The new mineral naalasite (IMA2023–027), NaAl(AsO3OH)2⋅H2O, was found at the Torrecillas mine, Iquique Province, Chile, where it is a secondary alteration phase associated with anhydrite, juansilvaite, magnesiokoritnigite and a lavendulan-like phase. Naalasite occurs in tightly intergrown aggregates and druses of equant crystals. Crystals are light to medium pink and transparent, with vitreous lustre and white streak. The Mohs hardness is ~3½. The density is 3.19(2) g⋅cm–3. Optically, naalasite is uniaxial (+), with ω = 1.630(3) and ɛ = 1.660(3) (white light). The empirical formula (based on 9 O apfu) is Na0.92Al0.61Fe3+0.39As2O9H4.07. Naalasite is trigonal, space group R32, with cell parameters: a = 8.494(4), c = 26.430(13) Å, V = 1651.5(4) Å3 and Z = 9. The structure, refined to R1 = 3.78% for 641 I > 2σI reflections, is based on a loose 3D framework of alternating AsO3OH tetrahedra and AlO6 octahedra. The structure is topologically equivalent to that of nafeasite and can be regarded as its Al analogue, even though nafeasite is monoclinic with space group C2.

The new mineral nafeasite (IMA2021-103), NaFe3+(AsO3OH)2⋅H2O, was found at the Torrecillas mine, Iquique Province, Chile, where it is a secondary alteration phase associated with anhydrite, gypsum, halite, lavendulan, magnesiokoritnigite and natrojarosite. Nafeasite occurs in tightly intergrown aggregates of equant crystals. Crystals are light to medium pink and transparent, with vitreous lustre and white streak. The Mohs hardness is ~2½. The density is 3.23(2) g⋅cm–3. Optically, nafeasite is biaxial (+), with α = 1.679(3), β = 1.682(3), γ = 1.730(5) (white light); 2V = 27(2)°; and slight r < v dispersion. The empirical formulae of the holotype and cotype (based on 9 O atoms per formula unit) are Na0.98K0.02Fe0.92Al0.07As2.00O9H4.01 and Na0.97Fe0.68Al0.33As2.00O9H4.01, respectively. Nafeasite is monoclinic, space group C2, with cell parameters: a = 18.6876(16), b = 8.6769(7), c = 14.8100(10) Å, β = 105.238 (5)°, V = 2317.0(3) Å3 and Z = 12. The structure, refined to R1 = 5.03% for 5979 Io > 2σI reflections, is based on a loose 3D framework of alternating AsO3OH tetrahedra and Fe3+O6 octahedra.