Age estimates from bomb 14C dating conflict with a well-recognized age reading protocol (grinding, polishing and staining in the sagittal plane) for otoliths of European eel (Anguilla anguilla). Proper alignment of calculated hatch years for 14C measurements taken from the earliest otolith growth—among the smallest otolith extractions to date for successful 14C analysis due to the advent of gas-AMS—was not achieved using age estimates from an accepted method. The realignment of otolith 14C values to a tropical bomb 14C reference chronology, which is most applicable to the Sargasso Sea as the natal origin of European eel, led to an increase of the original age estimates by 8 to 32 years. A maximum age of approximately 46 years was determined for the European eel specimen with the most massive otolith, of which mass is a reasonable proxy for age and was instrumental in identifying age estimate discrepancies. By extending the otolith mass-to-age relationships from this study to the most massive otoliths available from archived otoliths of Norway, an increase of up to several decades from the original otolith age estimates was discovered, leading to support for a potential lifespan of 70–100 years in the natural environment.

To investigate long-term relationships between climate, vegetation, landscape geochemistry and fires in the boreal forest zone of Western Siberia, a sediment core of 345 cm was collected from Shchuchye Lake (located in south taiga zone of southeast part of West Siberian plain) and investigated by spore-pollen, radiocarbon, LOI and charcoal analyses. Quantitative palaeoclimate was reconstructed based on pollen data. Investigation revealed 13.2 cal ka history of vegetation, climate, landscapes and fires. In the dry climate of Late Glacial, the landscape was treeless. Continuous permafrost existed in the soil. In the middle of the YD cooling 12.4–12.2 cal ka BP, our data showed warming that caused degradation of permafrost in soils and settlement of spruce in moist places. Later, thawing and accumulation of moisture in a local lowering in relief increased and a lake was formed. With the beginning of the Holocene, the climate sharply changed to warmer and wetter. Intensified surface flow caused accumulation of mineral and carbonate fraction in the lake. Dense birch forests spread on drylands. As a result, the leaching regime initiated the formation of podzols in the soil. At about 10.0 cal ka BP, Scots pine (Pinus sylvestris) quickly spread in the area of investigation. Fires became more frequent and more intense during the dry Late Glacial time, sharply decreasing with increased precipitation in the Early Holocene, and again moderately increasing with spread of pine forests in the mid Holocene. With the transition to Late Holocene (after 6.0 cal ka BP), the intensity of regional background fires and number of local fires decreased.

The study analyses in situ CO2 mole fraction, 14CO2, and fossil based excess CO2 mole fraction (Cfoss) data at Hegyhátsál (HUN) rural monitoring station (Central Europe) supplemented by passive monitoring of 14C content of tree-rings. Through the observed period (2014–2020) we focused on revealing trends in atmospheric CO2 and 14C levels, particularly during the year of the first COVID lockdown, in comparison to the preceding five years. In addition, monthly integrated samples of atmospheric CO2 and tree-rings from the six years were subjected to 14C analysis. The passive tree-ring measurements focuses on two major urban areas (Budapest and Debrecen) in Hungary, along with the rural monitoring site. Results show a steady increase in CO2 levels at HUN between 2014 and 2020. The calculated fossil based excess CO2 concentrations for the initial year of COVID are in good agreement with the previous five-year averages both at 115 m and 10 m elevations. These results also show seasonal variations of CO2 mole fractions, peaking in winter and decreasing in summer. Tree-ring results from Debrecen show a good alignment with the results of the atmospheric monitoring station, and it does not show a significant fossil contribution in the urban background area during the vegetation periods. Tree-ring results from Budapest show a stronger fossil contribution compared to the Debrecen ones. Our atmospheric CO2 results do not show a large decrease in fossil CO2 atmospheric contribution during the first lockdown. We found that the use of this passive CO2 monitoring technique can provide a valuable tool for investigating such differences.

Ecuador is a key area in South America when it comes to understanding the economic, social and archaeological aspects of pre-Hispanic cultures in the northwestern region of the Andes. Among the most complex societies to have inhabited this territory is the so-called Manteño culture (AD ∼800–1530), which spanned across most of Ecuador’s central Pacific coast. Ongoing research at the site of Ligüiqui (Manta, Manabí) has enabled us to obtain a more complete overview of the chronological sequence of the Manteño period as well as contributing further data on the advanced stage of social development reached during the period; characterized by the hierarchical arrangement of sites, the use of extensive settlement models, and semi-circular stone fish traps (corrales). In order to understand the role played by this coastal site in the complex Manteño culture, a detailed radiocarbon study was performed in the sequence of the Ligüiqui site. In addition, using a detailed review of available Manteño settlement radiocarbon data (13 sites and 64 dates), we established a chronostratigraphic framework for the culture. Our data indicate that Ligüiqui probably acted as a supply centre for marine-origin products from the twelfth century onwards with activity peaking during the Late Manteño period. A multisite comparison using Bayesian modeling indicates an early onset of the Manteño culture in Ligüiqui around AD 700, and a general demise in most of the sites AD ∼1500 or slightly before. This culture finally collapsed before AD ∼1600 during the early Spanish colonial period. Only one site, La Libertad, shows potential evidence of having remained a Manteño settlement after that date.

Highly precise and reproducible radiocarbon (14C) measurements are regularly performed at the Heidelberg Institute for Environmental Physics, Heidelberg, Germany, in collaboration with the radiocarbon laboratory of the Curt-Engelhorn-Center Archaeometry in Mannheim, Germany. Here, we report an update of the technical details, focusing on the analysis of cold-water corals (CWC), and present an improved long-term blank value with a mean of (0.190 ± 0.064) pMC (n = 138) and excellent reproducibility of the IAEA-C2 standard with a mean of (41.15 ± 0.16) pMC (n = 75), consistent with its certified consensus value. Furthermore, 33 duplicates of the CWC 14C measurements agree within 2σ, 85% even within the 1σ range. This provides excellent conditions for accurate 14C measurements. As an application example, we present combined 230Th/U and 14C ages of a coral-bearing sediment core from the upper Mauritanian slope. The resulting ventilation age record confirms decreasing ventilation between 30 and 25 kyr BP, most likely reflecting a northward propagation of a water mass originating from the south. During the LGM, we confirm a previously hypothesized southward displacement of the Cap Verde Frontal Zone. With the onset of the deglaciation, our record documents again an advance of a southern-sourced water mass into the subtropical North Atlantic. During the Bølling-Allerød warm period, strong ventilation fluctuations possibly indicate temporal influence of southern-sourced water.

Grand solar minima are periods spanning from decades to more than a century during which solar activity is unusually low. A cluster of such minima occurred during the last millennium, as evidenced by reductions in the numbers of sunspots observed and coeval increases in cosmogenic isotope production. Prior to the period of instrumental records, natural archives of such isotopes are the only resources available for detecting grand solar minima. Here, we examine the period 433–315 BCE, which saw a sustained increase in the production of the cosmogenic isotope, radiocarbon. Our new time series of radiocarbon data (Δ14C), obtained on cellulose extracted from known-age oak tree rings from Germany, reveal that the rise in production that occurred at this time was commensurate with patterns observed over recent grand solar minima. Our data also enhance, and to a degree challenge, the accuracy of the international atmospheric radiocarbon record over this period.

Excavation at the site of Bhagatrav yielded four layers of cultural deposits: the lowermost being the Sorath Harappan, the upper two are medieval, and layer three caps the Sorath Harappan layer. A horn-deity painted dish was found in a stratified context at the lowest level. The medieval deposit includes turquoise glazed and celadon wares, followed by an abundance of Monochrome Glazed Ware, which is otherwise known as Khambhat ware. The date of the Sorath Harappan layer of the site, the time and space of the horn-deity motif in the Harappan world, and the date of Khambhat ware have long been subjects of discussion. With the help of a series of absolute dating (radiocarbon and luminescence), this paper attempts to place the site, horn-deity motif, and the Khambhat ware in the cultural chronology of Gujarat.

A routine chemical procedure was developed at the Ede Hertelendi Laboratory of Environmental Studies (HEKAL), in Debrecen which can measure the dissolved organic radiocarbon content of groundwater as well as the inorganic and total fraction. The typical background of this non-purgeable dissolved organic radiocarbon preparation is 0.73 ± 0.14 percent modern carbon (pMC), using a carbon contamination correction on fossil dissolved material (potassium hydrogen phthalate) samples.

This paper presents the radiocarbon context of the megalithic monument El Amarejo 1, situated in the corridor of Almansa in the southern region of La Meseta in Spain. The monument was constructed using small and medium-sized masonry, comprising a short corridor and two separate chambers in which burials were carried out. The results of the 14C analyses of each of the 11 individuals documented indicate that the monument was in use between approximately 1900 and 1200 cal BC. Bayesian modeling of the radiocarbon dates allows for the proposition of hypotheses regarding the construction, utilisation dynamics, and abandonment of the monument. The combination of these new data with the analysis of the 14C dating of other burials from the Bronze Age of La Mancha reveals a complex and heterogeneous panorama. The evidence presented and analyzed in this paper suggests that burial practices associated with fortified settlements and their domestic areas shared space and time with the construction of megalithic monuments located near settlements.

We report a set of radiocarbon dating of prehistoric settlements located on the paleolake Baruun Khuree shores in the Gobi-Altai area, southern Mongolia. The obtained series of 11 AMS 14C measurements on charcoal and other charred plant macro-remains can be associated with one of the earliest episodes of the Holocene highly mobile desert-adapted hunter-gatherers activities from the Gobi desert (ca. 11,250–10,500 cal BP). Exploiting a wide range of environments, including dune fields, they are characterized by pottery usage and microblade core technology with wedge-shaped cores as well as osteological materials. These preliminary results are part of a project analyzing the nature of long-lasting prehistoric occupation around Tsakhiurtyn Hundi (Eng. Flint Valley)—one of the most extensive early prehistoric sites of Central Asia owing its name to the presence of abundant flint outcrops, lithic workshops and their innumerable flint artifacts.

Research by the Tlalancaleca Archaeological Project (PATP) has corroborated modifications to the Middle Formative chronology in Puebla-Tlaxcala (Lesure et al. 2006, 2014) using Bayesian modeling on 26 radiocarbon dates from Tlalancaleca. The present study is the first to evaluate the region’s Middle Formative chronology with radiocarbon dates from superposed stratigraphy. Nine Bayesian models were constructed with different combinations of radiocarbon dates and OxCal’s phase and sequence functions to determine the beginning and end of the Texoloc phase. Results place the Tlatempa-Texoloc transition at around 650 cal BC and the Texoloc-Tezoquipan transition at around 500 cal BC. The OxCal Interval function supports a timespan of approximately 150 years for the duration of the Texoloc phase. These results suggest the process of initial urbanization in Central Mexico was a rapid one.

By constraining organic carbon (OC) turnover times and ages, radiocarbon (14C) analysis has become a crucial tool to study the global carbon cycle. However, commonly used “bulk” measurements yield average turnover times, masking age variability within complex OC mixtures. One method to unravel intra-sample age distributions is ramped oxidation, in which OC is oxidized with the aid of oxygen at increasing temperatures. The resulting CO2 is collected over prescribed temperature ranges (thermal fractions) and analyzed for 14C content by accelerator mass spectrometry (AMS). However, all ramped oxidation instruments developed to date are operated in an “offline” configuration and require several manual preparation steps, hindering sample throughput and reproducibility. Here we describe a compact, online ramped oxidation (ORO) setup, where CO2 fractions are directly collected and transferred for 14C content measurement using an AMS equipped with a gas ion source. Our setup comprises two modules: (i) an ORO unit containing two sequential furnaces, the first of which holds the sample and is ramped from room temperature to ∼900°C, the second of which is maintained at 900°C and holds catalysts (copper oxide and silver) to ensure complete oxidation of evolved products to CO2; and (ii) a dual-trap interface (DTI) collection unit containing two parallel molecular sieve traps, which alternately collect CO2 from a given fraction and handle its direct injection into the AMS. Initial results for well-characterized samples indicate that 14C content uncertainties and blank background values are like those obtained during routine gas measurements at ETH, demonstrating the utility of the ORO-DTI setup.

Radiocarbon (14C) measurements on dissolved inorganic carbon (DIC) are a powerful tool to trace water masses and carbon cycling in the ocean. Existing methodologies to determine the 14C content of seawater DIC requires large volumes of sample (usually >100 mL) and specialized graphitization techniques to achieve the accuracy and precision needed for meaningful data interpretation. The advancement of the CO2 gas ionization accelerator mass spectrometry (AMS) technique today allows routine 14C measurements on small samples (<100 µgC) and may thus permit reducing the sample volumes needed to determine 14C content of seawater DIC to ∼2 mL. The proposed method utilizes the carbonate handling system (CHS), gas interface system (GIS) and MICADAS AMS, and provides good accuracy but reduced precision compared to established methods. Good accuracy is shown by comparing results for a marine in-house DIC standard and a DIC seawater profile from Antarctica between the proposed CHS-GIS-MICADAS approach and reference measurements conducted on the same material at established laboratories (ETH and NOSAMS). Further, two sedimentary porewater profiles from a fjord system in Svalbard are presented. Despite good agreement, the precision of the CHS-GIS-MICADAS approach is reduced, potentially limiting possible interpretations on seawater DIC. Nonetheless, the reduction of sample volumes proves particularly helpful to analyze porewater DIC from sediment cores, where sample material is notoriously limited, reduces the required amounts of toxic HgCl2 and simplifies expedition logistics.

Radiocarbon (14C) dating of soil samples by accelerator mass spectrometry (AMS) has been proven useful for studying carbon (C) cycling in terrestrial ecosystems. However, this application has two primary difficulties in sample preparation: inhibition of graphite formation due to sulfur (S)-containing impurities and contamination of samples with modern C (MC). Herein, we evaluated these effects using three sample preparation methods (silver foil, silver wire, and Sulfix) by conducting AMS-14C measurements of a 14C-dead charred wood and S-rich soil samples. The preparation methods were all successful in graphite formation and AMS-14C measurement for soil samples with an organic S content <6.9 wt%. The methods showed different percent modern carbon (pMC) values from 0.16% to 0.64% for the 14C-dead sample. The results also revealed that across different methods, MC contamination can be significantly reduced by applying two-step procedure (combustion and subsequent reaction to remove S-containing impurities) during sample preparation. The three methods had a negligible influence on determining the 14C age for samples that were at least younger than 12,000 yr BP. As the 14C ages of the soil samples are typically younger than 12,000 yr BP, any method explored in this study can be employed for 14C dating with sufficient accuracy for application to C cycle studies.

Most of the carbonate samples have a basic well-defined pretreatment protocol for 14C-AMS dating, but particularities of specific organisms have to be treated with care. This is the case of stromatolite samples, in which carbonate is formed by biogenesis and also has a porous structure that could contain recent organic material as a contaminant. In this work, we analyzed the differences in the radiocarbon content by using organic matter removals before chemical treatment with HCl: sodium hypochlorite (NaOCl) a 0.7M solution with pH ∼11, and hydrogen peroxide (H2O2) an 8.8M solution with pH ∼5. These treatments were chosen because they are the most used in stromatolite samples for geochemical analysis. To compare the impact of the organic matter removal treatments in stromatolite samples we also processed them as regular carbonate samples for radiocarbon analysis, with no organic matter removal (control samples). X-ray diffraction and X-ray fluorescence have been used to obtain mineral and elemental characterization, respectively. H2O2 could not influence the results of Mg-calcite concentrate samples. The use of NaOCl appears to have been effective in preserving more material than H2O2 independent of the mineralogical composition of the stromatolite layers. The F14C results after HCl etching for Mg-calcite concentrated samples were similar to those without etching suggesting that the HCl etching does not impact the results in this case. The organic matter removal is more important than the etching procedure for stromatolite samples. NaOCl is more indicated to be used as chemical pretreatment for radiocarbon analysis purposes independent of the mineral matrix of samples.

Ocean radiocarbon (14C) is a proxy for air-sea exchange, vertical and horizontal mixing, and water mass identification. Here, we present five pre- to post-bomb coral Δ14C records from West Flower Garden Bank and Santiaguillo reefs in the Gulf of Mexico, Boca de Medio, and Isla Tortuga near the Cariaco Basin north of Venezuela. To assess basin-wide Δ14C variability, we compiled the Atlantic Ocean reef-building surface coral Δ14C records (24 corals and 28 data sets in total) with these new records. Cumulatively, the Δ14C records, on their independent age models, reveal the onset of post-bomb Δ14C trends in 1958 ±1 to 2 years. A general decrease in maximum Δ14C values occurs with decreasing latitude reflecting the balance between air-sea gas exchange and surface water residence time, vertical mixing, and horizontal advection. A slightly larger atmospheric imprint in the northern sites and relatively greater vertical mixing and/or advection of low-14C waters influence the southern Caribbean and eastern Atlantic sites. The eastern Atlantic sites, due to upwelling, have the lowest post-bomb Δ14C values. Equatorial currents from the eastern Atlantic transport low Δ14C water towards the western South Atlantic and southern Caribbean sites. Decadal Δ14C averages for the pre-bomb interval (1750–1949) for the low latitude western Atlantic are relatively constant within analytical (3–5‰) and chronological uncertainties (∼1–2 years) due to mixing and air-sea exchange. The compiled Δ14C records provide updated regional marine Δ14C values for marine reservoir corrections.

Western Zhou Dynasty (ca. 1046–771 BC) was established soon after conquering the Shang Dynasty (ca. 1600–1046 BC) and brought about the earliest enfeoffment system in Chinese history. Yan was one of the vassal states of the same clan as Zhou. According to historical records, the capital of Yan state was located near Yan mountain, which is now known as the Liulihe site in the Fangshan District, Beijing. This study carries out the high-precision dating of two newly discovered Western Zhou Dynasty noble tombs at the Liulihe site. The man in tomb M1902 participated in the groundbreaking ceremony of Yan’s capital according to inscriptions on the bronze vessel found in this tomb. Samples of different materials, especially different parts of human skeletons from the tombs, were selected to form a sample series in chronological order. Wiggle-matching models were established in OxCal program based on the growth and development time of different teeth and bones of human skeletons. More accurate ages were acquired for the death of the individuals. The results indicate that the most probable distribution range of the death date of the individual in M1902 is about 1045–1010 BC. The radiocarbon dates of M1902 give important chronological information about the founding of Yan state, and they are very close to those of the year in which King Wu of Zhou conquered the Shang Dynasty.

Ever since the first discovery of urn burials in eastern Serbia during the 1980s, their dating has been uncertain and based on distant analogies and typological parallels. In this paper, we present radiocarbon dates from five urn cemeteries and three associated settlement sites, showing that the initial dating (Late Bronze Age; 14th–11th BCE) is highly questionable. Instead, radiocarbon dating and modeling presented here connect the urn cemeteries—characterized by a specific grave architecture and associated with settlements that display evidence of copper production—to a period between the 20th and 16th centuries BC. The fact that many of our dates come from cremated bones requires a discussion with regard to the circumstances of carbon exchange during cremation. The absolute dates thus far available for most urn cemeteries from the neighboring regions of the Balkans are all markedly younger (15th–11th century BC) than the data presented here and fall in the frame of the overall expansion of cremation in Europe during the Urnfield period. The new absolute dates from eastern Serbia provide a possibility to change our understanding of the Bronze Age dynamics of the 2nd millennium in the broader area of southeastern Europe and indicate a much earlier acceptance of cremation among certain groups than previously thought.