Adjuvants influence weed control and crop tolerance provided by postemergence (POST) herbicides. Adjuvant effects on weed control and corn and soybean tolerance with CGA-248757 and flumiclorac applied alone and soybean tolerance with CGA-248757 and flumiclorac applied in combination with imazethapyr or CGA-277476 were evaluated. Velvetleaf control in the greenhouse and common lambsquarters, redroot pigweed, and common ragweed control in the greenhouse and field with CGA-248757 and flumiclorac were increased by the addition of an adjuvant. However, corn and soybean tolerance to these herbicides was not affected by adding an adjuvant. Laboratory studies suggest enhanced weed control from the addition of an adjuvant resulted from an increase in CGA-248757 and flumiclorac foliar absorption. In greenhouse studies, velvetleaf, common lambsquarters, and redroot pigweed control with CGA-248757 plus imazethapyr; velvetleaf control with flumiclorac plus imazethapyr; redroot pigweed and common ragweed control with CGA-248757 plus CGA-277476; and velvetleaf, redroot pigweed, and common ragweed control with flumiclorac plus CGA-277476 increased by adding an organosilicone adjuvant when compared with adding a nonionic surfactant (NIS). However, in field evaluations of CGA-248757 or flumiclorac plus imazethapyr, the addition of NIS or an organosilicone adjuvant resulted in equivalent soybean injury, common lambsquarters and redroot pigweed control, and soybean yield. Yet in tank mixtures of CGA-248757 or flumiclorac plus CGA-277476, the addition of an organosilicone adjuvant increased redroot pigweed control and soybean yield compared to adding NIS.

The effect of DPX-79406 was evaluated on eight corn hybrids in 1993 and on 18 hybrids in 1994. Experiments were conducted each year at Charlottetown, Prince Edward Island, and Stewiacke, Nova Scotia. Corn tolerance was similiar between sites but varied from year to year with certain hybrids. Generally, tolerance was hybrid dependent. Most hybrids displayed chlorosis and stunting 7 days after treatment (DAT) but recovered quickly. Injury at 7 DAT ranged from 8 to 64%. Grain yield indicated that ‘Pickseed 2444,’ ‘Pioneer 3921,’ ‘Pioneer 3979,’ and ‘DK 302’ were tolerant to 25 g ai/ha of DPX-79406. Pioneer 3979 and Pickseed 2444 grain yields were reduced with DPX-79406 at 50 g/ha in 1 yr. ‘DK 291’ and ‘DK 235’ were severely injured both years and did not recover appreciably from early injury. Responses of ‘Pioneer 3984’ and ‘Pickseed 2477’ varied from year to year, and they were considered sensitive to DPX-79406. ‘Pioneer 3947,’ ‘Pioneer 3962,’ ‘Pickseed 2290,’ ‘Pickseed 2299,’ ‘DK 220,’ ‘G-4011,’ and ‘N0565’ were tested only 1 yr and were tolerant to both rates of DPX-79406.

Spurred anoda is an increasing weed problem in Colorado pinto bean production. This research was designed to evaluate reduced rates of bentazon and imazethapyr applied at various times for spurred anoda control and profitability. In 1993, spurred anoda control with early applications of either bentazon or imazethapyr was superior to late applications. Bentazon provided better spurred anoda control than imazethapyr in June. Spurred anoda control in 1993 was better than in 1994 due to late-emerging weeds and herbicide treatments not providing residual control. In 1994, bentazon controlled spurred anoda better than imazethapyr 1 and 3 wk after late POST, but no treatment provided commercially acceptable full-season control. The number of treatments with gross margins greater than the untreated check increased as pinto bean prices increased, but ranking of gross margin did not change due to pinto bean prices.

Wild carrot is becoming a serious weed problem in Michigan continuous no-tillage crop production. Greenhouse and field research was conducted to identify effective management strategies for wild carrot control in no-tillage cropping systems. In the greenhouse, PRE applications of acetochlor plus dichlormid (5.8:1 w:w), cyanazine, linuron plus chlorimuron (18:1), and metribuzin plus chlorimuron (10:1) and POST applications of bentazon, CGA-152005, clopyralid, cyanazine, and MON 12000 provided the greatest control of wild carrot seedlings. In the field, PRE and POST treatments containing chlorimuron consistently controlled overwintered wild carrot greater than 71% at 30 d after the POST application in no-tillage soybean. Atrazine, MON 12000, nicosulfuron, and primisulfuron applied POST consistently controlled overwintered wild carrot greater than 78% at 30 DAT in no-tillage corn. Glyphosate at 0.84 or 1.68 kg ae/ha applied in October to established wild carrot provided greater than 74% control the following spring. Early preplant (EPP) applications of glyphosate at 0.84 kg/ha in no-tillage soybean gave 95 and 24% control of overwintered wild carrot in St. Clair and Lenawee Counties, MI, respectively, at 70 DAT. PRE applications of glyphosate at 0.84 kg/ha controlled overwintered wild carrot less than 69% at 58 DAT in no-tillage corn and soybean. Fall applications of 2,4-D ester at 1.12 kg ae/ha provided 18 and 88% control of wild carrot the following spring in Clinton and Lenawee Counties, respectively. EPP applications of 2,4-D ester at 1.12 kg/ha provided 7 and 72% control of overwintered wild carrot in St. Clair and Lenawee Counties, respectively.

Field studies were conducted in 1995 and 1996 at three locations in Illinois to determine soybean response to combinations of thifensulfuron and bentazon. Thifensulfuron was applied at 2.2 to 8.8 g ai/ha alone or in combination with 280 to 560 g/ha of bentazon. Soybean injury 30 d after treatment ranged from 0 to 22% when thifensulfuron was applied alone at 2.2 g/ha. Increasing thifensulfuron rate to 8.8 g/ha increased soybean injury to a range of 12 to 44%. Soybean grain yield was significantly reduced compared to the yield of untreated soybean when thifensulfuron was applied at 4.4 and 8.8 g/ha in two of five and four of five experiments, respectively. The addition of bentazon to thifensulfuron consistently reduced soybean injury and stunting. In many cases, increasing the bentazon rate to 420 g/ha decreased soybean injury from thifensulfuron to a greater extent than 280 g/ha. In cases where thifensulfuron decreased soybean yield, the addition of 420 or 560 g/ha of bentazon restored yields to levels that were not lower than untreated soybeans. These studies demonstrate that thifensulfuron at 2.2 to 8.8 g/ha in combination with bentazon at 420 g/ha may be safely applied to soybean for broadleaf weed control.

Experiments were conducted to compare barnyardgrass control and rice injury and yield with emulsifiable concentrate and dry flowable formulations of propanil as single or repeat applications with crop oil concentrate, methylated seed oil, a blend of organosilicone surfactant and methylated seed oil or conventional nonionic surfactant, and organosilicone surfactant. Two applications of propanil were more effective in controlling barnyardgrass than a single application. The emulsifiable concentrate formulation of propanil controlled barnyardgrass more effectively than the dry flowable formulation in some but not all experiments. Differences in barnyardgrass control with propanil as influenced by adjuvants were minor and inconsistent. The most consistent barnyardgrass control and the highest rice yields were obtained with repeat applications of the emulsifiable concentrate formulation of propanil.

Greenhouse and field studies were conducted in 1991 and 1992 to determine the potential for interaction among pyridate (0.5, 1.0 kg ai/ha), sethoxydim (0.22 kg ai/ha), and crop oil concentrate (COC) (1.25% v/v) applied alone or in two- and three-way combinations to transplanted cabbage. Additionally, the effect of applying sethoxydim and COC 1 and 2 d before and after application of pyridate was investigated. In greenhouse-grown cabbage, injury increased twofold and dry weight was reduced 15% when pyridate dose was doubled. Sethoxydim increased pyridate injury significantly, reducing dry weight 31%. When COC was applied with pyridate, injury increased and dry weight decreased linearly. Despite substantial crop injury 7 d after treatment with pyridate alone, pyridate + sethoxydim, and pyridate + COC, yields of field-grown cabbage were reduced significantly in 1 yr only when the three materials were combined. Pyridate injury decreased as time between sethoxydim + COC applications, before and after pyridate was applied, increased.

Varying the type of nonionic surfactant greatly changed the biological activity of the ethyl ester of quizalofop-P on giant foxtail, barnyardgrass, and corn. These studies statistically evaluated 22 surfactants with widely different chemical, physical, and surface properties. Of the 14 surfactant properties analyzed, dynamic surface tension was the most important to enhance quizalofop-P activity. Alcohol ethoxylate surfactants like Genapol® 24-L-92 and Tergitol® 15-S-7 were among the most effective adjuvants. These surfactants performed significantly better than the commercial nonionic surfactant, Induce®, and equal to a high-quality petroleum crop oil concentrate, Agri-dex®. These surfactants offer a lower dose option to crop oil concentrates and a more effective surfactant alternative for mixtures that prohibit crop oil concentrates.

The effect of nonionic surfactant, crop oil concentrate, organosilicone surfactant, methylated seed oil, and a blend of organosilicone surfactant and methylated seed oil on absorption of 14C-clethodim was evaluated in barnyardgrass (Echinochloa crus-galli). Absorption of 14C-label was greatest during the first 40 min after application when 14C-clethodim was applied with methylated seed oil or a blend of methylated seed oil and organosilicone surfactant. These adjuvants increased the rate of absorption more than crop oil concentrate, organosilicone surfactant, or nonionic surfactant. Crop oil concentrate was more effective than organosilicone or nonionic surfactant in increasing absorption, with nonionic surfactant being more effective than organosilicone surfactant. These results generally agreed with the order of increasing efficacy of clethodim on barnyardgrass as affected by adjuvants in field experiments. Another study was conducted to determine the effect of bromoxynil on absorption and translocation of 14C-clethodim in yellow foxtail (Setaria glauca). Bromoxynil reduced absorption of 14C–clethodim 4, 8, and 24 h after application and also reduced the amount of 14C-label translocated from the treated leaf. These data suggest that antagonism of clethodim control of yellow foxtail by bromoxynil observed in previous research can be attributed partially to decreased absorption and translocation of clethodim.

Shattercane seeds were collected in 1992 from 16 fields in southeastern and south-central Nebraska that had been treated for 3 consecutive yr with primisulfuron or nicosulfuron. Approximately 11,200 plants, from a total of 16,000 seeds (1,000 per field) planted, were evaluated for primisulfuron resistance in greenhouse screening. A single resistant plant was found. No other primisulfuron resistance was found in evaluating an additional 1,718 plants from the remaining seeds collected in 1992 from the field where the original resistant plant was found. Shattercane seeds were collected in 1993 and 1994 from that field. All 17,038 plants from these collections were killed by primisulfuron. A field assessment of 118 descendents of the original resistant plant (S1 progeny) produced three responses to primisulfuron at an approximate 1:2:1 ratio: (1) death; (2) some interveinal chlorosis; or (3) no visible injury or symptoms. Discovery of this resistant shattercane biotype indicates the potential for selection of primisulfuron-resistant shattercane populations under field conditions.

Field experiments were conducted during 1996 and 1998 to determine the effect of atrazine, bentazon, atrazine + bentazon, the amine salt of 2,4-D, and bromoxynil on broadleaf signalgrass and barnyardgrass control when applied in mixture with sethoxydim. Herbicide combinations were applied with crop oil concentrate, crop oil concentrate + ammonium sulfate, or BCH 815. Bentazon and atrazine + bentazon reduced broadleaf signalgrass and barnyardgrass control by sethoxydim. Bromoxynil reduced barnyardgrass control but had no affect on broadleaf signalgrass control. Including ammonium sulfate with crop oil concentrate or substituting BCH 815 for crop oil concentrate increased barnyardgrass and broadleaf signalgrass control by sethoxydim when applied with bentazon. Ammonium sulfate and BCH 815 increased barnyardgrass control when sethoxydim was applied with bromoxynil but did not affect control when sethoxydim was applied with atrazine + bentazon. Atrazine and the ammonium salt of 2,4-D did not reduce barnyardgrass and broadleaf signalgrass control by sethoxydim regardless of adjuvant.

Rates and application timings of postemergence herbicides for wild oat control in spring wheat and barley were evaluated at Crookston, MN, from 1994 to 1996. Diclofop, imazamethabenz, and fenoxaprop plus MCPA plus thifensulfuron plus tribenuron were applied to one- to three-leaf wild oat; and difenzoquat, imazamethabenz, fenoxaprop plus MCPA plus thifensulfuron plus tribenuron, and fenoxaprop plus 2,4-D plus MCPA were applied to four- to five-leaf wild oat at 1/2 ×, 3/4 ×, and 1 × rates. Wild oat response to herbicide rate and timing was similar in wheat and barley. Wild oat control with 1/2 × rates generally was less than that with 3/4 × rates, which was lower than or similar to that with 1 × rates. Wild oat biomass was often reduced less with 1/2 × rates than 1 × rates. However, reducing herbicide rates generally did not influence grain yields or net economic return. Grain yields and net economic return were generally greater in herbicide-treated plots than in the nontreated control.

Optimal application timing for dicamba–acetamide tank mixes was examined in field studies conducted in Michigan and Wisconsin from 1993 to 1995. Dicamba was tank mixed with alachlor, metolachlor, or SAN 582H and applied at planting, 7 d after planting, and 14 d after planting. Additional dicamba plus alachlor tank mixes applied at all three timings were followed by nicosulfuron postemergence to determine the effects of noncontrolled grass weeds on corn yield. Delaying application of dicamba–acetamide tank mixes until 14 d after planting often resulted in lower and less consistent giant foxtail control compared with applications at planting or 7 d after planting. Corn grain yield was reduced at one site where giant foxtail control was lower when application was delayed until 14 d after planting. Common lambsquarters control was excellent with 7 or 14 d after planting applications. At one site, common lambsquarters control and corn yield was reduced by application at planting. Dicamba–alachlor tank mixes applied 7 d after planting provided similar weed control or corn yield, while at planting and 14 d after planting applications provided less consistent weed control or corn yield than a sequential alachlor plus dicamba treatment or an atrazine-based program.

Greenhouse and field studies were conducted to determine the interaction of clethodim sprayed in low volume with pyrithiobac or bromoxynil and to determine the influence of these mixtures on large crabgrass control. A low-volume, air-assisted spraying system was calibrated to deliver 26 L/ha and was compared to a conventional hydraulic fan spraying system calibrated to deliver 140 L/ha. Greenhouse data indicated that carrier volume had no effect on large crabgrass control with clethodim. The addition of pyrithiobac to clethodim in mixture was antagonistic compared to control with clethodim applied alone. The addition of bromoxynil to clethodim in mixture was synergistic. Field studies showed similar results.

The effect of adding a spray adjuvant to SAN 582H tank mixtures with fluazifop-P, imazethapyr, and sethoxydim was evaluated. SAN 582H synergistically increased broadleaf signalgrass control with reduced rates of all three postemergence (POST) herbicides when no spray adjuvant was used and when crop oil concentrate was added. For example, broadleaf signalgrass control increased from 50% to 83% when SAN 582H was tank-mixed with 52 g ai/ha sethoxydim and crop oil concentrate. In another experiment, several formulations of SAN 582H, including blank solvent-only formulations (no SAN 582H), were evaluated in combination with a reduced rate of sethoxydim to determine the source of synergism from tank mixtures. The SAN 582H molecule, not the carrier solvents in formulated product, was determined to be the source of synergism. The synergistic properties of SAN 582H were compared to other chloroacetamides. Synergism from acetochlor was similar to SAN 582H when applied POST with a reduced rate of either fluazifop-P, imazethapyr, or sethoxydim for grass control. Metolachlor also synergistically increased the control of grasses with the POST herbicides; however, metolachlor caused considerable phytotoxicity when applied alone and synergistic interactions were detected less frequently. The efficacy of sethoxydim mixed with SAN 582H was evaluated under different soil moisture conditions. Broadleaf signalgrass control increased from 81% to 93% under dry, moisture-stressed conditions when 210 g/ha sethoxydim was tank- mixed with SAN 582H.

Control of two perennial weeds, quackgrass and Canada thistle, and the differential sensitivities of three imidazolinone-resistant (IMI) corn hybrids and their sensitive isolines to various acetolactate synthase (ALS)-inhibiting herbicides were evaluated in greenhouse studies. The postemergence sulfonylurea herbicides nicosulfuron and primisulfuron controlled quackgrass > 80%. The imidazolinone herbicides imazapyr and imazamox applied postemergence controlled quackgrass 70 and 74%, respectively. Canada thistle control was 89% with the sulfonylurea herbicide metsulfuron. Primisulfuron, chlorsulfuron, and tribenuron controlled Canada thistle > 70%. The imidazolinonesensitive corn hybrids did not tolerate the imidazolinone herbicides imazethapyr, imazaquin, imazapyr, AC 263,222, and imazamox; the sulfonylurea herbicides chlorimuron, chlorsulfuron, metsulfuron, tribenuron, and triflusulfuron; and the pyrimidinylthiobenzoate herbicide pyrithiobac applied postemergence. The ‘Ciba 4393 IMR’ corn hybrid, homozygous for an unknown allele, was resistant to all of the various ALS-inhibiting herbicides that injured its sensitive isoline. The magnitude of resistance for this hybrid was greater than the other IR corn hybrids. The ‘Pioneer 3751 IR’ corn hybrid, homozygous for the XA-17 ALS allele, was also resistant to a number of ALS-inhibiting herbicides. The ‘ICI 8692 IT’ corn hybrid, heterozygous for the Mut2 allele, was only resistant to the imidazolinone herbicides.

Studies were conducted at Rosemount and Crookston, MN, in 1994 and 1995 to determine weed control efficacy and crop injury of F8426 (proposed common name carfentrazone-ethyl) in hard red spring wheat. F8426 alone and with 2,4-D or dicamba generally controlled common lambsquarters, kochia, and velvetleaf 90% or more at 0.026 and 0.035 kg/ha. F8426 alone and with 2,4-D or dicamba controlled Pennsylvania smartweed, wild buckwheat, and wild mustard 39 to 100% and was less consistent than control of the aforementioned species. Weed control varied little among the F8426 rates. Weed control was inconsistent between location, year, and species when F8426 was combined with crop oil concentrate, urea–ammonium nitrate solution, and nonionic surfactant. Control was more consistent when 0.28 kg/ha 2,4-D or 0.07 kg/ha dicamba was tank mixed with either F8426 rate. The best control with an F8426 treatment was similar to control from MCPA tank mixed with thifensulfuron plus tribenuron, bromoxynil, or dicamba. Weed control 30 and 45 days after treatment (DAT) was less for F8426-containing treatments than standard treatments, which likely was related to reduced crop competition after severe crop injury. Increasing F8426 rate from 0.026 to 0.035 kg/ha did not greatly increase wheat injury, whereas adding 0.28 kg/ha 2,4-D to either F8426 rate greatly increased crop injury. Wheat yield was reduced up to 63% by F8426 and 2,4-D combinations.

Kochia (Kochia scoparia) control dropped from about 90% to less than 20% after three consecutive annual applications of acetolactate synthase (ALS)-inhibiting herbicides in several northeastern South Dakota fields. Field experiments were conducted to evaluate control of kochia resistant to ALS-inhibiting herbicides using combinations of herbicides applied postemergence (POST) in wheat (Triticum aestivum) and using herbicides applied preemergence (PRE), POST, and PRE plus POST in soybean (Glycine max). Thifensulfuron plus tribenuron did not control kochia in wheat (> 600 kochia plants/m2 at harvest) and wheat yield was similar to yield of the untreated control. Dicamba plus 2,4-D (in 1996) and bromoxynil plus MCPA (in 1996 and 1997) controlled kochia and increased yields by 15% or more. Kochia was sparse (less than 1 plant/m2) in soybean plots, but grass weeds were prevalent. PRE plus POST or POST herbicide combinations that included ALS-inhibiting herbicides controlled grasses, and soybean yields were as much as 20% greater than yields with combinations that did not contain ALS-inhibiting herbicides. Adding ALS-inhibiting herbicides to wheat herbicide combinations decreased profitability because treatment costs increased while yields did not. In contrast, adding ALS-inhibiting herbicides to soybean treatments increased profitability due to better grass control, resulting in increased yield and better return.

Field studies were conducted in 1995 and 1996 to investigate postemergence tank mixtures of sethoxydim with various acetolactate synthase (ALS)- and non–ALS-inhibitor herbicides for weed control in sethoxydim-resistant (SR) corn. Giant foxtail control with sethoxydim was 96% and was equal to control with tank mixtures of sethoxydim plus bentazon, dicamba, dicamba plus atrazine, bromoxynil, and nicosulfuron plus bromoxynil. Giant foxtail control with sethoxydim plus atrazine, sethoxydim plus bentazon plus atrazine, and sethoxydim plus ALS-inhibiting herbicides plus 2,4-D was reduced to 60 to 89%. Common ragweed control was equal to or above 91% for tank mixtures that included bentazon plus atrazine, dicamba, dicamba plus atrazine, halosulfuron plus 2,4-D, and CGA 152005 plus primisulfuron plus 2,4-D, and the tank mixture of nicosulfuron plus bromoxynil. Common lambsquarters control was equal to or above 91% from all broadleaf herbicide treatments except bentazon and the tank mixture of halosulfuron plus 2,4-D. In these studies, only tank mixtures of sethoxydim plus dicamba or dicamba plus atrazine controlled giant foxtail, common ragweed, and common lambsquarters equal to or greater than 91% in SR corn.

Greenhouse and field research evaluated yellow nutsedge growth, vegetative control, and tuber production after application of glyphosate, various acetolactase synthase (ALS)–inhibiting herbicides, and tank mixtures thereof. Yellow nutsedge was controlled by the herbicides halosulfuron at 35 g ai/ha, chlorimuron at 12 g ai/ha, and imazethapyr–imazapyr at 62 g ai/ha (> 70% control); imazethapyr at 70 g ai/ha, glyphosate at 840 g ae/ha, cloransulam at 17.5 g ai/ha, and rimsulfuron at 17.5 g ai/ha (40 to 70% control); and imazamox at 45 g ai/ha (< 40% control). Compared with the untreated control, tuber fresh weight in the field was reduced 45 to 91%, and tuber density was reduced 33 to 90% by all herbicide treatments 42 wk after treatment (WAT) except imazamox and rimsulfuron. Tuber sprouting was reduced to 19% in plots treated with halosulfuron and pyrithiobac compared with untreated yellow nutsedge 42 WAT. Chlorimuron and imazethapyr–imazapyr controlled yellow nutsedge at least 90%, prevented panicle formation, and reduced tuber density and fresh weight by 90% or more 14 WAT in the greenhouse. The addition of glyphosate to cloransulam or imazethapyr increased yellow nutsedge control and reduced tuber density and fresh weight when compared with either ALS-inhibiting herbicide or glyphosate applied alone. Tuber density data indicated that there were 8 tubers for every gram of tubers harvested. Yellow nutsedge height was 15 to 20 cm 4 to 5 wk after tillage, using growth analysis data. Long-term yellow nutsedge management may be aided with treatments that reduce tuber production.