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In situ trace elements and S isotope systematics for growth zoning in sphalerite from MVT deposits: A case study of Nayongzhi, South China

Published online by Cambridge University Press:  26 March 2021

Chen Wei ,
Lin Ye ,
Zhilong Huang ,
Yusi Hu  and
Haoyu Wang
Chen Wei
Affiliation:
State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang550081, China University of Chinese Academy of Sciences, Beijing, 100049, China
Lin Ye*
Affiliation:
State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang550081, China
Zhilong Huang
Affiliation:
State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang550081, China
Yusi Hu*
Affiliation:
State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang550081, China University of Chinese Academy of Sciences, Beijing, 100049, China
Haoyu Wang
Affiliation:
State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang550081, China University of Chinese Academy of Sciences, Beijing, 100049, China
*
*Authors for correspondence: Lin Ye, Email: yelin@vip.gyig.ac.cn; Yusi Hu, Email: huyusi@mail.gyig.ac.cn
*Authors for correspondence: Lin Ye, Email: yelin@vip.gyig.ac.cn; Yusi Hu, Email: huyusi@mail.gyig.ac.cn
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Abstract

Zoning texture in sphalerite has been described in many studies, although its genesis and ore formation process are poorly constrained. In this investigation, we compare the in situ trace element and isotopic composition of colour-zoned sphalerites from Nayongzhi, South China, to explain the zoning growth process. Petrographic observations identified two broad types of zoned sphalerite, core–rim (CR) and core–mantle–rim (CMR) textures. Each zoned sphalerite displays two or three colour zones, including brown core, light colour bands and/or pale-yellow zones. In situ laser ablation inductively coupled plasma mass spectrometry trace-element analyses show that the three colour zones display variable trace-element compositions. Brown cores exhibit distinctly high Mn, Fe, Co, Ge, Tl and Pb concentrations, whereas pale-yellow and light colour zones have elevated Ga, Cd, Sn, In and Sb concentrations. Copper, Sb, In and Sn show slight variations between pale-yellow and light zones, the latter having higher In and Sn, but lower Cu and Sb abundances. Given the low concentration range of Pb, Ge, Tl, Mn Sb, Cd, etc., the colour of sphalerite is attributed mainly to Fe compositional variation. The δ34S values of sphalerite from Nayongzhi range from +22.3 to +27.9‰, suggesting reduced sulfur was generated by thermochemical sulfate reduction of marine sulfate in ore-hosted strata. Single-crystal colour-zoned sphalerite exhibits intracrystalline δ34S variation (up to 4.3‰), which is attributed to the δ34S composition of H2S in the original fluid. The lack of correlation between trace elements and δ34S values indicates episodic ore solution influxes and mixes with the reduced sulfur-rich fluid derived from the aquifers of the ore-hosted strata, which play a key role in the formation of the zoned Nayongzhi sphalerite. In conclusion, in situ trace element and S isotope studies of zoned sphalerite crystals might provide insight into the ore-forming process of MVT deposits.

Keywords

sphaleriteLA-(MC)-ICP-MStrace elementsin situ S isotopeTEMgrowth mechanism
Type
Article
Information
Mineralogical Magazine , Volume 85 , Issue 3 , June 2021 , pp. 364 - 378
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Jason Harvey

References

Barrie, C.D., Boyce, A.J., Boyle, A.P., Williams, P.J., Blake, K., Wilkinson, J.J., Lowther, M., McDermott, P. and Prior, D.J. (2009) On the growth of colloform textures: A case study of sphalerite from the Galmoy orebody, Ireland. Journal of the Geological Society, 166, 563–582.CrossRefGoogle Scholar
Barton, Jr P.B., Bethke, P.M. and Roedder, E. (1977) Environment of ore deposition in the Creede Mining district, San Juan Mountains, Colourado: Part III. Progress toward interpretation of the chemistry of the ore-forming fluid for the OH Vein. Economic Geology, 72, 1–24.Google Scholar
Beaudoin, G. (2000) Acicular sphalerite enriched in Ag, Sb, and Cu embedded within colour banded sphalerite from the Kokanee Range, BC. The Canadian Mineralogist, 38, 1387–1398.CrossRefGoogle Scholar
Belissont, R., Boiron, M.C., Luais, B. and Cathelineau, M. (2014) LA-ICP-MS analyses of minor and trace elements and bulk Ge isotopes in zoned Ge-rich sphalerites from the Noailhac-Saint-Salvy deposit (France): insights into incorporation mechanisms and ore deposition processes. Geochimica et Cosmochimica Acta, 126, 518–540.CrossRefGoogle Scholar
Chen, L., Chen, K., Bao, Z., Liang, P., Sun, T. and Yuan, H. (2017) Preparation of standards for in situ sulfur isotope measurement in sulfides using femtosecond laser ablation MC-ICP-MS. Journal of Analytical Atomic Spectrometry, 32, 107–116.CrossRefGoogle Scholar
CIGMR (2003) Geology map of the Yunnan-Guizhou-Sichuan-Chongqing provinces, scale 1:2,500,000. Chengdu Institute of Geology and Mineral Resources (CIGMR), China.Google Scholar
Claypool, G.E., Holser, W.T., Kaplan, I.R., Sakai, H. and Zak, I. (1980) The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation. Chemical Geology, 28, 199–260.CrossRefGoogle Scholar
Cook, N.J., Ciobanu, C.L., Pring, A., Skinner, W., Shimizu, M., Danyushevsky, L., Saini-Eidukat, B. and Melcher, F. (2009) Trace and minor elements in sphalerite: A LA-ICP-MS study. Geochimica et Cosmochimica Acta, 73, 4761–4791.10.1016/j.gca.2009.05.045CrossRefGoogle Scholar
Cook, N.J., Sundblad, K., Valkama, M., Nygård, R., Ciobanu, C.L. and Danyushevsky, L. (2011) Indium mineralisation in A-type granites in southeastern Finland: insights into mineralogy and partitioning between coexisting minerals. Chemical Geology, 284, 62–73.CrossRefGoogle Scholar
Danyushevsky, L., Robinson, P., Gilbert, S., Norman, M., Large, R., McGoldrick, P. and Shelley, M. (2011) Routine quantitative multi-element analysis of sulphide minerals by laser ablation ICP-MS: standard development and consideration of matrix effects. Geochemistry: Exploration, Environment, Analysis, 11, 51–60.Google Scholar
Deloule, E., Allegre, C., Doe, B. (1986) Lead and sulfur isotope microstratigraphy in galena crystals from Mississippi Valley-type Deposits. Economic Geology, 81, 1307–1321CrossRefGoogle Scholar
Di Benedetto, F., Bernardini, G.P., Costagliola, P., Plant, D. and Vaughan, D.J. (2005) Compositional zoning in sphalerite crystals. American Mineralogist, 90, 1384–1392.CrossRefGoogle Scholar
Fowler, D.A. and L'Heureux, I. (1996) Self-organized banded sphalerite and branching galena in the Pine Point ore deposit, Northwest Territories. The Canadian Mineralogist, 34, 1211–1222Google Scholar
Frenzel, M., Mikolajczak, C., Reute, M.A. and Gutzmer, J. (2017) Quantifying the relative availability of high-tech by-product metals–the cases of gallium, germanium and indium. Resource Policy, 52, 327–335CrossRefGoogle Scholar
Gagnevin, D., Menuge, J. F., Kronz, A., Barrie, C. and Boyce, A.J. (2012) Minor elements in layered sphalerite as a record of fluid origin, mixing, and crystallisation in the Navan Zn–Pb ore deposit, Ireland. Economic Geology, 109, 1513–1528.10.2113/econgeo.109.6.1513CrossRefGoogle Scholar
Goldhaber, M. B. and Kaplan, I. R. (1975) Controls and consequences of sulfate reduction rates in recent marine sediments. Soil Science, 119, 42–55.CrossRefGoogle Scholar
Hill, G. S., Rowlands, N. and Finch, J. (1985) Correlation between colour and iron content in Pine Point sphalerites. Economic Geology, 80, 2035–2037.CrossRefGoogle Scholar
Höll, R., Kling, M. and Schroll, E. (2007) Metallogenesis of germanium – a review. Ore Geology Reviews, 30, 145–180.10.1016/j.oregeorev.2005.07.034CrossRefGoogle Scholar
Holten, T., Jamtveit, B., Meakin, P., Cortini, M., Blundy, J. and Austrheim, H. (1997) Statistical characteristics and origin of oscillatory zoning in crystals. American Mineralogist, 82, 596–60610.2138/am-1997-5-619CrossRefGoogle Scholar
Holten, T., Jamtveit, B. and Meakin, P. (2000) Noise and oscillatory zoning of minerals. Geochimica et Cosmochimica Acta, 11, 1893–1904.10.1016/S0016-7037(99)00444-5CrossRefGoogle Scholar
Hu, Y. S., Ye, L., Wei, C., Li Z. L Huang Z. L. and Wang H. Y. (2020) Trace Elements in Sphalerite from the Dadongla Zn–Pb Deposit, Western Hunan–Eastern Guizhou Zn–Pb Metallogenic Belt, South China. Acta Geologica Sinica (English Edition), 94, 2152–2164Google Scholar
Jin, Z.G., Zhou, J.X., Huang, Z.L., Luo, K., Gao, J.G., Peng, S., Wang, B. and Chen, X.L. (2016) Ore genesis of the Nayongzhi Pb-Zn deposit, Puding city, Guizhou Province, China: Evidences from S and in situ Pb isotopes. Acta Petrologica Sinica, 32, 3441–3455 [in Chinese with English Abstract].Google Scholar
Kelley, K.D., Leach, D.L., Johnson, C.A., Clark, J.L., Fayek, M., Slack, J.F., Anderson, V.M., Ayuso, R.A. and Ridley, W.I. (2004) Textural, compositional, and sulfur isotope variations of sulfide minerals in the Red Dog Zn–Pb-Ag deposits, Brooks Range, Alaska: Implications for ore formation. Economic Geology, 99, 1509–153210.2113/gsecongeo.99.7.1509CrossRefGoogle Scholar
Kuhlemann, J. and Zeeh, S. (1995) Sphalerite stratigraphy and trace element composition of east Alpine Pb-Zn deposits (Drau Range, Austria-Slovenia). Economic Geology, 90, 2073–2080.CrossRefGoogle Scholar
Large, R.R., Danyushevsky, L., Hollit, C., Maslennikov, V., Meffre, S., Gilbert, S., Bull, S., Scott, R., Embsbo, P., Thomas, H., Singh, B. and Foster, J. (2009) Gold and trace element zonation in pyrite using a laser imaging technique: Implications for the timing of gold in orogenic and Carlin style sediment-hosted deposits. Economic Geology, 104, 635–668.10.2113/gsecongeo.104.5.635CrossRefGoogle Scholar
Leach, D.L., Sangster, D., Kelley, K.D., Large, R.R., Garven, G., Allen, C., Gutzmer, J. and Walters, S. (2005) Sediment-hosted lead-zinc deposits: A global perspective. Economic Geology 100th Anniversary, 561–607.Google Scholar
L'Heureux, I. (2000) Origin of banded patterns in natural sphalerite. Physical Review, E62, 3234–3245.Google Scholar
Longerich, H.P., Jackson, S.E. and Gunther, D. (1996) Laser ablation inductively coupled plasma mass spectrometric transient signal data acquisition and analyte concentration calculation. Journal of Analytical Atomic Spectrometry, 11, 899–904.CrossRefGoogle Scholar
McLimans, R.K., Barnes, H.L. and Ohmoto, H. (1980) Sphalerite stratigraphy of the upper Mississippi Valley zinc-lead district, southwest Wisconsin. Economic Geology, 75, 351–361.CrossRefGoogle Scholar
Ohmoto, H. (1972) Systematics of sulfur and carbon isotopes in hydrothermal ore deposits. Economic Geology, 67, 551–578.CrossRefGoogle Scholar
Paton, C., Hellstrom, J., Paul, B., Woodhead, J. and Hergt, J. (2011) Iolite: Freeware for the visualisation and processing of mass spectrometric data. Journal of Analytical Atomic Spectrometry, 26, 2508–2518.CrossRefGoogle Scholar
Pattrick, R.A.D., Dorling, M. and Polya, D.A. (1993) TEM study of indium bearing and copper-bearing growth-banded sphalerite. The Canadian Mineralogist, 31, 105–117.Google Scholar
Pfaff, K., Hildebrandt, L.H., Leach, D.L., Jacob, D.E. and Markl, G. (2010) Formation of the Wiesloch Mississippi Valley-type Zn–Pb–Ag deposit in the extensional setting of the Upper Rhinegraben, SW Germany. Mineralium Deposita, 45, 647–666.CrossRefGoogle Scholar
Pfaff, K., Koenig, A., Wenzel, T., Ridley, I., Hildebrandt, L.H., Leach, D.L. and Markl, G. (2011) Trace and minor element variations and sulfur isotopes in crystalline and colloform ZnS: Incorporation mechanisms and implications for their genesis. Chemical Geology, 286, 118–134.Google Scholar
Roedder, E. (1968). Noncolloidal origin of colloform textures in sphalerite ores. Economic Geology, 63, 451–471.10.2113/gsecongeo.63.5.451CrossRefGoogle Scholar
Roedder, E. and Dwornik, E.J. (1968). Sphalerite colour banding: Lack of correlation with iron content, Pine Point, Northwest Territories, Canada. American Mineralogist, 53, 1523–1529.Google Scholar
Sasaki, A. and Krouse, H.R. (1969) Sulfur isotopes and the Pine Point lead–zinc mineralization. Economic Geology, 64, 718–730.CrossRefGoogle Scholar
Seal, I.R. (2006) Sulfur isotope geochemistry of sulfide minerals. Pp. 633–677 in: Sulfide Mineralogy and Geochemistry (Vaughan, D.J., editor). Reviews in Mineralogy and Geochemistry, 61. Mineralogical Society of America and the Geochemical Society, Chantilly, Virginia, USA.10.1515/9781501509490-013CrossRefGoogle Scholar
Slack, G.A., Roberts, S., Ham, F.S. (1967) Far-infrared optical absorption of Fe2+ in ZnS. Physical Reviews, 155, 170–177.10.1103/PhysRev.155.170CrossRefGoogle Scholar
Sverjensky, D.A. (1984) Oil field brines as ore-forming solutions. Economic Geology, 79, 23–37.CrossRefGoogle Scholar
Vaughan, D.J. and Craig, J.R. (1997) Sulfide mineral stabilities, morphologies, and intergrowth texture. Pp. 367–434 in: Geochemistry of Hydrothermal Ore Deposits—Third Edition (Barnes, H.L., editor). John Wiley, New York.Google Scholar
Viets, J.G., Hopkins, R.T. and Miller, B.M. (1992) Variations in minor and trace-metals in sphalerite from Mississippi Valley-type deposits of the Ozark Region: Genetic implications. Economic Geology, 87, 1897–1905.CrossRefGoogle Scholar
Wei, C. (2018) Ore-Forming Fluid and Ore Genesis of The Nayongzhi Deposit in Northwestern Guizhou, China. A Thesis Submitted to University of Chinese Academy of Sciences, 106 pp [in Chinese with English abstract].Google Scholar
Wei, C., Huang, ZL., Yan, Z.F., Hu, Y.S. and Ye, L. (2018a) Trace element contents in Sphalerite from the Nayongzhi Zn–Pb deposit, Northwestern Guizhou, China: Insights into incorporation mechanisms, metallogenic temperature and ore genesis. Minerals, 8, 490.10.3390/min8110490CrossRefGoogle Scholar
Wei, C., Yan, Z.F., Huang, Z.L. and Hu, Y.S. (2018b) Geochemical characteristics of the hydrothermal dolomite from the Nayongzhi deposit, Northwestern Guizhou, China and their prospecting indication. Acta Mineralogica Sinica, 38, 666–674 [in Chinese with English abstract].Google Scholar
Wei, C., Ye, L., Huang, Z.L., Hu, Y.S. and Wang, H.Y. (2020) New advances in the study of Pb-Zn deposits in the Wuzhishan district of northwest Guizhou: Enlightenment on the attribution of metallogenic belt. Acta Mineralogica Sinica, 40, 394–403 [in Chinese with English abstract].Google Scholar
Zhou, J.X., Wang, X.C., Wilde, S.A., Luo, K., Huang, Z.L., Wu, T. and Jin, Z.G. (2018) New insights into the metallogeny of MVT Zn–Pb deposits: A case study from the Nayongzhi in South China, using field data, fluid compositions, and in situ S-Pb isotopes. American Mineralogist, 103, 91–108.CrossRefGoogle Scholar
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