Assume that x∈[0,1) admits its continued fraction expansion x=[a1(x),a2(x),…]. The Khintchine exponent γ(x) of x is defined by when the limit exists. The Khintchine spectrum dim Eξ is studied in detail, where Eξ:={x∈[0,1):γ(x)=ξ}(ξ≥0) and dim denotes the Hausdorff dimension. In particular, we prove the remarkable fact that the Khintchine spectrum dim Eξ, as a function of , is neither concave nor convex. This is a new phenomenon from the usual point of view of multifractal analysis. Fast Khintchine exponents defined by are also studied, where φ(n) tends to infinity faster than n does. Under some regular conditions on φ, it is proved that the fast Khintchine spectrum dim ({x∈[0,1]:γφ(x)=ξ}) is a constant function. Our method also works for other spectra such as the Lyapunov spectrum and the fast Lyapunov spectrum.