Published online by Cambridge University Press: 05 December 2011
The very beautiful experiment in question, described by C. Christiansen in Wiedemann's Annalen for November 1884, consists in immersing glass-power in a mixture of benzole and bisulphide of carbon of such proportions that for one part of the spectrum the indices of the solid and of the fluid are the same. Being interested in this subject from having employed the same principle for a direct-vision spectroscope (Phil. Mag. January 1880, p. 53) [vol. I. p. 456], I have repeated Christiansen's experiment in a somewhat improved form, which it may be worth while briefly to describe, as the matter is one of great optical interest.
I must premise that the beauty of the effect depends upon the correspondence of index being limited to one part of the spectrum. Rays lying within a very narrow range of refrangibility traverse the mixture freely, but the neighbouring rays are scattered laterally, much as in passing ground glass. Two complementary colours are therefore exhibited, one by direct, and the other by oblique, light. In order to see these to advantage, there should not be much diffused illumination; otherwise the directly transmitted monochromatic light is liable to be greatly diluted. The prettiest colours are obtained when the undisturbed rays are from the green; but the greatest general transparency corresponds to a lower point in the spectrum.
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