Wettability quantifies the affinity of a liquid over a substrate and determines whether the surface is repellent or not. When both the liquid and the solid phases are made of the same chemical substance and are at thermal equilibrium, complete wetting is expected in principle, as observed, for instance, with drops of molten metals spreading on their solid counterparts. However, this is not the case for water on ice. Although there is a growing consensus on the partial wetting of water on ice and several estimates available for the value of the associated macroscopic contact angle, the question of whether these values correspond to the contact angle at mechanical and thermal equilibrium is still open. In the present paper, we address this issue experimentally and demonstrate the existence of such a macroscopic contact angle of water on ice, from measurements and theoretical arguments. Indeed, when depositing water droplets on smooth polycrystalline ice layers with accurately controlled surface temperatures, we observe that spreading is unaffected by thermal effects and phase change close enough to the melting point (namely, for undercoolings below 1 K) so that conditions of thermal equilibrium are closely approached. Whereas the short time motion of the contact line is driven by an inertial-capillary balance, the evolution towards mechanical equilibrium is described by a viscous-capillary dynamics and is therefore capillary – and not thermally – related. Moreover, we show that the resulting contact angle remains constant for undercoolings below 1 K. In this way, we show the existence of a non-zero macroscopic contact angle of water on ice under conditions of mechanical and thermal equilibrium, which is very close to
$12^\circ$. We anticipate this key finding will significantly improve the understanding of capillary flows in the presence of phase change, which is of special interest in the realm of ice morphogenesis and glaciology, and will also be beneficial with the aim of developing numerical methods for resolving triple-line dynamics.