Climate on Earth strongly depends on the radiative balance of its atmosphere, and thus, on the abundance of the radiatively active greenhouse gases. Largely due to human activities since the Industrial Revolution, the atmospheric burden of many greenhouse gases has increased dramatically. Direct measurements during the last decades and analysis of ancient air trapped in ice from polar regions allow the quantification of the change in these trace gas concentrations in the atmosphere. From a presumably “undisturbed” preindustrial situation several hundred years ago until today, the CO2 mixing ratio increased by almost 30% (Figure 1a) (Neftel et al. 1985; Conway et al. 1994; Etheridge et al. 1996). In the last decades this increase has been nearly exponential, leading to a global mean CO2 mixing ratio of almost 370 ppm at the turn of the millennium (Keeling and Whorf 1999).

Calibration is essential for interpretation of radiocarbon dates, especially when the 14C dates are compared to historical or climatic records with a different chronological basis. 14C ages of samples from the marine environment, such as shells or fish bones, or samples with a marine component, such as human bone in coastal regions, require an additional consideration because of the reservoir age of the ocean. While the pre-industrial global mean reservoir correction, R(t), is about 400 years, local variations (ΔR) can be several hundred years or more. ΔR compilations on a global scale have been undertaken previously (Stuiver et al. 1986; Stuiver and Braziunas 1993), but have not been updated recently. Here we describe an on-line reservoir correction database accessed via mapping software. Rather than publishing a static ΔR compilation, new data will be incorporated when it becomes available. The on-line marine reservoir correction database can be accessed at the website http://www.calib.org/.

As first shown by Bard et al. (1990a), high-precision 230Th-234U ages can be used successfully to calibrate the radiocarbon time scale beyond the high-precision tree-ring calibration that now reaches 11,900 cal bp (Kromer and Spurk 1998). Using mass spectrometric techniques, we measured 14C and 230Th ages on new samples collected from boreholes drilled off the islands of Tahiti and Mururoa (French Polynesia) in order to complement the database previously obtained on Barbados corals (Bard et al. 1990a, 1993).

Our experience in radiocarbon dating has shown that dates obtained from samples of corn cob and kernels are usually too young compared with dates from wood samples. Since other laboratories have also commented on the same problem, a study of C13/C12 ratios in corn and other plant materials has been undertaken.

We present results that validate a new wet oxidation, stepped-combustion procedure for dating “old” charcoal samples. An acid–base–wet oxidation (ABOX) pretreatment procedure has been developed that is used in place of the conventional acid-base-acid (ABA) pretreatment. Combustions and graphitizations are performed in a vacuum line that is insulated from the atmosphere by a second backing vacuum to eliminate the risk of atmospheric leakage into the line at any stage of the procedure. Combustions are performed at 3 temperatures (330 °, 630 ° and 850 °) with a graphite target produced from the CO2 evolved during each combustion step. In this way, the removal of any contamination can be monitored, and a high degree of confidence can be placed on the final age. The pretreatment, combustion, graphitization, and measurement blank for the procedure, based on the analysis of a “radiocarbon-dead” graphite, is 0.5 ± 0.5 μg C (1σ, n=14), equivalent to 0.04 ± 0.02 pMC or an “age” of approximately 60 ka for a 1 mg graphite target. Analyses of a “radiocarbon-dead” natural charcoal after ABOX pretreatment and stepped combustion suggest that the total blank (including contamination not removed by pretreatment) may be higher than for graphite, ranging up to 0.10 ± 0.02 pMC. Additional experiments confirm good agreement with accepted values for the international low-14C “New Kauri” standard (0.16–0.25 pMC). They also confirm excellent reproducibility, with 3 separate dates on different aliquots of a charcoal sample from Ngarrabullgan Cave (Queensland, Australia) ranging from 35.2 to 35.5 ka 14C BP. It is also demonstrated that the ABOX pretreatment, in conjunction with the new vacuum line described here, is able to remove contamination not removed by the conventional ABA pretreatment, suggesting that the technique can be used to produce reliable 14C dates on charcoal up to at least 50 ka.

We present two new high-resolution sediment records from the southwestern Iceland and Norwegian Seas that were dated by numerous 14C ages up to 54 14C ka bp. Based on various lines of evidence, the local 14C reservoir effect was restricted to 400–1600 yr. The planktic stable isotope records reveal several meltwater spikes that were sampled with an average time resolution of 50 yr in PS2644 and 130 yr in core 23071 during isotope stage 3. Most of the δ18O spikes correlate peak-by-peak to the stadials and cold rebounds of the Dansgaard-Oeschger cycles in the annual-layer counted GISP2 ice core, with the major spikes reflecting the Heinrich events 1–6. This correlation indicates large fluctuations in the calibration of 14C ages between 20 and 54 14C ka bp. Generally the results confirm the 14C age shifts as predicted by the geomagnetic model of Laj, Mazaud and Duplessy (1996). However, the amplitude and speed of the abrupt decrease and subsequent major increase of our 14C shifts after 45 14C ka bp clearly exceed the geomagnetic prediction near 40–43 and 32–34 calendar (cal) ka bp. At these times, the geomagnetic field intensity minima linked to the Laschamp and the Mono Lake excursions and confirmed by a local geomagnetic record, probably led to a sudden increase in cosmogenic 14C and 10Be production, giving rise to excess 14C in the atmosphere of up to 1200%.

Sixty years ago, the advent of radiocarbon dating rewrote archaeological chronologies around the world. Forty years ago, the advent of calibration signaled the death knell of the diffusionism that had been the mainstay of archaeological thought for a century. Since then, the revolution has continued, as the extent of calibration has been extended ever further back and as the range of material that can be dated has been expanded. Now a new revolution beckons, one that could allow archaeology to engage in historical debate and usher in an entirely new kind of (pre)history. This paper focuses on more than a decade of experience in utilizing Bayesian approaches routinely for the interpretation of 14C dates in English archaeology, discussing both the practicalities of implementing these methods and their potential for changing archaeological thinking.

We present routine methods of target preparation for radiocarbon analysis at the ANTARES Accelerator Mass Spectrometry (AMS) Centre, as well as recent developments which have decreased our procedural blank level and improved our ability to process small samples containing less than 200 μg of carbon. Routine methods of 14C sample preparation include sample pretreatment, CO2 extraction (combustion, hydrolysis and water stripping) and conversion to graphite (graphitization). A new method of cleaning glassware and reagents used in sample processing, by baking them under a stream of oxygen, is described. The results show significant improvements in our procedural blanks. In addition, a new graphitization system dedicated to small samples, using H2/Fe reduction of CO2, has been commissioned. The technical details of this system, the graphite yield and the level of fractionation of the targets are discussed.

The levels and sources of the measurement background in an AMS 14C dating system have been studied in detail. The relative contributions to the total background from combustion, graphitization, storage, handling, and from the accelerator were determined by measuring the C concentrations in samples of anthracite coal ranging in size from 15μg to 20mg. The results show that, for the present system, the uncertainty in the background is greater than that due to measurement precision alone for very old or for very small samples. While samples containing 100μg of carbon can yield useful 14C dates throughout the Holocene, 200 to 500μg are required for dating late Pleistocene materials. With the identification of the procedures that introduce contamination, the level and uncertainty of the total system background should both be reducible to the point that 100μg of carbon would be sufficient for dating most materials.

Precision and accuracy in accelerator mass spectrometry (AMS) dating relies on the systematic reduction of errors at all stages of the dating process, from sampling to AMS measurement. With new AMS systems providing much better precision and accuracy for the final stage of the process, we need to review the process as a whole to test the accuracy of reported results. A new High Voltage Engineering Europa (HVEE) AMS system was accepted at Oxford in September 2002. Since then, the system has been in routine use for AMS dating and here we report on our experiences during the first year. The AMS system itself is known to be capable of making measurements on single targets to a precision of better than 0.2% for the 14C/13C ratio and better than 0.1% for the 13C/12C ratio. In routine operation, we measure known-age wood to a precision of just above 0.3%, including uncertainties in background and pretreatment. At these levels, the scatter in results is no higher than reported errors, suggesting that uncertainties of ±25 to ±30 14C yr can be reliably reported on single target measurements. This provides a test of all parts of the process for a particular material in a particular state of preservation. More generally, sample pretreatment should remove as much contamination as feasible from the sample while adding as little laboratory contamination as possible. For more complex materials, such as bone, there is clearly more work needed to prove good reproducibility and insignificant offsets in all circumstances. Strategies for testing accuracy and precision on unknown material are discussed here, as well as the possibilities of one day reaching precisions equivalent to errors of <±20 14C yr.

The combined oak and pine tree-ring chronologies of Hohenheim University are the backbone of the Holocene radiocarbon calibration for central Europe. Here, we present the revised Holocene oak chronology (HOC) and the Preboreal pine chronology (PPC) with respect to revisions, critical links, and extensions. Since 1998, the HOC has been strengthened by new trees starting at 10,429 BP (8480 BC). Oaks affected by cockchafer have been identified and discarded from the chronology. The formerly floating PPC has been cross-matched dendrochronologically to the absolutely dated oak chronology, which revealed a difference of only 8 yr to the published 14C wiggle-match position used for IntCal98. The 2 parts of the PPC, which were linked tentatively at 11,250 BP, have been revised and strengthened by new trees, which enabled us to link both parts of the PPC dendrochronologically. Including the 8-yr shift of the oak-pine link, the older part of the PPC (pre-11,250 BP) needs to be shifted 70 yr to older ages with respect to the published data (Spurk 1998). The southern German part of the PPC now covers 2103 yr from 11,993–9891 BP (10,044–7942 BC). In addition, the PPC was extended significantly by new pine chronologies from other regions. A pine chronology from Avenches and Zürich, Switzerland, and another from the Younger Dryas forest of Cottbus, eastern Germany, could be crossdated and dendrochronologically matched to the PPC. The absolutely dated tree-ring chronology now extends back to 12,410 cal BP (10,461 BC). Therefore, the tree-ring-based 14C calibration now reaches back into the Central Younger Dryas. With respect to the Younger Dryas-Preboreal transition identified in the ring width of our pines at 11,590 BP, the absolute tree-ring chronology now covers the entire Holocene and 820 yr of the Younger Dryas.

The prototype mini carbon dating system (MICADAS) at ETH Zurich has been in routine operation for almost 2 yr. Because of its simple and compact layout, setting up a radiocarbon measurement is fast and the system runs very reliably over days or even weeks without retuning. The stability of the instrument is responsible for the good performance in highest-precision measurements where results of single samples can be reproduced within less than 2‰. The measurements are described and the performance of MICADAS is demonstrated on measured data.

As a follow-up to the meeting of experts convened at the International Atomic Energy Agency (IAEA) in February 1989, and the International 14C Workshop held in Glasgow in September 1989, the 14C Quality Assurance Program was formulated. In a joint effort of several radiocarbon teams and IAEA staff, we have prepared a set of five new intercomparison materials. These are natural materials frequently used by radiocarbon laboratories. The materials were distributed to 137 laboratories in May 1990. In February 1991, a meeting of experts was convened in Vienna to evaluate the results, to determine the radiocarbon activity of the five samples expressed in % Modern (pMC) terms and to define the 13C/12C ratio, and to make recommendations on further use of these materials. We present here the results of the exercise and the agreed consensus values for each of the five materials and discuss the different analyses that were undertaken.

We have developed a method of graphitization from CO2 samples for accurate 14C measurements by accelerator mass spectrometry. Our batch method, using a sealed Vycor tube, reduces the risk of contamination during graphitization and makes it possible to prepare many samples in a short time (typically 20 samples per day).

A calibration is presented for conventional radiocarbon ages ranging from 10 to 7240 years BP and thus covering a calendric range of 8000 years from 6050 BC to AD 1950. Distinctive features of this calibration include 1) an improved data set consisting of 1154 radiocarbon measurements on samples of known age, 2) an extended range over which radiocarbon ages may be calibrated (an additional 530 years), 3) separate 95% confidence intervals (in tabular from) for six different radiocarbon uncertainties (20, 50, 100, 150, 200, 300 years), and 4) an estimate of the non-Poisson errors related to radiocarbon determinations, including an estimate of the systematic errors between laboratories.

We present and discuss quasi-continuous long-term 14CO2 observations from the continental background station Schauinsland (48°N, 8°E, 1205 m asl, Black Forest, southern Germany). The observed steady decline of atmospheric 14CO2 from 1977 to 1996 can be described by a single exponential function with an e-folding time of (16.3 ± 0.2) yr. Summer means (May to August) in atmospheric 14CO2 at Schauinsland compare within Δ14C = ±4‰ with measurements made on individual rings from a tree grown in the near vicinity of the Schauinsland site. Both data sets are slightly depleted by up to 5‰ if compared to maritime background measurements of atmospheric 14CO2 made at Izaña, Tenerife. This is due to the influence of fossil fuel CO2 emissions over the European continent as well as generally in mid latitudes of the Northern Hemisphere. δ13C analyses from the Schauinsland samples show mean seasonal variations with an amplitude of ±0.4‰, caused by atmosphere-biosphere exchange, and a mean decrease from 1977 to 1996 of δ13C = −0.017‰ yr−1. This trend is mainly due to an increasing quantity of fossil fuel CO2 in the atmosphere, depleted in 13C/12C ratio, and compares well to trends measured at other stations in mid-to-high northern latitudes.

The application of AMS to the detection of 14C makes possible a new class of sensitive experiments in molecular biology. Such experiments inherently produce large numbers of samples for the determination of biological variability in molecular interactions. The samples vary in 14C concentration over many orders of magnitude. We added TiH2 to aid the reduction of CO2 by zinc in a sealed tube to reproducibly make graphite without sample cross-contamination. The CO2 is transferred from a combustion tube to the reaction tube through a disposable plastic manifold. The sealed tubes are heated to a single-reaction temperature in a muffle furnace. The process is complete within 5 h. Bulk isotopic fractionation in the finished graphite is less than 0.5%.

The radiocarbon ages of dendrochronologically-dated wood samples, each covering 10 years, are now available for the cal AD 1950–6000 BC age range. The decadal calibration curve constructed from these data comprises 1) the previously published AD 1950–2500 BC portion (Stuiver & Becker 1986), to which minor 14C age corrections were applied, and 2) the new 2500–6000 BC extension.

This paper is concerned with the expected deviations in the production rate of natural 14C on the earth due to changes in solar activity. We review the published estimates of the global production rates of 14C due to galactic and solar cosmic ray particles, and present new estimates of the expected secular variations in 14C production, taking into account the latest information available on galactic cosmic ray modulation and long-term variations in solar activity.

A long-term mountain station series of tropospheric 14C data for the period 1959 to 1984 is presented. This series is considered representative of the higher altitude14C level over central Europe. Even tree-ring 14C levels from a rural ground level site in southern Germany are consistently lower (by Δ14Cdepression = −15‰ if compared with the mountain station summer average in atmospheric CO2). The rural tree-ring series is considered to represent the additional continental Suess effect at ground level without local contamination. This Suess effect decreases gradually with the distance from the ground (ie, source) level. We therefore estimate the additional continental Suess effect in the vegetation period to be Δ14Cdepression = −5‰ for the mountain station and −20‰) for a rural ground level site, respectively. Based on this assumption, yearly mean tropospheric 14C levels corrected for fossil fuel contamination and representative of the Northern Hemisphere are provided for use in global carbon cycle models.