We study the interplay between stellar population of the Brightest Cluster Galaxies (BCG) and cluster global properties. We use X-ray properties from Chandra, ROSAT and ASCA observations and BCGs spectra from SDSS-DR6. Using STARLIGHT we determined the star formation history of the BCGs and look for relations with the intra-cluster gas properties. Our first results show no correlation between the recent star formation with x-ray temperature and dynamic state. An important star formation is happening in cool-core Cluster. This new stellar population has low metallicity, pointing to an external source of cold gas to form stars.