Boaretto et al. (2005) published 68 radiocarbon dates relating to 30 samples from 10 Iron Age sites in Israel as part of their Early Iron Age Dating Project. Though the main goal of their paper was an interlaboratory comparison, they also presented results of Bayesian models, calculating the transition from Iron Age I to Iron Age II in Israel to be about 900 BCE instead of the conventional date of about 1000 BCE. Since this date has great importance for all of Eastern Mediterranean archaeology, in this paper we examine the results in light of the dates published in the above-mentioned article. Our paper was revised in light of new data and interpretations published by Sharon et al. (2007).

Following a survey of the contexts and specific results at each site, we present several Bayesian models. Model C2 suggests the date range of 961–942 BCE (68% probability) for the transition from Iron Age I to Iron Age II, while Model C3 indicates a somewhat later date of 948–919 BCE (compare the date 992–961 BCE calculated at Tel Rehov for the same transition). In our Model D, we calculated this transition date at Megiddo as taking place between 967–943 BCE. Finally, we calculated the range of dates of major destruction levels marking the end of the Iron Age I, with the following results: Megiddo VIA: 1010–943 BCE; Yoqne'am XVII: 1045–997 BCE; Tell Qasile X: 1039–979 BCE; Tel Hadar: 1043–979 BCE (all in the 68.2% probability range). Figure 4 indicates that the transition between Iron I and II probably occurred between these above-mentioned destruction events and the dates achieved in our Models C2 or C3, namely during the first half of the 10th century BCE.

This study emphasizes the sensitivity of Bayesian models to outliers, and for reducing or adding dates from the models. This sensitivity should be taken into account when using Bayesian models for interpreting radiometric dates in relation to subtle chronological questions in historical periods.

Grant Kocharov was a man whose life mirrored all the complexity and controversy of the fate of Russia in the second part of the 20th century. Kocharov was a bright, colorful, and ambitious person. He was born in Georgia, and his childhood and youth were not sunny and cloudless. His father died early and it was very difficult for his mother to feed their large family.

Radiocarbon analysis in annual rings of a teak tree (Tectona grandis) is reported in comparison with previously published results. Samples (disks) were collected from Hoshangabad (22°30′N, 78°E), Madhya Pradesh, in central India. The previously published sample was collected from Thane (19°12′N, 73°E), Maharashtra, near the west coast of India (Chakraborty et al. 1994). Two short Δ14C time series were reconstructed with these tree samples to capture the bomb peak of atmospheric 14C and the spatial variability in this record. These time series represent the periods 1954–1977 and 1959–1980 for Hoshangabad and Thane, respectively. The 14C peaks in these places appear around 1964–1965. The Hoshangabad tree records a peak Δ14C value of 708 ± 8%, which conforms to the peak value of Northern Hemisphere Zone 3 as described in Hua and Barbetti (2004). But the peak Δ14C at Thane is somewhat less (630 ± 8%) probably due to the dilution by fossil fuel CO2 free of 14C emanating from the neighboring industrial areas. This depletion of peak values has been used to estimate the local emission of fossil fuel CO2, which is approximately 2.3% of the background atmospheric CO2 concentration.

The open-air archaeological site at Krems-Hundssteig is a well-known Upper Paleolithic site located in Lower Austria. The site was discovered in the late 19th/early 20th centuries when a large number of archaeological remains were collected during the course of loess quarrying. Although no systematic excavation has ever been performed, Krems-Hundssteig has been described since its discovery as typical of the Aurignacian period in this region based on the numerous archaeological finds; accordingly, the culture has been named Kremsien by some authors. Surprisingly, the artifacts found in a recent excavation adjacent to this location showed solely Gravettian features, calling into question the original assignment to the Aurignacian. Although the earlier assignment was supported by a radiocarbon date of ∼35 kyr BP (Hahn 1977), new accelerator mass spectrometry (AMS) 14C dates proved that the recently excavated cultural layer originates from the Gravettian period. Older paleosols were also detected by sondage drillings at some depth below it.

The new results indicate that a large Aurignacian level and a substantial complex of Gravettian layers are present in this area. Therefore, it must be assumed that more than 1 cultural level was affected and destroyed by the historic loess quarrying, and that the assemblage of Krems-Hundssteig artifacts, traditionally ascribed to the Aurignacian, might be interspersed with Gravettian pieces.

This research presents the first comprehensive radiocarbon chronology for central Alaska, encompassing the late Pleistocene and Holocene archaeological record. Dated component distributions, comprised of 274 14C dates from 160 components, indicate changing land-use strategies and subsistence economies, reflecting primarily lowland exploitation of bison, wapiti, and birds prior to 6000 cal B P, followed by increasing caribou and fish exploitation and use of upland areas. Microblade technology is conserved from the earliest components to ~1000 cal B P, and this continuity is not reflected in current cultural history sequences. Using component abundance as a proxy for population, initial colonization is associated with climate amelioration after ~14,000 cal BP, and population declines are associated with the Younger Dryas (13,000–12,000 cal BP) and initial establishment of widespread spruce forests (10,000–9000 cal BP).

The reliability of radiocarbon ages based on soil organic matter (SOM) from Holocene buried soils in Middle Park, Colorado, is assessed by comparison with ages of charcoal. On average, 14C ages of SOM from buried surface horizons are 880 ± 230 14C yr younger than charcoal ages from the same horizon. Humic acid (HA) and low-temperature (400 °) combustion residue (LT) fractions are 390 ± 230 and 1290 ± 230 14C yr younger than charcoal ages, respectively, and HA ages are on average 860 ± 140 14C yr older than LT fractions. We interpret the offsets between 14C ages of charcoal and SOM fractions and the consistent offsets between the HA and LT fractions to reflect the duration of pedogenesis and different residence times of the SOM fractions examined here. The stratigraphic coherence of charcoal 14C ages suggests short residence time on the landscape, with little subsequent reworking. 14C ages of HA and LT fractions are complimentary to charcoal, and HA ages are interpreted to represent minimum ages for the onset of pedogenesis and LT ages are considered maximum ages for burial. The 14C chronology from buried soils indicates an episode of hillslope erosion in Middle Park during the early Holocene, followed by a long period of land surface stability and soil formation between 9000–4500 BP. Two episodes of late Holocene hillslope erosion between 3500–2500 and 1000–500 BP correspond with warming recognized in the Colorado Front Range, while surface stability and soil formation between 2500–1000 BP is contemporaneous with evidence for cooling at higher elevations.

Radiocarbon dating has been used infrequently as a chronological tool for research in Anglo-Saxon archaeology. Primarily, this is because the uncertainty of calibrated dates provides little advantage over traditional archaeological dating in this period. Recent advances in Bayesian methodology in conjunction with high-precision 14C dating have, however, created the possibility of both testing and refining the established Anglo-Saxon chronologies based on typology of artifacts. The calibration process within such a confined age range, however, relies heavily on the structural accuracy of the calibration curve. We have previously reported decadal measurements on a section of the Irish oak chronology for the period AD 495–725 (McCormac et al. 2004). In this paper, we present decadal measurements for the periods AD 395–485 and AD 735–805, which extends the original calibration set.

When ancient hearths at open archaeological sites do not yield carbonized annual plant remains or other high-quality samples, wood charcoal is commonly used for radiocarbon dating. Sagebrush (Artemisia tridentata Nutt.), a shrub frequently used for fuel across much of the western United States, seems a potentially better candidate for 14C dating than tree wood since the possibility for significant age discrepancy might be less. A comparison of multiple assays from single features reveals that sagebrush can overestimate age more than even tree wood charcoal. A plausible cause of this appears to be persistence of the shrub on the ground surface for an extended interval after death, such that use as fuel almost invariably occurs hundreds of years after fixation of carbon. The potential for age discrepancy may decrease as population density increases because the demand for fuel wood would have resulted in a more rapid turnover of the fuel biomass. This is not true for Archaic period foragers of western North America when population levels were likely quite low and residential mobility quite high.

A reanalysis of the chronology of Pololu Valley, located in the district of Kohala on Hawai'i Island, is presented using standard radiocarbon and accelerator mass spectrometry (AMS) dating. Using curated materials from the 1970s, Pololu is reassessed and found to have the earliest coastal occupations in this part of Hawai'i, beginning about AD 1300. Occupations at the dunes and in the valley interior are investigated, as are dryland and wetland field agricultural systems. These data provide a refined model for expansion and intensification of agricultural production in the 15th–17th centuries, and link this remote valley to demographic and sociopolitical trends that were occurring in the rest of Hawai'i.

Various organic fractions of an Indonesian tropical peat deposit were dated using radiocarbon accelerator mass spectrometry (AMS). Four different depth layers, deposited during the last 28,000 14C yr, were analyzed and the data compared to bulk sample analyses. The pollen extracts consistently produced the oldest dates. The bulk samples (<250 μm and <100 μm) often yielded the youngest dates. The age difference between the individual fractions depended on the layer depth and hence the true age of the sampled peats. The age discrepancy was highest (∼16,000 14C yr) in the oldest peat material. We interpret this to be a consequence of the input of organic matter over a long period of time, with peat oxidation and/or no peat accumulation during the last glacial maximum (LGM). The age discrepancies were smaller (between 10 and 900 14C yr) for the Holocene peat samples. It was concluded that the pollen extract fraction might be the most reliable fraction for dating tropical peat deposits that are covered by deeply rooting vegetation.

For at least 100,000 yr, marine shell beads have been important ornamental and symbolic artifacts intimately associated with the behavior of anatomically modern humans. In California, giant rock scallop (Hinnites multirugosus) beads were once thought to have been used only for the last 1000 yr, where they were considered to be markers of high social status among the Chumash Indians of the Santa Barbara Channel region. Direct accelerator mass spectrometry (AMS) radiocarbon dating of 1 giant rock scallop ornament and 2 beads from San Miguel Island extends the use of this shell for personal adornment to at least 8000 cal BP. Our study emphasizes the importance of direct AMS 14C dating of artifacts to enhance cultural chronologies and clarify the antiquity of various technologies and associated behaviors. Our results also caution archaeologists when equating artifact rarity with sociopolitical complexity.

Bayesian analysis of 6 radiocarbon and 2 luminescence determinations from Punta de Chimino's acropolis provides subcentury chronometric accuracy for a Protoclassic hiatus and a more decisive, incipient Early Classic abandonment. For the latter event, sensitivity tests and a redundant modal value pattern reduce the period of historical interest from a few centuries to several decades. The findings aid in selecting between 2 historical scenarios and demonstrate that improved chronological accuracy is attainable for sites and contexts lacking calendrical dates.

Five short cores (top 40–45 cm of sediment) from 4 lakes of the Plitvice Lakes system (Croatia) were measured for 210Pb, 137Cs, a14C, δ13C, and δ18O in order to study the influence of environmental changes on the sediment system in small and large lakes. Sediment chronology based on the constant flux (CF) 210Pb model was the most reliable. Lake sediments consisted mainly of autochthonous carbonates with higher sedimentation rates in small lakes. Sediments from 2 large lakes, Prošće and Kozjak, showed constant stable isotope profiles for the carbonate fraction and full agreement between the 137Cs and 210Pb chronologies. Sediments from 2 small lakes, Gradinsko and Kaluderovac, showed synchronous increases in 14C and δ13C and disturbed 137Cs records. All lakes showed an increase in a14C in the carbonate sediments above the first occurrence of 137Cs, which was interpreted as a damped (~10 pMC increase in a14C) and decades-delayed consequence of the bomb-induced increase in a14C in atmospheric CO2. For the small lakes, increased δ13C in the last 2 decades and part of the a14C increase is probably due to an increase in primary productivity, which enhanced biologically induced calcite precipitation with concomitant changes in the carbon isotopic composition of carbonate sediments. δ13C values of a near-shore sediment core close to the confluence of one of the tributaries of Lake Kozjak showed that the carbonates in this core are a mixture of autochthonous and eroded allochthonous mineral carbonate. This core had a higher fraction of organic material. The sedimentation rate at this core site was high, but rates could not be quantified by 210Pb, 137Cs, or 14C.

This paper presents 31 new ΔR results of known-age, pre-AD 1950 shells from the South Pacific subtropical gyre region, spanning from the Tuamotu Archipelago in the east to New Caledonia in the west. This doubles the number of available ΔR values for the Oceania region. These values indicate that the regional offset (ΔR) from the modeled radiocarbon marine age has remained relatively constant over the last 100 yr prior to 1950. Variation from the norm can be attributed to various influences including localized upwelling around islands, the presence of a hardwater effect, direct ingestion of old carbon by the live shellfish, or enhanced exchange with atmospheric CO2 as a consequence of photosynthetic activity or increased aeration.

We present a new method developed for measuring radiocarbon of methane (14CH4) in ancient air samples extracted from glacial ice and dating 11,000–15,000 calendar years before present. The small size (∼20 μg CH4 carbon), low CH4 concentrations ([CH4], 400–800 parts per billion [ppb]), high carbon monoxide concentrations ([CO]), and low 14C activity of the samples created unusually high risks of contamination by extraneous carbon. Up to 2500 ppb CO in the air samples was quantitatively removed using the Sofnocat reagent. 14C procedural blanks were greatly reduced through the construction of a new CH4 conversion line utilizing platinized quartz wool for CH4 combustion and the use of an ultra-high-purity iron catalyst for graphitization. The amount and 14C activity of extraneous carbon added in the new CH4 conversion line were determined to be 0.23 ± 0.16 μg and 23.57 ± 16.22 pMC, respectively. The amount of modern (100 pMC) carbon added during the graphitization step has been reduced to 0.03 μg. The overall procedural blank for all stages of sample handling was 0.75 ± 0.38 pMC for ∼20-μg, 14C-free air samples with [CH4] of 500 ppb. Duration of the graphitization reactions for small (<25 μg C) samples was greatly reduced and reaction yields improved through more efficient water vapor trapping and the use of a new iron catalyst with higher surface area. 14C corrections for each step of sample handling have been determined. The resulting overall 14CH4 uncertainties for the ancient air samples are ∼1.0 pMC.

We report radiocarbon ages on cellulose isolated from the gut contents of a Diprotodon found at Lake Callabonna, South Australia. The maximum age obtained corresponds to a minimum age of >53,400 BP for this extinct giant marsupial. This is older than, and hence consistent with, the generally accepted Australian megafauna extinction window. We argue that dichromate and other strong oxidants are less selective than chlorite for lignin destruction in wood, and our results suggest that ages approaching laboratory background can be obtained using a repeated pretreatment sequence of chlorite-alkali-acid and measurement of the sometimes discarded 330°C combustion fraction.

Marine sediment records from the north Icelandic shelf, which rely on tephrochronological age models, reveal an average ΔR (regional deviation from the modeled global surface ocean reservoir age) of approximately 150 yr for the last millennium. These tephra-based age models have not hitherto been independently verified. Here, we provide data that corroborate ΔR values derived from these sediment archives. We sampled the youngest portion (ontogenetic age) of a bivalve shell, Arctica islandica (L.), for radiocarbon analysis, which was collected alive in 2006 from the north Icelandic shelf in ∼80 m water depth. Annual band counting from the sectioned shell revealed that this clam lived for more than 405 yr, making it the longest-lived mollusk and possibly the oldest non-colonial animal yet documented. The 14C age derived from the umbo region of the shell is 951 ± 27 yr BR Assuming that the bivalve settled onto the seabed at AD 1600, the corresponding local value of ΔR is found to be 237 ± 35 yr by comparison of the 14C age with the Marine04 calibration curve (Hughen et al. 2004) at this time. Furthermore, we cross-matched a 287-yr-old, dead-collected, A. islandica shell from AD 1601 to 1656 from the same site with the live-caught individual. 14C analysis from the ventral margin of this shell revealed a ΔR of 186 ± 50 yr at AD 1650. These values compare favorably with each other and with the tephra-based ΔR values during this period, illustrating that 14C from A. islandica can effectively record 14C reservoir changes in the shelf seas.