 100 to 600 J. For the given laser and target parameters, the nonlinear behaviour of conversion efficiency and relevant physics are also described in detail.