Late-glacial and Holocene 14C/12C ratios of atmospheric CO2 vary in magnitude from a few per mil for annual/decadal pertubations to more than 10% for events lasting millennia. A data set illuminating 10- to 104-yr variability refines our understanding of oceanic (climatic) versus geomagnetic or solar forcing of atmospheric 14C/12C ratios. Most of the variance in the Holocene atmospheric 14C/12C record can be attributed to the geomagnetic (millennia time scale) and solar (century time scale) influence on the flux of primary cosmic rays entering the atmosphere. Attributing the observed atmospheric 14C/12C changes to climate alone leads to ocean circulation and/or global wind speed changes incompatible with proxy records. Climate-(ocean-)related 14C redistribution between carbon reservoirs, while evidently playing a minor role during the Holocene, may have perturbed atmospheric 14C/12C ratios measurably during the late-glacial Younger Dryas event. First-order corrections to the radiocarbon time scale (12,000–30,000 14C yr B.P.) are calculated from adjusted lake-sediment and tree-ring records and from geomagnetically defined model 14C histories. Paleosunspot numbers (100–9700 cal yr B.P.) are derived from the relationship of model 14C production rates to sunspot observations. The spectral interpretation of the 14C/12C atmospheric record favors higher than average solar activity levels for the next century. Minimal evidence was found for a sun-weather relationship.

Early and Middle Wisconsin glaciolacustrine sediments exposed at Scarborough Bluffs, Toronto, Canada, contain a low-diversity benthic ostracode fauna dominated by Candona subtringulata and C. caudata. We have studied the oxygen and carbon isotopic compositions of the two ostracode species from the base of the Scarborough section to its top immediately below a Late Wisconsin till. We find an upward decrease in δ18O in both species that is more marked in C. caudata. The shift in δ18O of ostracode calcite from interglacial values of −6 to −8‰, to values of −17‰ immediately below the Late Wisconsin till is the result of (1) lowering of δ18O of the lake as a result of addition of isotopically light meltwater from an advancing and thickening Laurentide Ice Sheet combined with (2) lowering of δ18O of local precipitation entering the lake, due to falling temperatures. In the last stages of the lake, δ18O of the lake water was between −17 and −21‰, corresponding to a lake body composed of between 35 and 55% glacial meltwater. The lake appears to have been isotopically and thermally stratified for part of its history. Differences in δ13C values between C. caudata and C. subtriangulata increase upward in the stratigraphic section. This may record enhanced partitioning of carbon isotopes between surface and bottom waters as a result of increased water depths, photosynthesis by algae, and changes in the input of dissolved organic carbon from the oxidation of organic matter. If the age assessments of these sediments are correct, then these data provide valuable information regarding the isotopic composition of ancestral Lake Ontario and also confirm that the basin was only fully glaciated during the Late Wisconsin.

Earth's land-sea distribution modifies the temperature response to orbitally induced perturbations of the seasonal insolation. We examine this modification in the frequency domain by generating 800,000-yr time series of maximum summer temperature in selected regions with a linear, two-dimensional, seasonal energy balance climate model. Previous studies have demonstrated that this model has a sensitivity comparable to general circulation models for the seasonal temperature response to orbital forcing on land. Although the observed response in the geologic record is sometimes significantly different than modeled here (differences attributable to model limitations and feedbacks involving the ocean-atmosphere-cryosphere system), there are several results of significance: (1) in mid-latitude land areas the orbital signal is translated linearly into a large (>10°C) seasonal temperature response; (2) although the modeled seasonal response to orbital forcing on Antarctica is 6°C, the annual mean temperature effect (<2°C) is only about one-fifth that inferred from the Vostok ice core, and primarily restricted to periods near 41,000 yr; (3) equatorial regions have the richest spectrum of temperature response, with a 3000-yr phase shift in the precession response, plus some power near periods of 10,000–12,000 yr, 41,000 yr, 100,000 yr, and 400,000 yr. Peaks at 10,000–12,000 yr and 100,000 and 400,000 yr result from the twice-yearly passage of the sun across the equator. The complex model response in equatorial regions has some resemblance to geologic time series from this region. The amplification of model response over equatorial land masses at the 100,000-yr period may explain some of the observed large variance in this band in geologic records, especially in pre-Pleistocene records from times of little or no global ice volume.

Results of a high-resolution late-glacial AMS 14C chronology from Rotsee, central Switzerland, have given evidence that the atmospheric radiocarbon concentration was not constant between 13,000 and 9500 yr B.P. This resulted in three marked phases of constant radiocarbon age: at 12,700, at 10,000, and at 9500 yr B.P. New results of a late-glacial varve chronology from Soppensee, central Switzerland, suggest that the younger two phases of constant 14C age each had a duration of ca. 400 calendar years. The length of the late-glacial chronozones has been calculated on the basis of these replicate varve counts and a comparison with their estimated duration in radiocarbon years shows that the estimated duration of the chronozones Bölling (ca. 800 calendar yr vs 1000 14C yr) and Younger Dryas (ca. 900 calendar yr vs 1000 14C yr) agree with the expected time span, whereas the estimated duration of the Alleröd chronozone (ca. 400 calendar yr vs 1000 14C yr) is substantially shorter than expected. Furthermore, a tentative comparison of varve ages and 14C ages suggests that the varve chronology is more than 1000 yr offset toward older ages from the radiocarbon chronology during the late-glacial period.

A 1-m-deep gully section 460 m beyond the maximum Little Ice Age marginal moraines of Blåisen, Hardangerjøkulen, central southern Norway, revealed alternations of minerogenic and organic sediments. The geographical/geological settings of the dated section provides a unique on/off signal of Holocene glacier fluctuations of Blåisen. Lithostratigraphy, sediment characteristics, and radiocarbon dates from the study section indicate one period of glacier (re)advance between the late Preboreal deglaciation of the inland ice sheet and 8660 ± 100 yr B.P. A grey sand layer 56–57 cm below the surface is interpreted to be of fluvial/colluvial origin and is radiocarbon dated to about 7700 yr B.P. At 48 cm below the surface, a bluish-grey sand/silt layer is radiocarbon dated to 7590 ± 12 yr B.P. (6560–6240 B.C.) and interpreted to be glaciofluvial origin. A minor glacier oscillation postdates 1130 ± 70 yr B.P. (810–990 A.D.). The Medieval/Little Ice Age glacier advance of Blåisen beyond its modern extent occurred after 1040 ± 60 yr B.P. (960–1030 A.D.). Calculations of the modern and Little Ice Age equilibrium-line altitudes (ELAs) on Hardangerjøkulen suggest an ELA depression of ca. 130 m during the Little Ice Age maximum.

The geochemistry, petrography, and distribution of the Jarvis Creek Ash (Péwé, 1965, 1975a) indicate that this tephra from the lower Delta River area of central Alaska is correlative with vol volcanic ash from sites in south-central Alaska near Tangle Lakes (upper Delta River area) and the Cantwell ash from Hayes volcano found in the upper Nenana River area (Riehle et al., 1990). Volcanic glass compositions of distal Jarvis Creek and Tangle Lakes tephra samples are compositionally restricted, while several discrete glass populations are present in some samples are compositionally collected nearer Hayes volcano. These correlations extend the known distribution of Hayes volcano tephras across the Alaska Range and into central Alaska, a distance of more than 650 km. New geochronologic data for the Jarvis Creek Ash suggest it was deposited ca. 3660 ± 125 yr B.P., consistent with previous age estimates of tephra eruptions at the Hayes volcano. The name “Jarvis Creek Ash” has well-established priority with respect to “Cantwell ash” or other local names for this tephra layer from the Hayes volcano.

Temporal change in the growth of speleothems in the United Kingdom during the past 150,000 years is shown to be related to the insolation variation by the Milankovitch theory. The speleothem data compiled by Gordon et al. (1989. Quarternary Research 31, 14–26) have two Milanokovitch frequencies: the ca. 40,000-yr period related to change in the earth's obliquity and the ca. 20,000-yr period related to the precession of the equinoxes. The abundance of speleothem growth was, in general, large during the last interglaciation and small during the last glaciation. In both periods, however, speleothem abundance was greater during periods of strong insolation and less during weak insolation.

Holocene marine terraces along 15 km of the northeastern coast of North Island record episodic tectonic uplift. A maximum of seven terraces are arranged in staircase fashion and lie about 20 km above the subduction interface between the Pacific and Australian plates. The highest (T1) corresponds with the maximum of the Holocene marine transgression about 6700 14C yr B.P. Younger terraces are marine abrasion platforms overlain by thin beach deposits. Radiocarbon ages of marine shells from beach deposits indicate that uplift above marine conditions occurred ca. 6700(T1), 5500(T2), 3900(T3), 2500(4), 1600(T5), 1000(T6), and slightly younger than 600(T7) yr B.P. Uplift probably occurred coseismically. The maximum late Holocene uplift rate in the study area is 8 mm/yr. Altitudinal distribution of terraces suggests deformation exists as a ca. 20-km elongate dome, broken at the southern end by the Pakarae fault, which trends across the dome. Rupture on this fault has accompanied the growth of the dome but is not responsible for it. Bathymetric profiling suggests that an active fault, parallel to and about 5 km offshore, is probably responsible for the episodic coastal uplift.

A 12-m sequence of lake sediment and peat in a 45-m high exposure on Birch Creek, northeast Alaska, contains pollen of Picea, Betula, Alnus and Populus, and wood of Picea and Populus. This sequence, which may represent 10,000 yr of more of accumulation, is beyond the limit of radiocarbon dating. It lies between two units of loess; the underlying loess lies above the Old Crow Tephra, recently dated at 149,000 ± 13,000 yr B.P. The lake sediments probably were deposited during the last interglaciation (isotope substage 5e) and subsequently buried by Wisconsinan loess. Analogs for the ancient lake may be deep, long-lived thaw lakes that are present in the modern landscape. When Birch Creek is correlated with other sites across nonglaciated Alaska and northwest Canada, there appears to be a common interglacial signal in sediments overlying the Old Crow Tephra.

Recent explanations of widespread rhythmically layered sediments in eastern Washington as the result of repeated great floods from glacial Lake Missoula implicitly suggest a paleomagnetic test for validity. If each conjectural flood layer is separated by years or decades, as hypothesized, a sequence of several such flood beds should record measurable secular variation in geomagnetic field direction. In the Sanpoil River valley where the rhythmite sequences are thought to have been deposited in glacial Lake Columbia, the paleomagnetic test consists of measuring remanent magnetization (RM) directions for thick, upwardly fining beds inferred to be sediments deposited by the influx of flood waters from glacial Lake Missoula into glacial Lake Columbia. Laboratory measurements of samples from three widely spaced sections along the Sanpoil River yield RM vectors with erratic inclinations, apparently affected by varying contributions of inclination error and (or) compaction shallowing, but with declinations that generally differ statistically from one flood to the next and that show the same west-to-east trend at all three locations. The rates of declination change inferred from these data are consistent with modern rates, thus providing the first geophysical evidence supporting the timing in the tens-of-floods theory.

Thermoluminescence (TL) age determinations of alluvial sediments in the tropics are evaluated by comparison with U/Th age determinations of pedogenic accumulations in the alluvium of the lower Gilbert River, a large fan delta in the wet-dry tropics of northern Queensland, Australia. This study extends U/Th dating by applying it not only to calcretes, but also to Fe/Mn oxyhydroxide/oxide accumulations. While a direct correlation cannot be made between U/Th dates from secondary minerals and TL dates from the host sediments, both sets of data show broad consistency. In addition to providing a minima for acceptable TL ages, U/Th dates are useful for determining the chronology of pedogenesis/diagenesis. They show that calcretes and ferricretes have formed under similar climatic conditions in the wet-dry tropics of northern Australia during the late pleistocene. Beneath about 5–12 m the Gilbert fan delta consists of an extensive sand body older than 85,000 yr and probably about 120,000 yr in age, representative of a period of major fluvial activity not repeated since this time. Above are muds and fine sandy muds that extend uninterrupted to the present surface except in the downstream fan where they are bisected by a thin unit of medium sand that TL dates at 40,000–50,000 yr B.P. A system of sandy distributary channels over the fan surface represents an early Holocene fluvial phase probably more active than at present.

Twelve reworked shell fragments were recovered from five till samples collected on Nottingham Island in western Hudson Strait, Canada. Total hydrolysate amino acid ratios (D-alloisoleucine/L-isoleucine) for each fragment range from 0.043 to 0.154 and are significantly higher than ratios for radiocarbon-dated Holocene shells, which average 0.022. One shell fragment with an aIle/Ile ratio of 0.065 yielded an AMS radiocarbon age of 44,200 ± 2300 yr B.P. (AA-3254). Absolute age estimates based on the amino acid ratios are constrained by reasonable limits on the estimated effective diagenetic temperature of the fossils. On this basis, the shell fragments are correlated with oxygen isotope substages 5e and 5a and stage 3 in the preferred hypothesis. Theses results independently support hypotheses calling for at least partial deglaciation and marine incursion in Hudson Strait and Hudson Bay at these times.

Amino acid racemization data for marine molluscs of the last interglaciation from southern Australia provide the basis for a predictive model for relative dating of late Quaternary sequences. Genera analyzed include Anadara sp., Katelysia sp., Glycymeris sp., and Fulvia sp. that exhibit moderate racemization rates. A genus effect on racemization is not evident in these taxa. Coefficients of variation for intershell D/L ratio variation for each deposit are generally less than 12%. The extent of racemization in molluscan fossils of the last interglaciation from temperate coastal settings in southern Australia represents an exponential function of temperature and is in general accord with data from Northern Hemisphere sites with similar contemporary mean annual temperature values. These data highlight the potential of amino acid racemization for global correlation programs. The amino acid data from southern Australia suggest, however, that a larger margin of variation may have to be accounted for in stratigraphic correlation, as indicated by the greater scatter of data around the oxygen isotope substage 5e isochron. These data have implications regarding the age-resolving power of amino acid racemization.

A zircon fission-track age of about 400,000 yr B.P. has been determined for the Rockland tephra, a widespread pyroclastic layer in northern California and western Nevada. New ages of zircon separates from both proximal and distal exposures of this layer range from 370,000 to 460,000 yr; ages of the best material provide a narrower range, from 370,000 yr for unwelded ash-flow tuff to 420,000 yr for distal air-fall ash that appears to be uncontaminated by clastic detritus or xenocrysts. Detrital or xenocrystic grains in the ash-flow tuff may have been annealed during emplacement and cooling of the tuff. Detrital and xenocrystic zircons are identified on the basis of their physical characteristics and distinctly older ages. Independent stratigraphic and magnetostratigraphic data constrain the age of the Rockland tephra between 300,000 and 600,000 yr, a range that is compatible with the fission-track age. Zircon grains containing no spontaneous (fossil) tracks are regarded as part of the normal population of comagmatic grains because maximum ages calculated for these grains form a population that mimics the distribution of ages of individual zircon grains that contain fossil tracks; modal ages of both groups fall between 250,000 and 500,000 yr. Induced fission tracks from grains that lack fossil tracks are included in the age calculations, resulting in significantly younger and more coherent dates than would result if these tracks had been omitted, especially those of the finer-grained distal samples.

Magnetic and chemical analyses of 1-m piston cores from Loch Ba, Scotland illuminated the presence of a ferrimagnetic mineral which is sensitive to atmospheric oxidation and is soluble in H2O2. This phase, plausibly only an authigenic sulfide, is probably spinel Fe3S4 (greigite). Authigenesis of Fe3S4 requires reactive FeS and elemental S, the latter likely being derived from in situ oxidation of bisulfide near the sediment redoxycline. This is consistent with the observation of maximum “oxidation-sensitive” magnetic fractions around the oxic/anoxic sediment boundary at ca. 4–16 cm depth. Progressive pyritization of Fe3S4 during burial provides the most viable explanation for the loss of “oxidation-sensitive” phases at greater depth. The results extend the range of environments known to be subject to postdepositional magnetic enhancement to include oligotrophic lakes with relatively low productivity. This may have ramifications for magnetically based sediment-source linkage, core correlation, and pollution studies which fail to demonstrate that magnetostratigraphic profiles are solely reflectively of allogenic mineral presence.

Cambridge Fiord functions as a major outlet trough whenever Laurentide ice approaches the eastern coast of Baffin Island. During the last glacial maximum (late Foxe glaciation), an outlet glacier occupied most of the fiord, possibly terminating as far seaward as Buchan Gulf. Glacier retreat began prior to 8800 yr B.P. and was punctuated by the formation of two onshore moraines with upper age limits of 7900 and 7200 yr B.P. Correlative offshore moraines (recognized on seismic reflection profiles) formed prominent submarine sills which partitioned the fiord into three basins. These formed effective sediment traps that restricted the seaward migration of debris flows and turbidites, thus facilitating the accumulation of thick (> 100 m) stratified glacialmarine sediments in the inner fiord. Correlations of onshore and offshore moraines allow time lines to be placed within an offshore seismic stratigraphic section that is inaccessible to piston coring. Resultant estimates of sediment accumulation rates give a mean value of 2.34 × 106 m3/yer for deposits trapped in the inner fiord basins. These thick sequences of sediments do not represent extended Foxe/Wisconsin time periods, but, rather, were rapidly deposited in the inner fiord during the last deglaciation.

The 13C/12C ratios of occluded carbon within opal phytoliths from the northern Great Plains show potential as a basis for paleoclimatic reconstruction. A significant correlation exists between the carbon isotopic composition of a host plant and that of the organic matter in its phytoliths. The 13C/12C ratios for phytoliths from surface layers of soils along climatic gradients reflect the current proportions of C3 and C4 plants. Variations in the δ13C values of phytoliths with soil depth are caused by a variety of processes: burial of soil surface by dust, bioturbation, and possible illuviation by percolating water. Also, contributions of phytoliths by dust and roots have unknown isotopic effects. The δ13C values of phytoliths from soils increase with decreasing 14C age, suggesting that the proportion of C4 plants in this region has increased during the Holocene. Phytoliths of apparent mid-Holocene age suggest exclusive dominance by C4 plants which agrees with paleoclimatic interpretations of an arid middle Holocene climate.

Four soil chronosequences in the southern Great Basin were examined in order to study and quantify soil development during the Quaternary. Soils of all four areas are developed in gravelly alluvial fans in semiarid climates with 8 to 40 cm mean annual precipitation. Lithologies of alluvium are granite-gneiss at Silver Lake, granite and basalt at Cima Volcanic Field, limestone at Kyle Canyon, and siliceous volcanic rocks at Fortymile Wash. Ages of the soils are approximated from several radiometric and experimental techniques, and rates are assessed using a conservative mathematical approach. Average rates for Holocene soils at Silver Lake are about 10 times higher than for Pleistocene soils at Kyle Canyon and Fortymile Wash, based on limited age control. Holocene soils in all four areas appear to develop at similar rates, and Pleistocene soils at Kyle Canyon and Fortymile Wash may differ by only a factor of 2 to 4. Over time spans of several millennia, a preferred model for the age curves is not linear but may be exponential or parabolic, in which rates decrease with increasing age. These preliminary results imply that the geographical variation in rates within the southern Great Basin-Mojave region may be much less significant than temporal variation in rates of soil development. The reasons for temporal variation in rates and processes of soil development are complexly linked to climatic change and related changes in water and dust, erosional history, and internally driven chemical and physical processes.