A detailed radiocarbon chronology has been established for the deep-sea core CT85-5 from the Tyrrhenian Sea. This chronology, which is based on the analysis of foraminifera shells, shows a set of reversed 14C ages for sediments deposited during the eruption of the Campanian Ignimbrite (∼40 ka cal BP). The anomalous young 14C ages coincide with elevated concentrations of 10Bc measured in the same core. Although reversals in 14C ages have been previously found in other records at 40 ka cal BP, such extreme changes have not been observed elsewhere. The enhancement in 14C concentration in CT85-5 sediments associated with the Campanian Ignimbrite is equivalent to an apparent age ∼15 ka younger than the age for the sediments deposited shortly before the eruption. Here, we present consistent results of repeated measurements showing no analytical problems that can explain the observed rapid changes in 14C of this particular record.

Procedures and equipment used in the University of Wisconsin laboratory have been described in previous date lists. Except as otherwise indicated, wood, charcoal, and peat samples are pretreated with dilute NaOH—NA4P2O7 and dilute H3PO4 before conversion to the counting gas methane; when noted, marls and lake cores are treated with acid only. Very calcareous materials are treated with HCL instead of H3PO4. Pretreatment of bone varies with the condition of the bone sample; solid bone with little deterioration is first cleaned manually and ultrasonically. The bone is treated with 8% HCL for 15 minutes, then dilute NaOH—Na4P2O7 for 3 hours at room temperature, washed until neutral, and the collagen extracted according to Longin (1971). Charred bone is treated with dilute HCL, NaOH—Na4P2O7, and then dilute HCL again.

The South Pacific Ocean contributes to the global carbon cycle by exchanging CO2 between the atmosphere and intermediate to deep water masses. The path of the Antarctic Intermediate Water (AAIW) in the South Pacific gyre has been inferred from salinity, oxygen, and nutrient measurements, but radiocarbon (14C) measurements—a direct tracer of the carbon cycle—remain sparse. Here, we present the first radiocarbon profiles in the western Coral Sea and compare our measurements with South Pacific stations from GLODAPv2, a database of ocean hydrochemistry. Surface and subsurface waters in the Coral Sea cannot be attributed to a single source based on their Δ14C signatures, and we observe a penetration of bomb-produced 14C. AAIW in the western Coral Sea shows Δ14C values comparable to those in the South Pacific gyre, consistent with circulation of AAIW in the lower part of the southern equatorial current. The deep waters of the western Coral Sea have significantly higher 14C than the South Pacific at the same isopycnal, consistent with a northward intrusion of Circumpolar Deep Water from the Tasman Sea, along with a westward influx of deep waters from the Central Pacific. In accordance with silicate concentrations published previously, this shows the dual origin of deep waters in the Coral Sea.

Previous studies of live-collected pre-weapons testing mollusk shells in the northern Gulf of California have demonstrated that the local radiocarbon reservoir effect (ΔR) is large and highly variable. To test the validity of this observation for paired charcoal and shell samples from archaeological contexts, we dated samples from four shell midden locations and six midden layers from the eastern shoreline of the Gulf of California near Puerto Peñasco, Sonora, Mexico. Dated charcoal samples were small twigs or brushy plants used to cook shellfish and the shells dated within each midden showed signs of burning. Ages range from approximately 5700 to 1900 cal BP. The offset between the modeled marine 14C age for calibrated ages of the middens and measured shell 14C age (ΔR) averaged 425 yr with a standard deviation of 115 yr.

All samples processed from November 1971 through January 1973 at the Illinois State Geological Survey Radiocarbon Dating Laboratory are reported here. The benzene liquid scintillation technique was used. Laboratory procedures used were the same as those reported by Coleman (1973), with the exceptions that bone collagen was separated by the Longin (1970; 1971) technique and acetylene was trimerized to benzene as described by Coleman, et al (1972).

The monastery of St. John in Müstair, a UNESCO world heritage site, preserves archaeological remains and stone structures dated from the 8th century to the present. It has been extensively studied archaeologically so that numerous samples of historical materials, including mortar, are available for study. In addition to that, some of the structures have been precisely dated with dendrochronology. The monastery is located in a region characterized by dolomite rocks and the mortars are therefore of dolomitic nature, being perfectly suited to test the possibility of being dated with 14C. Furthermore, the presence of embedded carbon fragments has provided additional independent data to support or deny the results of mortar dating. A comparison of the results obtained from radiocarbon (14C) dating of bulk mortars, sieved fractions enriched in binder, lime lumps and carbon fragments, for two samples is presented, in relation to the petrographic characterization and the mineralogical phase content. This preliminary study shows that the dating of 14C can potentially be applied to the mortar of Müstair, as results in accordance with the established chronologies have been obtained for one sample. However, if the dolomitic sand contamination is very high, further studies are needed to develop a specific sample preparation technique.

We have performed a new determination of the half-life of 41Ca by measuring the specific activity of an enriched Ca material with known 41Ca abundance. We measured the activity via the 3.3-keV X-rays emitted in the electron capture decay of 41Ca, and the 41Ca abundance was measured by low-energy mass spectrometry. The result, t1/2 = (1.01 ± 0.10) × 105 yr, agrees with the recent ‘geological’ half-life of Klein et al., (1991), t1/2 = (1.03 ± 0.07) × 105 yr, and with the corrected value of Mabuchi et al. (1974), t1/2 = (1.13 ± 0.12) × 105 yr. We recommend the weighted mean of these three measurements, t1/2 = (1.04 ± 0.05) × 105 yr, as the most probable half-life of 41Ca. We also discuss the situation of the radioisotopes, 32Si, 44Ti, 79Se and 126Sn, whose half-lives, though still uncertain, are potentially interesting for future AMS studies and other applications.

Radiocarbon (14C) analysis of carbon dioxide (CO2) provides unique information on the age, turnover and source of this important greenhouse gas, raising the prospect of novel scientific investigations into a range of natural and anthropogenic processes. To achieve these measurements, cartridges containing zeolite molecular sieves are a reliable and convenient method for collecting CO2 samples. At the NERC Radiocarbon Facility (East Kilbride) we have been refining our molecular sieve methods for over twenty years to achieve high-quality, reproducible and precise measurements. At the same time, we have been developing novel field sampling methods to expand the possibilities in collecting gas from the atmosphere, soil respiration and aquatic environments. Here, we present our latest improvements to cartridge design and procedures. We provide the results of tests used to verify the methods using known 14C content standards, demonstrating reliability for sample volumes of 3 mL CO2 (STP; 1.6 mg C) collected in cartridges that had been prepared at least three months earlier. We also report the results of quality assurance standards processed over the last two years, with results for 22 out of 23 international 14C standards being within measurement uncertainty of consensus values. We describe our latest automated procedures for the preparation of cartridges prior to use.

Accelerator mass spectrometry (AMS) at the milligram level is routinely performed, but it is difficult to go substantially below 100 μg of carbon. We discuss various approaches for sample preparation, machine operation and data evaluation, to meet the special requirements of 14C AMS measurements at the microgram-carbon level. Furthermore, we present first results obtained at the Vienna Environmental Research Accelerator (VERA) from 14C measurements of a snow sample from Gaithersburg, Maryland, USA, prepared at the National Institute of Standards and Technology (NIST).

The traditional archaeological chronology in the Japanese Islands during the Jomon period was essentially based on the relative age given to cord-impressed patterns marked on pottery, as well as the shape of the pottery and the thickness of the cultural layers that were excavated. We aimed to correlate the classical archaeological chronology with calibrated radiocarbon dates, to posit a new chronology for the Jomon period in northeastern Japan. We calibrated 80 accelerator mass spectrometry (AMS) 14C dates from NE Japan and reconstructed a chronological timetable for Hokkaido and the Tohoku District. We collected 43 samples from 5 shellmounds and 2 archaeological sites on Hokkaido Island and 4 shellmounds in the Tohoku District in order to determine the calibrated age of their sites. ΔR values used on Hokkaido Island and the Tohoku District were between 282 and –158 yr and between ±0 and –40 yr, respectively. The large ΔR value for the eastern part of Hokkaido Island indicates the influence of the Oyashio Current, while an anomalous ΔR value was obtained from northern Hokkaido Island. These figures show larger apparent ΔR values than those from southwest Japan (Nakamura et al. 2007). The calibrated Jomon period in the investigated area was from 2000 to 200 yr younger than the previous chronology. Calibrated 14C ages of the shellmounds investigated ranged between ∼6000 and 3000 yr, correlating to the Early Jomon and Final Jomon periods as indicated by the former archaeological chronology of Honshu Island.

In the Valencia region of Spain, the dominant use of natural caves for collective burials during the Late Neolithic and Chalcolithic periods has been documented. Collective burials are central to the hypothesis about social relationships in Copper Age societies from Iberia, and key to interpreting kinship-based societies. Les Llometes (Alcoi, Alicante) is one of the biggest collective burial sites existing in eastern Iberia. This article presents the direct 14C dates on 25 skeletal remains at the site. The results indicate that the site was used as a burial place from the end of the 5th millennium cal BC until the end of the 4th millennium cal BC, and is a first milestone for future studies that will shed light on the transition towards social structure through the use of a cemetery space. Moreover, this research is one of the few investigations of Late Neolithic collective burials in Iberia that comprises an extensive accelerator mass spectrometry (AMS) 14C data set of almost all the individuals reported at a single site. This case also serves to highlight the utility of revisiting materials from historic excavations by 14C dating all the skeletal remains that define the minimum number of individuals, and therefore ensuring a more complete picture of the prehistoric human record.

The development of radiocarbon dating for degraded bone samples collected at Korean archaeological sites has been successful through the characterization of raw bone C/N ratios and application of an ultrafiltration method. It was found that the C/N ratios of raw bone samples are inversely proportional to the carbon content and residue amount after gelatinization. We have examined a few dozen Korean archaeological bone samples for this study. Well-preserved bone samples are found to be physically dense. The range of C/N ratios of Korean raw bone samples ranged from 3.4 to 74. We found that the C/N ratios of degraded raw bone samples can be used to determine whether 14C samples are acceptable for normal pretreatment processing and eventual dating. The results of this study support that even if the C/N ratio of a degraded raw bone sample is 11, extraction of collagen for bone dating is feasible by a carefully designed ultrafiltration process. Our preliminary 14C dating results of a depth profile of Gunang-gul Cave, an archaeological site in Danyang, Korea, indicate that this site has been either geologically or anthropologically disturbed in the past, with 14C ages ranging from 28,910 ± 200 to 48,090 ± 1050 yr BP. The C/N ratios of the collagen samples of Gunang-gul were determined to be 3.2–3.6. Our study establishes a new guide for the pretreatment of degraded bone samples such as those collected in Korea for 14C dating.

We used the radiocarbon wiggle-match dating technique to date the varved sediments of Lake Gyltigesjön in southern Sweden with the main aim to construct an accurate chronology covering the period between about 3000 and 2000 cal BP. Wiggle-match dating was applied to bulk sediments to evaluate the possibility of constructing accurate chronologies in the absence of terrestrial plant macrofossils and when the amount of old carbon in the sediments is unknown. Facilitated by a floating varve chronology and relatively stable 14C reservoir ages, the results show the possibility to assess the contribution of old carbon solely based on the 14C wiggle-matching of bulk sediments. We confirm the wiggle-matched chronology and the 14C reservoir age of approximately 260 yr by cross-checking the results with 14C dating of macrofossils. The obtained calibrated ages based on bulk sediments have an uncertainty range of about 60–65 yr (95.4% confidence interval). This study confirms that 14C wiggle-match dating of bulk sediments is a viable tool when constructing high-resolution chronologies. The method is especially useful in Sun-climate studies since the timing between solar activity variations (expressed as 14C variations) and climate changes can be accurately determined.

The “governor’s residency” at Tel ‘Eton was destroyed in the late 8th century BCE in an Assyrian military campaign. While the numerous finds enable a detailed reconstruction of life on the eve of the destruction, this elite house was cleaned continuously, and since no floor raisings were identified, little was known of the building’s period of use. Radiocarbon (14C) samples taken from within a foundation deposit and from the floor make-up, however, indicate that the earliest phase of the residency was built in the late 11th–10th century BCE. This has bearings on the date in which social complexity evolved in Judah, on the debate regarding the historicity of the kingdom of David and Solomon, and it also provides the earliest date for the use of ashlar stones in Judah. Finally, the long life of the “governor’s residency” exemplifies a little addressed phenomenon—the old-house effect—in which buildings and settlements existed for a few centuries, but only left significant remains from their last phase. The earlier phases are hardly represented in the finds, barely studied, and rarely published. We suggest that the old-house effect influences archaeological interpretations world-wide, and is also responsible for recent attempts to down-date social complexity in Judah.

The following date list covers samples dated by the La Jolla (Mt Soledad) Radiocarbon Laboratory from January 1979 through August 1982. Most archaeologic, most geologic, and some geochemical samples measured during that period are included here. Results of 14C analyses of samples of tree rings, banded coral rings, and Antarctic seawater dissolved inorganic carbon measured during this period will be published elsewhere. Because of the cessation of all federal grant funding of this laboratory, this is the last date list to be published by it.

Pearl shell was an important and highly valued resource for producing tools and ornaments in Oceania. One pearl shell artifact type that is quite rare in Micronesia, however, is the crescent-shaped scraper/grater. These artifacts have recently been found in 2 burial caves in Palau, Western Caroline Islands, suggesting they may have played important social and symbolic roles in society. The first direct accelerator mass spectrometry (AMS) dating of this tool type, found in association with an in-situ female burial at the Chelechol ra Orrak site, provides a date of AD 150–270, while associated dates range from 770 BC–AD 180. These dates help contextualize human burials and associated artifacts from one of the earliest and most diverse burial sites in Austronesia.

Most of these analyses we obtained during 1966 withequipment and techniques previously employed.Methane from the higher numbered samples wasproduced in a bomb reactor at pressures up to 1000psi. Also, many smaller samples were counted in a700-ml vol counter at 2 atm pressure, which has abackground of 1.76 = .02 counts/min.

In this paper, a record of the 14C and 13C isotope content of atmospheric CO2 for Gliwice is presented for samples collected on a weekly basis in the years 2011–2013. In addition, measurements were performed on the early and late wood from the annual rings of pine trees from five sites located 3–6 km from the atmospheric CO2 sampling point. The concentration of 14C in CO2 samples from the air was much lower relative to the concentration of this isotope in “clean air,” indicating a pronounce Suess effect, with a mean Δ14C lower by ca. 60‰ than Jungfraujoch data when the 15% of the highest differences are excluded, which leads to the FFCO2 estimate of 5.8%. In winter, the main source of fossil CO2 was fuel combustion, as confirmed by significant correlations with air pollutants. In the vegetation seasons, the Δ14C was highly variable due to biogenic influence and more variable winds. The isotopic results were also affected by an additional significant CO2 source for the Gliwice air, which was a closed mine shaft. The Δ14C and δ13C in tree rings did not record a strong Suess effect in the years 2008–2013 in woodland areas around Gliwice city.

A new type of miniaturized, externally heated graphitization reaction furnace, the microconventional furnace (MCF), was constructed following our development of the laser heated furnace (LHF). The MCF is comprised of a gas reactor, a cold finger cooling system, and a compact resistive heater, which can raise the temperature of the hot finger to 850°C. The gas reactor is provided with three integrated valves to connect with the hydrogen/vacuum manifold, to isolate the reactor, and to connect with sample vessels. We made two types of MCF: the type 1 furnace (volume of 0.9 mL), with an integral stainless steel cold finger, and the type 2 furnace (volume from 1.3 to 10 mL), with a changeable glass cold finger. The MCF is designed for above atmospheric pressure (up to 2500 mbar) operation to decrease the overall graphitization time and improve the carbon yield. The MCF provides an effective solution for producing graphite from carbon dioxide (CO2) sample gas from 5 to 2000 µg of carbon with only 0.083 μg of 100 pMC extraneous carbon added. Cross-contamination tests show that the MCFs have no memory effect from previous samples.

We present here radiocarbon analyses made since our previous list (Srdoč et al. 1989). Sample pretreatment, combustion and counting techniques are essentially the same as described previously (Srdoč, Breyer & Sliepčević 1971), supplemented by new techniques for groundwater processing (Srdoč et al. 1979). The calculation of ages follows conventional protocol (Stuiver & Polach 1977). These ages can be converted from the 5570-year half-life to the chronometrically more correct half-life of 5730 years by multiplying by the factor, 1.029. Ages and standard deviations of all samples are adjusted for stable isotope fractionation according to the recommendations in Stuiver and Polach (1977), except for groundwater, calcareous deposits and aquatic plants. The δ13C values of the latter reflect the environmental conditions during their formation or growth rather than fractionation (Mook 1976; Krajcar Bronić et al. 1986; Marčenko et al. 1989). Thus, any percent modern (pMC) correction based on δ13C values is meaningless or even misleading. Sample descriptions are prepared in collaboration with collectors and submitters. Calibrated ages were calculated using the program of Stuiver and Reimer (1987).