Georgia represents an interesting case to study the agency of small states in reshaping their regional identity and external environment. Although much of the world has considered Georgia as politically part of the South Caucasus region, the country’s political elites themselves have long attempted to escape the geographic boundaries of the South Caucasus region and relocate their country into Eastern Europe. We argue that Georgian elites were partially successful in their quest for foreign political identity change. Although they did not manage to entirely change the international perception about Georgia’s geographic belonging, the country has politically moved closer to Eastern Europe and is considered to be part of “Associated Trio” together with Ukraine and Moldova—and recently became an EU candidate. From a theoretical perspective, we argue that Georgia’s quest for foreign policy identity recalibration fits the constructivist paradigm of international relations well. It can be argued that Georgia’s political elites were partially driven by ideational factors and were ignorant of the balance of power in their external environment, which cost the country the lost wars and compromised territorial sovereignty.

Six kaolin samples from the Lower Tertiary Huber Formation near Wrens, Georgia were analyzed using transmission electron microscopy (TEM), electron diffraction (ED), powder X-ray diffraction (XRD), chemical analysis, and magnetic susceptibility to characterize the Ti-bearing phases. Selected samples were treated with 5 M NaOH to remove kaolinite and concentrate the Ti-bearing phases for additional analysis. TiO2 content in the bulk fraction ranges from 1.2 to 5.4 wt. %. There are at least three Ti-bearing phases, including anatase, rutile, and a poorly defined nanocrystalline form. Anatase is most abundant and is commonly found with {010} faces in association with kaolinite edge and basal faces. The nanocrystalline form occurs at 0–1 wt. %, and rutile occurs in trace amounts. Bulk XRD analysis correlates well with the bulk TiO2 chemical measurements. Average anatase unit-cell parameters are a = 0.37908 ± 0.0002 nm and c = 0.951 ± 0.001 nm. These parameters indicate an approximate chemical formula of Fe3+0.05Ti4+0.95O1.95(OH)0.05.

The distribution of TiO2 content as a function of depth may be useful to obtain original grain-size variations associated with relative sea-level changes responsible for the deposition of the Huber Formation. Evidence for original depositional sediment properties can be seen in the occurrence of pseudomorphic replacement of micas and fecal pellets by kaolinite. Additional evidence for post-depositional changes includes the sub-micrometer euhedral character and low Fe content of the anatase (relative to soil-derived anatase). These observations for the Huber Formation are consistent with a previously published theory for kaolin genesis that includes biomineralization of originally coarser-grained aluminosilicates into a kaolinite-rich ore body.

Additional well-crystallized kaolin from Washington County, Georgia, has been supplied to the Clay Minerals Society Source Clay Repository to replace the exhausted supply of KGa-1. This kaolin is called KGa-1B and is from a geographic location and stratigraphic position close to where KGa-1 was collected. Slight mineralogical and chemical differences are observed between KGa-1 and KGa-1B. KGa-1B crude appears slightly better crystalline than KGa-1, and it has a slightly higher titania content than KGa-1. The Al2O3, SiO2, Fe2O3, alkali, and alkaline earth contents appear similar for both samples. KGa-1 has a slightly coarser particle size than KGa-1B crude. More intensive post-depositional alteration may have cleansed and crystallized the KGa-1B material to a slightly greater degree than the KGa-1 material.

Wine was deeply embedded in all aspects of Roman life and its role in society, culture and the economy has been much studied. Ancient Roman texts and archaeological research provide valuable insights into viticulture and the manufacture, trade and consumption of wine but little is known of the sensory nature of this prized commodity. Here, the authors offer a novel oenological approach to the study of Roman dolia through their comparison with modern Georgian qvevri and associated wine-production techniques. Far from being mundane storage vessels, dolia were precisely engineered containers whose composition, size and shape all contributed to the successful production of diverse wines with specific organoleptic characteristics.

The sedimentology and mineralogy of a 2.5 m core from a palygorskite deposit of the Miocene Hawthorne Formation, southern Georgia is described. The lithology involves laminated clay-rich sediment composed of ∼90% clay and 10% sand, with six clay-pebble layers present. Sand to pebble-size clasts of phosphate material are common throughout the core. The sand laminations are probably flood-related and the clay-pebble layers are storm deposits, with the pebbles being derived locally from subaerial environments. Phosphate clasts are reworked bone material.

The sands are quartz-rich and are subarkosic in composition with average quartz counts of 86.50% and average total feldspar counts of 11.50%. Heavy minerals observed include orthopyroxene, clinopyroxene, amphibole, zircon, rutile, garnet, tourmaline, kyanite, muscovite, biotite, spinels and opaques. Palygorskite fibers dominate the clay-size fraction of the samples and comprise ∼80–90% of sample material with smectite comprising the remainder. Hydroxylapatite comprises ∼3% of sediment volume and occurs as individual euhedral hexagonal crystals and as clusters of crystals.

Investigation of this core suggests that the palygorskite deposit represents a dynamic system with regular flooding and storm deposition being common. Mineral composition of sands may be useful for stratigraphic correlation of palygorskite deposits in the Apalachicola Embayment. This study supports the general environmental interpretations of previous workers for the palygorskite deposits of southern Georgia, but provides greater detail.

The high-density siliciclastic minerals (e.g. zircon) in the coarse fractions (>44 mm, informally known as grit) of the mined Georgia kaolins are potential and significant sources of the rare-earth elements (REE). The abundances and provenance of the REE signature have not been studied extensively for the Georgia kaolins. The objective of the present study was, therefore, to define the contribution of these heavy minerals (e.g. zircon) to the REE inventory of the coarse fractions of Georgia kaolins. Heavy-mineral subfractions separated from the coarse fractions contained 1647 mg/kg REE from the Jeffersonville Member of the Lower Tertiary Huber Formation and 5012 mg/kg REE from the Buffalo Creek Kaolin Member of the Upper Cretaceous Galliard Formation, respectively. These heavy-mineral subfractions were enriched 10–100 times in the heavy rare-earth elements (HREE, Gd—Lu,), Hf, and Zr relative to the concentrations of these elements in Upper Continental Crust. The heavy-mineral subfractions comprised 5% of the coarse fractions (grit) of these two kaolin-producing formations. The heavy-mineral subfractions consisted of zircon, anatase, rutile, kaolinite, and minor amounts of muscovite, trace ilmenite, and staurolite. The large concentrations of REE were obtained by separating the dense heavy minerals from the coarse fraction (grit) obtained during the typical production of kaolin-group minerals (kaolinite) from kaolin ore. The amount of zircon (estimated from the 6–11 wt.% Zr) and the absence of monazite did not explain the high concentrations of REE in the heavy-mineral subfractions. The large amounts of REE could have resulted from the sorption of REE released during weathering reactions, or from the presence of small amounts (0.025 wt.%) each of monazite and xenotime in addition to the presence of zircon. This heavymineral subfraction represented a novel domestic resource of extractable REE, especially the HREE, of a grade as high as 0.50 wt.% total REE.

Most previous studies of the kaolin deposits in the southeastern United States have focused on their mineralogy and petrology to understand better the depositional and diagenetic environments of the kaolins. Many studies suggest, however, that much of the information held within the minerals was changed during extensive post-depositional groundwater and microbial alteration. Organic δ13C and biomarker analyses were used, therefore, to provide further information on the nature of the original sediments, the depositional environment(s), and the amount of diagenetic alteration that has occurred in Georgia kaolin deposits.

Two different types of kaolin can be discerned, based on their total organic carbon contents: organic-lean kaolin and lignitic kaolin. The bulk organic δ13C in the Georgia kaolins ranges from ~−26 to −19% (VPDB, Vienna Pee Dee Belemnite standard), with a noticeable enrichment in 13C with decrease in organic carbon concentration. The lean kaolins are by far the more dominant types, with an organic-matter composition primarily of C16–C22n-alkanes, C16 and C18 fatty acids, and unresolved complex mixtures. Lignitic kaolin has a distinctly different organic matter (OM) composition. The lignitic material is primarily C15–C33n-alkanes with a greater abundance of C23–C31n-alkanes and lesser amounts of resinous and microbial constituents along with the oxidized forms of the saturated lipid fractions.

Biomarker data suggest that the lignitic material is primarily terrestrially derived from conifers with minor input from microbial lipids. The OM in both types of kaolin shows strong signs of microbial decomposition that yield the organically lean kaolins. The oxidation of the detrital organic matter would subsequently yield organic acids that would have exerted significant influence on the mineralogy and metal mobility.

A microtexture analysis by TEM and AFM of palygorskite deposits from the Hawthorne Formation, southern Georgia is given. Palygorskite is the dominant mineral comprising an average of 65–70% of the sample volume with smaller volumes of smectite, illite and kaolinite. Morphologic observations indicate that the palygorskite formed in an unconfined environment, such as in the water column or in open-pore space. Some palygorskite textures appear to be secondary growths filling voids. An unusual texture is observed where smectite or illite-smectite (Reichweite, R = 0) form epitaxially on detrital illite and kaolinite particles. Oxides of Fe and Ti are common, and authigenic cassiterite is present but rare. Apatite is a common trace mineral in these sediments and occurs in a variety of textures. Apatite occurs as clusters which are believed to be small fecal pellets. These clusters have been partially dissolved and recrystallized and the crystals in the clusters are 50–100 µm in diameter. Other apatite crystals occur either as single crystals or in clusters that are not associated with fecal pellets.

The textural data of this study suggest that there was an evolving and complex mineralogical and geochemical system during and after deposition of the palygorskite deposits in the Hawthorne. The epitaxial overgrowths of smectite on detrital illite and kaolinite particles indicate an intermittent stratified water column occurring in the system. Freshwater was introduced into the system from the northeast of the Apalachicola embayment and overrode more saline water in the southwest portion of the embayment. The results of this study are consistent with previous environmental interpretations and provide additional details.

The total concentrations of rare-earth elements (REE) in the mined kaolin (0.02–0.06 wt.%), kaolin mine tailings (0.03–1.9 wt.%), and the kaolin-associated Marion Member sand lithology (0.03–4.6 wt.%) opened questions regarding the modes of occurrence of the REE and the role(s) of chemical weathering and secondary processes to explain the presence of REE in these materials. The REE were hosted primarily by phosphate minerals (monazite, xenotime) based on mineralogic analyses (scanning electron microscopy, X-ray diffraction). Enrichments in the light rare-earth elements (LREE: La–Gd) and the high correlation coefficient values were noted between P and the total REE concentrations (r2 = 0.99) for the sands and the mine tailings. Lower correlation coefficient values were noted between total REE concentrations and Zr (r2 = 0.31). The coarse fractions of the mined kaolins were enriched in the heavy rare-earth elements (HREE: Y, Tb–Lu) relative to the kaolin-associated sand lithologies. The REE inventory cannot be explained solely by mineral inheritance within the mined kaolins. Lower correlation coefficient values between P and total REE, positive Eu/Eu* anomalies, and the presence of xenotime overgrowths on zircon showed the importance of the role of chemical weathering of the detrital minerals during post-depositional processes (such as diagenesis) leading to redistributed and fractionated REE within the mined kaolin. The possibility of adsorption of the REE to kaolin mineral surfaces in the fine fraction of the mined kaolins remains open and permits further study to characterize fully the multi-modal fractionation of REE possible in the Georgia kaolin deposits.

Former president Trump made hundreds of candidate endorsements in the 2022 Republican primaries. The state of Georgia garnered outsized attention because it was ground zero for Trump’s false accusations of a stolen 2020 presidential election. Trump endorsed several candidates in Georgia’s May 2022 GOP primary contests, including candidates challenging Governor Brian Kemp and Secretary of State Brad Raffensperger, incumbents drawing Trump’s ire for upholding the 2020 outcome favoring Joe Biden. In a survey of likely Georgia GOP primary voters randomizing whether they are told which candidate Trump endorsed in five statewide races (governor, US Senate, lieutenant governor, secretary of state, and insurance commissioner), our analysis shows substantial variability in the influence of Trump’s endorsement. With scant prior information in low-profile contests (e.g., insurance commissioner), the Trump endorsement has a substantial impact, whereas it is rendered ineffectual in the most high-profile race for governor. Thus, the findings demonstrate the remarkable variability of a Trump endorsement, which is primarily contingent upon the salience of a specific race.