We present the results of the distribution of CO-dark H2 gas in a sample of 2223 interstellar clouds in the inner Galaxy (l=−90° to +57°) detected in the velocity resolved [CII] spectra observed in the GOT C+ survey using the Herschel HIFI. We analyze the [CII] intensities along with the ancillary HI, 12CO and 13CO data for each cloud to determine their evolutionary state and to derive the H2 column densities in the C+ and C+/CO transition layers in the cloud. We discuss the overall Galactic distribution of the [CII] clouds and their properties as a function Galactic radius. GOT C+ results on the global distribution of [CII] clouds and CO-dark H2 gas traces the FUV intensity and star formation rate in the Galactic disk.

Attempting to distangle density and kinetic temperature of the star forming molecular gas in the central regions of galaxies, we have embarked on a project involving sensitive measurements of a variety of formaldehyde (H2CO) and ammonia (NH3) transitions. Preliminary results, based on observations from the Green Bank Telescope (GBT) and the Very Large Array (VLA) are summarized and an outline for the entire project is given.

Cool neutral gas provides the raw material for all star formation in the Universe, and yet, from a survey of the hosts of high redshift radio galaxies and quasars, we find a complete dearth of atomic (Hi 21-cm) and molecular (OH, CO, HCO+ & HCN) absorption at redshifts z ≳ 3 (Curran et al. 2008). Upon a thorough analysis of the optical photometry, we find that all of our targets have ionising (λ ≤ 912 Å) ultra-violet continuum luminosities of LUV ≳ 1023 W Hz−1. We therefore attribute this deficit to the traditional optical selection of targets biasing surveys towards the most ultra-violet luminous objects, where the intense radiation excites the neutral gas to the point where it cannot engage in star formation (Curran & Whiting 2010). However, this hypothesis does not explain why there is a critical luminosity, rather than a continuum where the detections gradually become fewer and fewer as the harshness of the radiation increases. We show that by placing a quasar within a galaxy of gas there is always a finite ultra-violet luminosity above which all of the gas is ionised. This demonstrates that these galaxies are probably devoid of star-forming material rather than this being at abundances below the sensitivity limits of current radio telescopes.

When galaxies merge the resulting conditions are some of the most extreme found anywhere in nature. Large gas flows, shocks and active black holes all can affect the ISM. Nearby merging galaxies with strong starbursts are the only places where we can conduct detailed study of star formation in conditions that mimic those under which the majority of stars in the universe formed. Here we study molecular gas tracers in 8 galaxies selected from the VIRUS-P Investigation of the eXtreme ENvironments of Starbursts (VIXENS) survey. Each galaxy has also been observed using the integral field unit spectrograph VIRUS-P, allowing us to investigate the relation between the chemical state of the gas, star formation and total gas content. Full details can be found in Heiderman et al. (2011). Here we report on new results obtained from IRAM-30m/NRO-45m 3mm line surveys towards 14 positions in these 8 merging galaxies. We detect ≈ 25 different molecular transitions towards these objects, many which have never been observed in these galaxies before. Our measurements show that the mean fraction of dense gas increases in later-stage mergers (Fig. 1, left), as does the average optical depth of the gas. Molecular diagnostic diagrams (Fig. 1, right) show that molecular regions we probe are, in general, UV photon dominated. Triggered AGN activity, and/or cosmic ray ionisation (from SNe II in the starburst) are not yet energetically important in determining the state of the gas.

We study the redshift evolution of neutral and molecular gas in the interstellar medium with the results from semi-analytic models of galaxy formation and evolution, which track the cold gas related physical processes in radially resolved galaxy disks. Two kinds of prescriptions are adopted to describe the conversion between molecular and neutral gas in the ISM: one is related to the gas surface density and gas metallicity based on the model results by Krumholz, Mckee & Tumlinson; the other is related the pressure of ISM. We try four types of star formation laws in the models to study the effect of the molecular gas component and the star formation time scale on the model results, and find that the H2 dependent star formation rate with constant star formation efficiency is the preferred star formation law. We run the models based on both Millennium and Millennium II Simulation haloes, and the model parameters are adjusted to fit the observations at z = 0 from THINGS/HERACLES and ALFALFA/COLD GASS. We give predictions for the redshift evolution of cosmic star formation density, H2 to HI cosmic ratios, gas to star mass ratios and gas metallicity vs stellar mass relation. Based on the model results, we find that: (i) the difference in the H2 to HI ratio at z > 3 between the two H2 fraction prescriptions can help future observations to test which prescription is better; (ii) a constant redshift independent star formation time scale will postpone the star formation processes at high redshift and cause obvious redshift evolution for the relation between gas metallicity and stellar mass in galaxies at z < 3.

We investigate the formation of molecular hydrogen on ISM dust grains at T < 10 K. We use laboratory methods to detect newly formed D2 that is rovibrationally excited at v” = 4, J” = 2. We discover that recombination is catalyzed by pre-existing molecules on the dust surface and present this an important process in the coldest regions of the ISM.

Interactions and mergers of gas-rich galaxies are important drivers of galaxy evolution, in particular in reshaping spirals and fueling powerful starbursts and supermassive nuclear black holes. Hubble Space Telescope observations of nuclei in merging galaxies have shown an increasing nuclear luminosity density in the optical/near-infrared light with advancing merger stage (Laine et al. 2003, Rossa et al. 2007, Veilleux et al. 2009, Haan et al. 2011a), suggesting an increase of nuclear starburst activity. To address the physical conditions in major mergers and excitation mechanisms such as shocks and starbursts, it is necessary to resolve the spatial variations of the warm dust, molecular gas, and ionized gas on subgalactic scales. Here we summarize the main results based on Spitzer IRS spectral mapping observations of a sample of eight nearby, IR-bright galaxies of the Toomre Sequence (Toomre & Toomre 1972) that span the range from early through mid- to late-stage major mergers (Haan et al. 2011b).

We find that the cold molecular gas component as observed in the CO emission line does not correlate with the warm gas in early merger systems, leading to large spatial variations in the ratio of cold-to-warm molecular gas. In particular, the cold molecular gas distribution in NGC 4676 and NGC 6621 show a significant offset not only from the warm gas component, but also from the stellar (NIR) and dust distribution (PAH, mid-IR continuum). On locally resolved scales within a merger, we find an intrinsic relation between H2 and PAH flux as given by a power law with a very similar exponent (0.61 ± 0.05) for all galaxies but with a constant that can vary up to a factor of ten between different galaxies. These findings suggest a common dominant excitation mechanism for H2 emission over a large range of global H2/PAH flux ratios in major mergers. The spatial extent of the warm gas component (H2) is larger than for the PAH emission (in all galaxies but more extrem in mid-stage merger), which leads to an increase of the H2/PAH ratio as function of radius. Two merger systems (NGC 7592 and NGC 6621) show evidence for buried star formation in overlap regions between the nuclei, namely strong PAH, [Ne II], [Ne III] and warm gas (H2) emission, but no apparent corresponding CO (J = 1−0) emission. Our findings also demonstrate that the variations of the physical conditions within a merger are much larger than any systematic trends along the Toomre Sequence.

Ammonia (NH3) was the first polyatomic molecule observed in the ISM. Its importance in interstellar molecules is only second to CO because its rovibrational spectroscopic signature can be used very effectively at deducing the conditions of the interstellar environment such as temperature and density, and because it is found in so many different interstellar objects in a wide temperature range. However, experimental determination of NH3 IR spectra is extremely difficult due to the large-amplutide inversion vibration, and the existing HITRAN2008 database for NH3 is limited in temperature, coverage, completeness, and accuracy. With rapid progress in theoretical chemistry and computational resources, now we are able to generate a highly reliable/accurate IR line list of NH3 (and its isotopologues) for astronomical studies. Exact quantum rovibrational computations on an empirically refined potential energy surface (with nonadiabatic corrections included) have achieved accuracies of 0.02-0.05 cm−1 (for line position) and better than 85-95% (for line intensity) for both NH3 and 15NH3 spectra. The unique feature of our work is that our predictions are essentially as accurate as reproducing existing measurements, suitable for synthetic simulation of various astrophysical environments or objects. The reliabilty and accuracy of our predictions for missing bands and higher energies computed on HSL-2 (Fig. 1) have been proved by the most recent high-resolution experiments and extended up to 7000 cm−1. See Huang et al. 2008, Huang et al. 2011, & Sung et al. 2012 for more details.

We describe an on-going 194-671 μm spectroscopic survey of a flux-limited sample of 125 local luminous infrared galaxies (LIRGs) with Herschel SPIRE Fourier Transform Spectrometer (FTS). The survey targets primarily the CO spectral line energy distribution (SLED), from J = 4-3 up to J = 13-12, to probe dense and warm molecular gas that should play an intimate role in star formation and/or active galactic nuclear activities in these galaxies. The program is about 75% finished. At S/N > 5, besides the CO lines, we also detected [N ii] 205 μm and [C i] 370 μm (3P2 − 3P1) lines in every target observed. In about half of the observed targets, we also detected [C i] 609 μm (3P1 – 3P0).

This work reports the chemical evolution of adenine, alanine & glycine along with their precursor molecules during the collapsing phase of protostars. Since the abundances of these three molecules are not in the detectable range, we are proposing to observe some of its pre-cursor molecules to predict the abundances of these bio-molecules. We perform a higher order quantum chemical simulation to provide detailed spectroscopic knowledge of the precursor of these bio-molecules in the infrared and electronic range. These pre-biotic molecules could be produced in the gas phase as well as in the ice phase. Spectral properties significantly vary depending upon the environment around these molecules. To approximate recent observational/experimental features, we conduct our simulation for various astrophysical conditions. We found that our results are in line with the some recent experiments and observations.

We present Atacama Large Millimeter/submillimeter Array (ALMA) and Australia Telescope Compact Array (ATCA) data of molecular absorption lines toward the bright central core of the prominent, nearby (d ∼ 3.8 Mpc) radio galaxy Centaurus A, at 13, 7, 3, and 1mm wavelengths. The line of sight crosses the prominent dust lane and continues through the disk and eventually through gas that may be very close to the central supermassive black hole. The goal of our survey is to determine the physical conditions of the gas via analyses of molecular line tracers including molecular abundances and excitation conditions that are sensitive to changes in temperature, density, ionization, and shocks. This study allows us to derive the physical processes that are shaping each molecular environment.

The evolution and dynamics of the molecular cores traced by 13CO J = 1 → 0 emission in the Taurus molecular cloud are studied. We performed a systematic examination of the distribution and dynamic state of cores in a large contiguous region, as well as the core ages, which lie between 106 and 107 years. The core velocity dispersion (CVD), which is the variance of the core velocity difference δ v, exhibits a power-law behavior as a function of the apparent separation L, i.e. CVD (km/s) ∝ L (pc)0.7, with similarities to Larson's law for the velocity dispersion of the gas.

Previous studies of the molecular gas excitation in high-redshift galaxies have focused on galaxy-wide averages of CO line ratios. However, it is possible that these averages hide spatial variation on sub-galactic scales, disguising the true distribution and conditions of the molecular gas within star-forming galaxies. Even in the pre-ALMA era we have begun to see evidence for spatial variation of CO excitation in both rest-UV selected and submillimeter-selected galaxies at z > 2, aided both by the increased frequency coverage of the Jansky Very Large Array (allowing high-resolution observations of the CO(1–0) line, the best tracer for the coldest molecular gas) and by the benefits of gravitational lensing for spatially extended sources. We show new results for multiple high-redshift systems that reveal spatial and/or spectral variations in CO excitation, including an early-stage merger that has different conditions in its two components, thereby illustrating the need for high spatial and spectral resolution mapping in order to accurately characterize the molecular ISM in high-z galaxies.

Dwarf irregular galaxies are usually low-metallicity objects, and show ongoing or very recent star formation, giving rise to their irregular appearance. Especially HII galaxies, a sub-category of dwarf irregulars showing unusually high star formation activity, are believed to be among the least evolved galaxies in existence today. Therefore, they are very interesting objects for studies of early galaxy evolution and of metallicity enrichment mechanisms.

Several groups have developed theoretical evolutionary models of galaxies of this type, describing different possible formation and evolutionary scenarii, and varying factors such as gas infall and outflow, as well as the star formation history, and making predictions about their chemical evolution. One way to evaluate these models is by determining the metallicities of the different components of these galaxies, their gas and stars.

We examine a sample of HII galaxies from the Sloan Digital Sky Survey, which possibly contains the largest homogeneous sample of HII galaxy spectra to date. Using very restrictive selection criteria, which guarantee a sample of high quality spectra and avoid “contamination” by spectra of objects of other nature, we defined a sample of ∼ 700 HII galaxies spectra.

Through emission line strength calibrations and a detailed stellar population synthesis, we determined the metallicities of both the gas and the stellar content of these galaxies.

For HII galaxies up to stellar masses of 5 × 109M⊙, we find enrichment mechanisms not to vary with galactic mass, being the same for low- and high-mass galaxies on average. They do seem to present a greater variety at the high-mass end, though, indicating a more complex assembly history. Our results favour galaxy evolutionary models featuring constantly infalling low-metallicity clouds that retain part of the galactic winds. Above 5 × 109M⊙ stellar mass, the retention of high metallicity gas by the galaxies' gravitational potential dominates.

I would like to thank the Fundação de Amparo à Pesquisa do Estado do São Paulo (FAPESP) for financial support.

We have performed a survey study of rotational excited-state H2 Lyman-Werner absorption lines in the entire FUSE Magellanic Clouds Legacy archive. These lines reflect the UV pumping and formation conditions of H2, enabling a more comprehensive study of H2 gas properties, e.g. J-level populations N(J) and b-values (generally indicating the velocity dispersion). Combining with our previous measurements of N(Hi) and N(H2), we derived H2 excitation temperatures, gas volume density n(H), and local UV radiation field strength IUV for each sight line. The results indicate a weaker correlation between n(H) and IUV in Magellanic Clouds than the Galactic sight lines. We also obtained N(H)/E(B − V) ratios from the Spitzer-SAGE and previous CO J = 1 − 0 / Hi 21 cm surveys at sight line locations, using dust modeling and standard line brightness-column density conversion factors. They show a roughly linear correlation with absorption-based N(H)/E(B − V) values, and have a similar scatter (∼0.7 dex) across the LMC and SMC.

The [N ii] line is a major coolant in ionized interstellar medium, and is expected to be a good star formation rate indicator. Here we present a statistical study of [N ii] line emission for a large sample of local luminous infrared galaxies (LIRGs) using Herschel SPIRE FTS data (Lu et al. 2012; Zhao et al. 2012, in preparation). For our sample of galaxies, the [N ii] to the total infrared luminosity ratio (L[Nii]/LIR) varies from ∼ 10−5 to ∼ 10−4. We investigate the correlation between L[Nii] and LIR, as well as the dependence of L[Nii]/LIR on LIR, infrared colors (f60/f100) and the OIII 88 μm to [N ii] luminosity ratio. We find that L[Nii] strongly, and almost linearly correlates with LIR for star-forming galaxies, namely log LIR = (4.23 ± 0.33) + (0.99 ± 0.05) log L[NII] (see Fig. 1). The scatter in this relation is mainly due to the variation of hardness, and/or high ionization parameter, of the background UV field.

Infrared (IR) observations provide significant information on the lifecycle of dust grains in the interstellar medium (ISM), which is crucial for the understanding of the evolution of matter in the universe. The IR spectral energy distribution (SED) of the dust emission tells us the relative abundance of sub-micron grains, very small grains, and carriers of the unidentified infrared (UIR) emission bands, since they emit the far-IR, the mid-IR, and the UIR bands from the near- to mid-IR, respectively. On the other hand, the UIR emission bands themselves offer a useful means to probe the physical conditions from which the band emission arises because each band is assigned to a specific C-H or C-C vibration mode and because its relative intensity should reflect the properties of the band carriers and the physical conditions of the environment. Here the two diagnostic methods using IR observations are briefly described together with examples of the observational results. Implications for the dust lifecycle are also discussed.

Within galaxies, gas and dust are constantly exchanged between stars and the interstellar medium (ISM). The life-cycle of gas and dust is the key to the evolution of galaxies. Despite its importance, it is has been very difficult to trace the life-cycle of gas and dust via observations. The Spitzer Space Telescope and Herschel Space Observatory have provided a great opportunity to study the life-cycle of the gas and dust in very nearby galaxies, the Magellanic Clouds. AGB stars are more important contributors to the dust budget in the Large Magellanic Cloud (LMC), while in the Small Magellanic Cloud (SMC), SNe are dominant. However, it seems that the current estimates of the total dust production from AGB stars is insufficient to account for dust present in the ISM. Other dust sources are needed, and supernovae are promising sources. Alternatively the time scale of dust lifetime itself needs some revisions, potentially because they could be unevenly distributed in the ISM or clumps.

With AKARI, we have performed a systematic study of interstellar dust grains in various environments of galaxies. In many cases, the IR emission of dust is an important tool to trace star-forming activities in galaxies. However it is much more than just star-formation tracers. AKARI has revealed the detailed properties of dust grains in regions not relevant to star formation as well, some of which are found not to follow our old empirical knowledge. Because of its unique capabilities, such as near- and far-IR spectroscopy, and all-sky coverage, AKARI has provided new knowledge on the processing of carbonaceous grains including polycyclic aromatic hydrocarbons. We present the latest results obtained from our AKARI observations of the ISM in our Galaxy and nearby galaxies.

The Herschel-ATLAS (H-ATLAS) will provide an unrivalled sample of galaxies, probing the normal star-forming submillimetre population of galaxies for the first time. Here, we exploit the Science Demonstration Phase (SDP) data to model the evolution of the interstellar content of galaxies in recent history. The most massive H-ATLAS galaxies show a large increase in the dust content five billion years ago compared to the present epoch. These observations are difficult to explain using standard dust models, one possibility could be contributions from a non-stellar source of dust e.g. grain growth in dense clouds; this would imply that less than 10% of dust would be condensed in stellar atmospheres. Alternatively, an initial mass function which becomes top heavy at high star formation rate densities could also explain this discrepancy.