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XPS Studies of Chromium Atoms Interacting with a PMDA-ODA Polyimide Surface

Published online by Cambridge University Press:  21 February 2011

R. Haight ,
B. D. Silverman ,
R. C. White ,
P. S. Ho  and
A. R. Rossi
R. Haight
Affiliation:
IBM Research Division T.J. Watson Research Center Yorktown Heights, NY 10598
B. D. Silverman
Affiliation:
IBM Research Division T.J. Watson Research Center Yorktown Heights, NY 10598
R. C. White
Affiliation:
IBM Research Division T.J. Watson Research Center Yorktown Heights, NY 10598
P. S. Ho
Affiliation:
IBM Research Division T.J. Watson Research Center Yorktown Heights, NY 10598
A. R. Rossi
Affiliation:
IBM Research Division T.J. Watson Research Center Yorktown Heights, NY 10598
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Abstract

XPS data obtained during the initial stages of vapor deposition of chromium atoms onto a PMDA-ODA polyimide substrate is presented. Utilizing the results of molecular orbital calculations it is emphasized that the data is consistent with the formation of a charge transfer complex between the deposited metal atoms and the PMDA unit of the polymer.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 108 , 1987 , 233
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

1.Chou, N.J. and Tang, C.H., J. Vac. Sci. and Technol. A2, 751 (1984).Google Scholar
2.Ho, P.S., Hahn, P.O., Bartha, J.W., Rubloff, G.W., LeGoues, F.K., and Silverman, B.D., J. Vac. Sci. and Technol. A3, 739, (1985).Google Scholar
3.Bartha, J.W., Hahn, P.O., Legoues, F.K., and Ho, P.S., J. Vac. Sci. and Technol. A3, 1390, 1985.Google Scholar
4.Sanda, P.N., Bartha, J.W., Clabes, J.G., Jordan, J.L., Feger, C., Silverman, B.D. and Ho, P.S., J. Vac. Sci. and Technol. A4, 1035, 1986.Google Scholar
5.Jordan, J.L., Sanda, P.N., Morar, J.F., Kovac, C.A., Himpsel, F.J., Pollack, R.A., J. Vac. Sci. and Technol. A4, 1046, 1986.Google Scholar
6.White, R.C., Haight, R., Silverman, B.D. and Ho, P.S., Appl. Phys. Lett., 51, 481, 1987.Google Scholar
7.Takahashi, N., Yoon, D.Y. and Parrish, W., Macromolecules, 17, 2583, 1984.Google Scholar
8.Kramer, E.J., Volksen, W., and Russell, T.P., Mater. Res. Soc. Symp. Proc., 72, 195, 1986.Google Scholar
9.Timms, P.L., Proc. R. Soc. Lond, A396, 1, 1984.Google Scholar
10.Andrews, M.P., Mattar, S.M. and Ozim, G.A., J. Phys. Chem., 90, 744, 1986.Google Scholar
11.Rossi, A.R., Sanda, P.N., Silverman, B.D. and Ho, P.S., OrganometaUics, 6, 580, 1987.Google Scholar
12.Dupuis, M., Spangler, D. and Wendelowski, J.J., NRCC Software Catalogue, Program QG01, Vol.1, 1980.Google Scholar
13.Dobbs, K.D. and Hehre, W. J., Journ. of Comp. Chem., 8, 861, 1987.Google Scholar
14.Buchwalter, L.P. and Baise, A.I., in Polyimides: Synthesis, Characterization and Applications, Mittal, K.L., Ed., Plenum, New York, 1984, Vol.1, p.537.Google Scholar
15.Silverman, B.D., Sanda, P.N., Ho, P.S. and Rossi, A.R., J. Polym. Sci., Polym. Chem. Ed., 23, 2857, 1985.Google Scholar
16.Haight, R., White, R.C., Silverman, B.D. and Ho, P.S., to be published.Google Scholar
17.Albert, M.R. and Yates, J.T., in the “Surface Scientists Guide to Organometallic Chemistry”, American Chenical Society, Washington, DC 1987.Google Scholar