We study the largest exposed example of an early Cambrian palaeokarst, associated with laterites and developed during rifting of the Ossa–Morena Zone. The lithostratigraphy, biostratigraphy, facies and the genesis reflect episodes of sea-level fall (Cerro del Hierro Regression) related to tectonic events and palaeoclimate. This palaeokarst can be primarily considered as the result of early Cambrian polyphase karstification in an extensional tectonic regime, later modified by Neogene–Quaternary geomorphological processes. The event may correlate with other regressive events of a similar age in Spain, Italy, United Kingdom, South America and Australia. This episode also has local names (e.g. Cerro del Hierro Regression in the Mediterranean region; Woodlands Regression in the UK). It is sometimes accompanied by additional karst development outside of Spain that is compared and interpreted in a global context.

The terminal Ediacaran Dengying Formation (c. 551.1–538.8 Ma) in South China is one of two successions where Ediacara-type macrofossils are preserved in carbonate facies along with skeletal fossils and bilaterian animal traces. Given the remarkable thickness of carbonate-bearing strata deposited in less than 12.3 million years, the Dengying Formation holds the potential for construction of a relatively continuous chemostratigraphic profile for the terminal Ediacaran Period. In this study, a detailed sedimentological and chemostratigraphic (δ13Ccarb, δ18Ocarb, δ13Corg, δ34Spyrite, and 87Sr/86Sr) investigation was conducted on the Dengying Formation at the Gaojiashan section, Ningqiang County of southern Shaanxi Province, South China. Sedimentological results reveal an overall shallow-marine depositional environment. Carbonate breccia, void-filling botryoidal precipitates and aragonite crystal fans are common in the Algal Dolomite Member of the Dengying Formation, suggesting that peritidal facies were repeatedly karstified. The timing of karstification was likely early, probably soon after the deposition of the dolomite sediments. The presence of authigenic aragonite cements suggests high alkalinity in the terminal Ediacaran ocean. Geochemical analysis of micro-drilled samples shows that distinct compositions are registered in different carbonate phases, which should be considered when constructing chemostratigraphic profiles representative of true temporal variations in seawater chemistry. Integrated chemostratigraphic data suggest enhanced burial of organic carbon and pyrite, and the occurrence of extensive marine anoxia (at least in the Gaojiashan Member). Rapid basinal subsidence and carbonate accumulation during a time of elevated seawater alkalinity and increased rates of pyrite burial may have facilitated the evolutionary innovation of early biomineralizing metazoans.