As most analysts recognize, the method generally used for the determination of carbon dioxide present as carbonate, by decomposition with acid, absorption in soda-lime or soda-asbestos, and weighing as carbon dioxide, is open to several objections; and several suggestions have been made from time to time with the object of avoiding the use of absorption tubes, but none of these have come into general use, generally because of inconvenience in manipulation.
The principal objection to the use of absorption tubes (apart from their general inconvenience and the numerous precautions their use entails) lies in the uncertainty of the blank correction; when a blank experiment is performed, under precisely the same conditions as the actual determination, a small gain in weight of the absorption tubes is almost invariably observed, but in a series of several blank experiments, this gain is frequently very variable, and by no means proportional to the volume of air drawn through the absorbers, unless many precautions are observed.