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Preparation and characterization of nanocrystalline PbSe in poly(acrylic acid-co-styrene)

Published online by Cambridge University Press:  31 January 2011

Yangyang Sun ,
Xuefeng Qian ,
Jie Yin ,
Junchao Huang ,
Xiaodong Ma  and
Zikang Zhu
Yangyang Sun
Affiliation:
Research Institute of Polymer Materials, School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai, 200240, People's Republic of China
Xuefeng Qian
Affiliation:
Research Institute of Polymer Materials, School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai, 200240, People's Republic of China
Jie Yin
Affiliation:
Research Institute of Polymer Materials, School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai, 200240, People's Republic of China
Junchao Huang
Affiliation:
Research Institute of Polymer Materials, School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai, 200240, People's Republic of China
Xiaodong Ma
Affiliation:
Research Institute of Polymer Materials, School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai, 200240, People's Republic of China
Zikang Zhu*
Affiliation:
Research Institute of Polymer Materials, School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai, 200240, People's Republic of China
*
a)Address all correspondence to this author.xfqian@mail.sjtu.edu.cn
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Abstract

The in situ reduction method was used to prepare nanocrystalline PbSe in a poly(acrylic acid-co-styrene) matrix. Metal precursor-doped polymer film was treated with selenium and reducing reagent (NaBH4) in ethylenediamine, leading to the formation of assemblies of crystalline semiconductive PbSe in polymer. The preparation was done at room temperature and ambient pressure. X-ray diffraction, x-ray photoelectron spectroscopy, infrared, scanning electron microscopy, transmission electron microscopy, and ultraviolet-visible spectra were used to characterize the as-prepared materials. The key factor for successful preparation of this composite was also discussed.

Type
Articles
Information
Journal of Materials Research , Volume 16 , Issue 10 , October 2001 , pp. 2922 - 2927
Copyright
Copyright © Materials Research Society 2001

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