In Australia’s neoliberal context, volunteers play a crucial role in refugee settlement but face significant challenges despite their intercultural skills. Neoliberal outsourcing of social welfare work to volunteers and NGOs not only undermines the altruistic essence of volunteerism but also transforms it into a tool for cost-cutting and social service privatisation. The undervaluation of volunteers’ work, due to difficulties in measuring their skills within Australia’s labour framework, leads to their contributions being underappreciated. Moreover, resource constraints within the neoliberal environment hinder adequate support and professional development opportunities for volunteers. The outsourcing of volunteers by NGOs exacerbates power imbalances, as volunteers become dependent on NGOs, which exert significant control over their work. This dynamic embeds a power differential, where volunteers are beholden to the mechanisms of state and institutional power that control resources, messaging, and accountability. Tensions and ideological disparities also arise between paid employees and volunteers. Furthermore, the study underscores how NGOs’ accountability to donors may compromise their autonomy and mission, diverting attention from addressing the needs of marginalised communities. The process of responsibilisation imposed by NGOs, aligning with donors’ priorities, imposes stringent rules and accountability on volunteers, potentially undermining their voice and autonomy. However, while the study criticised certain aspects of neoliberalism, it also recognised its encouragement and valorization of volunteering. It emphasises the need to invest in volunteers through fair compensation, proper training, monitoring, and policies to prevent exploitation, recognising their vital role alongside professionals in refugee settlement.