Cryogenic carbon capture (CCC) is an innovative technology to desublimate
$\text {CO}_2$ out of industrial flue gases. A comprehensive understanding of
$\text {CO}_2$ desublimation and sublimation is essential for widespread application of CCC, which is highly challenging due to the complex physics behind. In this work, a lattice Boltzmann (LB) model is proposed to study
$\text {CO}_2$ desublimation and sublimation for different operating conditions, including the bed temperature (subcooling degree
$\Delta T_s$), gas feed rate (Péclet number
$Pe $) and bed porosity (
$\psi$). The
$\text {CO}_2$ desublimation and sublimation properties are reproduced. Interactions between convective
$\text {CO}_2$ supply and desublimation/sublimation intensity are analysed. In the single-grain case,
$Pe $ is suggested to exceed a critical value
$Pe _c$ at each
$\Delta T_s$ to avoid the convection-limited regime. Beyond
$Pe _c$, the
$\text {CO}_2$ capture rate (
$v_c$) grows monotonically with
$\Delta T_s$, indicating a desublimation-limited regime. In the packed bed case, multiple grains render the convective
$\text {CO}_2$ supply insufficient and make CCC operate under the convection-limited mechanism. Besides, in small-
$\Delta T_s$ and high-
$Pe $ tests,
$\text {CO}_2$ desublimation becomes insufficient compared with convective
$\text {CO}_2$ supply, thus introducing the desublimation-limited regime with severe
$\text {CO}_2$ capture capacity loss (
$\eta _d$). Moreover, large
$\psi$ enhances gas mobility while decreasing cold grain volume. A moderate porosity
$\psi _c$ is recommended for improving the
$\text {CO}_2$ capture performance. By analysing
$v_c$ and
$\eta _d$, regime diagrams are proposed in
$\Delta T_s$–
$Pe $ space to show distributions of convection-limited and desublimation-limited regimes, thus suggesting optimal conditions for efficient
$\text {CO}_2$ capture. This work develops a viable LB model to examine CCC under extensive operating conditions, contributing to facilitating its application.