Analysis of the chronological data and observation of a lagoonal sediment core reveal sand washover events between around 2.4 to 2.5 cal. ky BP in the Isumi River lowland. We conducted radiocarbon dating with AMS and constructed an age-depth model using the latest calibration curve and appropriate model routine. In the middle to lower part of the core, dark-gray sand layers are repeatedly deposited. Sand layers may exhibit an erosional surface at the base with fining upward grading. The overwash layers are composed of well-rounded sand with occasional gravel, indicative of transportation. overwash sediment characteristics are consistent with proximal marine deposits, suggesting an ocean origin (though riverine sediment is also similar in character). The age-depth model indicates very high sediment accumulation rates associated with overwash deposits. Based on the amount of accumulated sediment, relatively large-scale redeposition events occurred during this period but more information is needed to constrain the mechanism(s) causing the events. We also present a local reservoir age correction compatible with the Marine20 calibration curve.

The AMS Golden Valley laboratory is equipped with two accelerator mass spectrometers: the AMS facility from the Budker Institute of Nuclear Physics (BINP) and the Mini Carbon Dating System (MICADAS-28) from Ionplus AG and two graphitization systems: the Automated Graphitization Equipment (AGE-3) from Ionplus AG and the Absorption-catalytic setup (ACS) developed at the Boreskov Institute of Catalysis (BIC). The ACS was designed for graphite preparation from labeled biomedical samples, dissolved organics, and dissolved or gaseous carbon dioxide but has proven to be suitable for the traditional dating of objects no older than 35,000 years. Here we present two series of AMS data for the samples from Glasgow International Radiocarbon Inter-comparison (GIRI), prepared using AGE-3 and ACS, and then measured on MICADAS-28. The mean value of the background F14C was 0.0024 ± 0.0009 and 0.012 ± 0.003 for AGE-3 and ACS, respectively, and both methods gave reproducible results for the OXI.

Cellulose of tree rings is often assumed to be predominantly formed by direct assimilation of CO2 by photosynthesis and consequently can be used to reconstruct past atmospheric 14C concentrations at annual resolution. Yet little is known about the extent and the age of stored carbon from previous years used in addition to the direct assimilation in tree rings. Here, we studied 14C in earlywood and latewood cellulose of four different species (oak, pine, larch and spruce), which are commonly used for radiocarbon calibration and dating. These trees were still growing during the radiocarbon bomb peak period (1958–1972). We compared cellulose 14C measured in tree-ring subdivisions with the atmospheric 14C corresponding to the time of ring formation. We observed that cellulose 14C carried up to about 50% of the atmospheric 14C signal from the previous 1–2 years only in the earlywood of oak, whereas in conifers it was up to 20% in the earlywood and in the case of spruce also in the latewood. The bias in using the full ring of trees growing in a temperate oceanic climate to estimate atmospheric 14C concentration might be minimal considering that earlywood has a low mass contribution and that the variability in atmospheric 14C over a few years is usually less than 3‰.

Yakushima is a small, mountainous island off southern Kyushu, Japan. Its proximity to active volcanos and subduction zones leaves Yakushima vulnerable to large megathrust earthquakes and tsunamis, in addition to powerful typhoons and storm surges. These hazardous events deposit beach boulders: large rocks moved above sea-level by powerful waves. By radiocarbon dating the fossilized coral within these boulders, one can derive age estimates of the hazard events. Reliably estimating the magnitude and timing of geological events in the historical record is vital for future hazard prediction and mitigation. In this study, we estimated the deposition age of ten boulders on the north coast of Yakushima to infer potential paleo tsunamis and storm surges. We found that large wave events have occurred frequently throughout the Holocene. Based on the boulders’ ages, we identified four potential deposition events at 1986–2692 cal yr BP, 3522–4075 cal yr BP, 4773–5232 cal yr BP, and 6187–6638 cal yr BP. These deposits are likely a result of storm surges, or tsunamis from nearby volcanic activity or subduction earthquakes. Another set of boulders dated to 5125–5738 cal yr BP were likely exposed due to a decline in sea-level following the Holocene high sea-level stand. Further modelling could determine the wave height necessary to move the boulders and distinguish between storm and tsunami deposits. This is especially pertinent given the high frequency of coastal geohazards, and the likelihood of similar hazards impacting southeast Japan in the future.

The AMS Golden Valley radiocarbon analysis laboratory is equipped with two accelerator mass spectrometers: AMS facility from Budker Institute of Nuclear Physics (BINP AMS) and MIni CArbon DAting System (MICADAS-28) from Ionplus AG and two graphitization systems: Automated Graphitization Equipment (AGE-3) from Ionplus AG and Absorption-catalytic setup developed in Boreskov Institute of Catalysis (ACS BIC). The laboratory provides routine 14C analyses of various samples: collagen, cellulose, humic acids, carbonates from sediments, etc. The main focus of the laboratory is to determine the age of archaeological artifacts by radiocarbon dating. This work presents a comprehensive description of the BINP AMS facility, with its operation compared with that of MICADAS in the same laboratory. In 2022, the AMS Golden Valley laboratory participated for the first time in the Glasgow International Radiocarbon Inter-comparison (GIRI). The samples were graphitized on the AGE-3 and subsequently measured in both AMS facilities. A comparison of the results of the two series of experiments, namely AGE-3 + MICADAS-28 and AGE-3 + BINP AMS, is given.

A newly developed compact AMS, LEA (Low Energy Accelerator), is tested and compared with a state-of-the-art AMS system MICADAS (Mini Carbon Dating System), which has a precision performance of better than 1‰ for modern 14C. The main difference between these two systems is the acceleration voltage, which has been reduced from 200 kV with the MICADAS system to 50 kV with the LEA system. In order to execute the final performance tests, exactly same samples (2 sets consisting of 7 standards, 4 blanks, 26 wood samples) are measured on both systems successively. The results show that the LEA system is fully operational, and the performance is entirely comparable with that of the MICADAS system.

Single-year 14C sampling of a spruce log from the timber platform on which the Āraiši lake-fortress was built dates this timber exactly, by synchronization with AD 774/5 Miyake event. Dendrochronological synchronisms between the dated log and other timbers provide annual precision for the construction of the site. The felling date obtained, AD 835, is 50–60 years later than that proposed previously (Meadows and Zunde 2014) on the basis of a wiggle-match between 14C ages of decadal blocks and the IntCal13 calibration curve (Reimer et al. 2013), although the same 14C data favor a felling date in the AD 830s when wiggle-matched to IntCal20 (Reimer et al. 2020). Our results appear to confirm doubts expressed by Philippsen et al. (2022) about IntCal20 values from ca. AD 825-835.

Eight atmospheric carbon dioxide samples (as calcium carbonate—CaCO3—precipitates) from Lindesnes site (58ºN, 7ºE), belonging to 1963 and 1980 (four samples from each year) and stored at the National Laboratory for Age Determination (NTNU), have been reevaluated through radiocarbon (14C) analysis. Previous 14C results indicated the presence of a contaminant, which was not removed through different chemical cleansing procedures (e.g., hydrochloric acid—HCl and/or hydrogen peroxide—H2O2). Here, we present a follow up investigation using 14C step-combustion and Fourier-transform infrared spectroscopy (FTIR) analysis. Results from 14C data indicate unsuccessful removal of the contaminant, while further FTIR analysis displayed the presence of moisture. This finding alludes to the possibility that the contaminant is of ambient air-CO2 deeply embedded in CaCO3 powders (within clogged CaCO3 pores and/or bonded to the lattice). Samples were found exposed to air-CO2 and humidity. These conditions may have lasted for years, possibly even decades, leading to the 14C offsets detected here.

We present an alternative radiocarbon (14C) age-depth model using IntCal20 to calibrate new accelerator mass spectrometry (AMS) data applied to a Lake Baikal sediment core (VER99G12) in southern Siberia. 14C dating showed that the core extends to 31 ka. To take into account uncertainties in 14C age and sedimentation depth in the core, a new age-depth modeling routine, undatable, was used in this study. Undatable revealed that significant changes in sedimentation rate correspond to global climate events, either warm or cold, which periods are likely close to the timing of the occurrence of the Meltwater pulses (MWP) at 19 and 14 ka, and the Last glacial Maximum (LGM) at 21–20 ka. Since the Selenga River accounts for 50% of the total river inflow to Lake Baikal, we interpret that these changes in sedimentation rate could be signals of significant changes in Selenga River discharge to the lake, which is expected to be affected by global climate change. Based on pollen analysis, it is highly probable that the sudden influx of the Selenga River to Lake Baikal, particularly at 19 ka, was due to the thawing of permafrost water through the Selenga River, which had developed in the region. Total organic carbon content and mean grain size increases concurrent with sedimentation rate, suggesting river inflow increased available nutrients for biological activity. Our results indicate that hydrological changes corresponding to MWP events can be observed in continental areas of the Northern Hemisphere.

GIRI (Glasgow International Radiocarbon Intercomparison) was designed to meet a number of objectives, including to provide an independent assessment of the analytical quality of the laboratory/measurement and an opportunity for a laboratory to participate and improve (if needed). The principles in the design of GIRI were to provide the following: (a) a series of unrelated individual samples, spanning the dating age range, (b) linked samples to earlier intercomparisons to allow traceability, (c) known age samples, to allow independent accuracy checks, (d) a small number of duplicates, to allow independent estimation of laboratory uncertainty, and (e) two categories of samples—bulk and individual—to support laboratory investigation of variability. All of the GIRI samples are natural (wood, peat, and grain), some are known age, and overall their age spans approx. >40,000 years BP to modern. The complete list of sample materials includes humic acid, whalebone, grain, single ring dendro-dated samples, dendro-dated wood samples spanning a number of rings (e.g., 10 rings), background and near background samples of bone and wood. We present an overview of the results received and preliminary consensus values for the samples supporting a more in-depth evaluation of laboratory performance and variability.

At the Intertropical Convergence Zone (ITCZ), the northern and southern Tradewinds converge, and this region is characterized by low atmospheric pressure and high precipitation. The climate in the Timor Sea is characterized by seasonal precipitation changes driven by meridional migrations of the ITCZ and the monsoonal front. The ITCZ shifts in response to changes in the thermal balance between the northern and southern hemispheres. Thus, reconstruction of paleo-precipitation in the Timor Sea is expected to reveal past changes in both regional and global climate, the latter through inference of the ITCZ position. To reconstruct paleo-precipitation in the Timor Sea, we performed extensive radiocarbon analysis on both planktonic foraminifera and total organic carbon (TOC), which is derived from terrestrial and marine sources. Increased precipitation enhances the fraction of relatively old, terrestrial carbon to the core site, which in turn increases the difference between the ages of TOC and planktonic foraminifera. Variations in radiocarbon ages reveal that during northern hemisphere cooling intervals such as Heinrich Stadial 1 and the Younger Dryas, the ITCZ was in a southern position, thus increasing precipitation in the Timor Sea. However, the Timor Sea was dryer during the Bølling–Allerød warming as the ITCZ shifted northward.

Investigations of stable carbon isotope composition in α-cellulose extracted from tree rings of pines (Pinus sylvestris L.) growing in the unpolluted Suwałki region, northeastern part of Poland, are undertaken. The presented carbon isotope record covers the period of 1931–2003. Values of δ13C measured in the tree ring α-cellulose are compared to meteorological data. These δ13C values in tree ring cellulose respond to summer temperature, insolation, relative humidity, and precipitation. The best correlation is observed between relative humidity and carbon isotope data. The August relative humidity is found more influential on δ13C values than relative humidity for any other month or combination of months (r = –0.65). Relations between isotopic and meteorological data demonstrate that precipitation influences the stable carbon isotopic ratios to a lower extent than humidity. The intensity and duration of summer rainfall events can determine this effect. The temporal stability of climate-proxy connections is an important issue in paleoclimatic reconstruction. Therefore, the temporal stability of climatic signals recorded by stable carbon isotopes is analyzed in this research using the moving correlation function for moving intervals with a 25-year window. Based on those investigations the highest time stability of correlation was found for the carbon isotope and the August relative humidity. More variability is observed for the correlation of δ13C values with precipitation.

A new vacuum line to extract CO2 from carbonate and dissolved inorganic carbon (DIC) in water was established at Guangxi Normal University. The vacuum line consisted of two main components: a CO2 bubble circulation region and a CO2 purification collection region, both of which were made of quartz glass and metal pipelines. To validate its reliability, a series of carbonate samples were prepared using this system. The total recovery rate of CO2 extraction and graphitization exceeded 80%. Furthermore, the carbon content in calcium carbonate exhibited a linear relationship with the CO2 pressure within the system, demonstrating its stability and reliability. The system was also employed to prepare and analyze various samples, including calcium carbonate blanks, foraminiferal, shell, groundwater, and subsurface oil-water samples. The accelerator mass spectrometry (AMS) results indicated that the average beam current for 12C- in the samples exceeded 40 μA. Additionally, the contamination introduced during the liquid sample preparation process was approximately (1.77 ± 0.57) × 10−14. Overall, the graphitized preparation system for carbonate and DIC in water exhibited high efficiency and recovery, meeting the requirements for samples dating back to approximately 30,000 years.

The article presents results of measurements of radiocarbon (14C) concentration in sub-annual dendrochronologically dated tree rings of English oak (Quercus robur L.) from Grabie village near Kraków (southern Poland). Samples of early wood (EW) and late wood (LW) spanning the years 664–658 BCE. α-cellulose was extracted from each sample and their radiocarbon content was measured at the ATOMKI laboratory in Debrecen, Hungary. The EW and LW data confirm a prolonged increase in Δ14C values around 665–663 as was observed by Park et al. (2017), Rakowski et al. (2019), or Sakurai et al. (2020). In addition, we found that this event may consist of two relatively small events, as was proposed by Sakurai et al. (2020). Based on obtained in this and previous study data we estimate that the occurrence of the two events were between 665 and 664 BCE (Rakowski et al. 2019), and in late spring of 663 BCE (May–June, before beginning of LW formation).

As a required sample preparation method for 14C graphite, the Zn-Fe reduction method has been widely used in various laboratories. However, there is still insufficient research to improve the efficiency of graphite synthesis, reduce modern carbon contamination, and test other condition methodologies at Guangxi Normal University (GXNU). In this work, the experimental parameters, such as the reduction temperature, reaction time, reagent dose, Fe powder pretreatment, and other factors, in the Zn-Fe flame sealing reduction method for 14C graphite samples were explored and determined. The background induced by the sample preparation process was (2.06 ± 0.55) × 10–15, while the 12C– beam current were better than 40μA. The results provide essential instructions for preparing 14C graphite of ∼1 mg at the GXNU lab and technical support for the development of 14C dating and tracing, contributing to biology and environmental science.

A single-stage accelerator mass spectrometer (GXNU-AMS) developed for radiocarbon and tritium measurements was installed and commissioned at Guangxi Normal University in 2017. After several years of operational and methodological upgrades, its performance has been continuously improved and applied in multidisciplinary fields. Currently, the measurement sensitivity for radiocarbon and tritium is 14C/12C ∼ (3.14 ± 0.05) ×10–15 and 3H/1H ∼ (1.23 ± 0.17)×10–16, respectively, and the measurement accuracy is ∼0.6%, which can meet the measurement requirements in the nuclear, earth, environmental and life science fields. This study presents the performance characteristics of GXNU-AMS and several interesting application studies.

We have conducted radiocarbon (14C) dating of Japanese tree rings from 1053 to 921 BCE and 41 BCE to 130 CE. Dating was also performed using oxygen isotope dendrochronology to investigate subtle structures of the calibration curve corresponding to the beginning and the end of the Yayoi period in Japan. These two results followed IntCal20, which included the 14C ages of two Japan-sourced trees. The findings suggest that dating of specimens obtained from areas around the Japanese archipelago may be affected by periodic monsoons from the ocean, an effect that needs further examination.

A low-cost and computer-controlled graphitization system connected to an elemental analyzer (EA) has been designed and built at the NTUAMS Lab. This semiautomatic system equips 6-unit reactors for the graphitization of CO2 with H2 on the iron catalyst. The entire procedure takes about 7 hours for iron conditioning, sample combustion and loading, and graphitization. The system can produce good-quality graphite for samples containing 0.5–1.6 mg carbon mass, with the pressure yield of graphitization ranging from 57.7% to 87.1%. The average values of OXI and OXII agree well with the consensus value, but the result of ANU sucrose was observed to be slightly higher than the reported one. The background samples of anthracite over ten months yielded an average of 0.38±0.10 pMC (n=21) corresponding to a 14C age of 45 kyr BP. Intercomparison samples L and M of FIRI exhibit that the measured 14C ages are almost identical to the consensus values and have a small spread in these values. The system has been carrying out graphitization for total organic carbon (TOC) of peat samples, and providing a more efficient and convenient way for AMS 14C dating.

Short-term fluctuations in atmospheric radiocarbon (14C) concentration mark the tree-ring record for the last ∼15 kyr. Terrestrial macrofossils from sediment cores of Lake Suigetsu, Japan, extend this record of fluctuations back to >35 cal ka BP. Their significance, however, is under debate since the signal-to-noise ratio of the Suigetsu record is low and progressively decreases with increasing age. Coherent semi-millennial-scale structures of the Suigetsu 14C record have nevertheless been identified by three different techniques, namely visual inspection, analyses of the first derivative of 14C vs. calendar age, and Bayesian spline inflections of 14C concentration vs. calendar age, and hence appear objectively real. These 14C fluctuations correlate closely with those of the tree-ring-based 14C master record ∼10–14 cal ka. Thus, Suigetsu fine structures attain global significance and may properly reflect atmospheric 14C variability back to ∼35 cal ka. Carbonate-based 14C records from speleothems and ocean sediments are far smoother and form, together with Suigetsu and other data, the backbone of the IntCal20 record >14 cal ka that largely lacks the Suigetsu fine structure. 14C decay reduces 14C-signal amplitudes over time, so Holocene-style 14C signals of solar modulation disappear in the noise beyond ∼10 cal ka. The remaining older 14C fine structures had larger forcings, most likely linked to climate and carbon cycle, especially ocean-atmosphere CO2 exchange, and thus contain valuable information about these factors. They may also provide global stratigraphic tie points to correlate 14C records of oceanic plankton sediments and climate signals independent of problems with local 14C reservoir effects.

The Second International Mortar Dating Intercomparison Study (MODIS2) took place in 2020. Three mortar samples from different sites and chronologies were distributed among various research groups in form of bulk mortar and grain fraction smaller than 150 µm. This is the first time the Zagreb Radiocarbon Laboratory, with support of the Center of Applied Isotope Studies, University of Georgia, took part in the international mortar intercomparison. The initial approach of the Laboratory to mortar dating was to separate 32–63 µm grain fraction and collect three CO2 gas portions by sequential dissolution with acid. After checking the 14C date trends of the gas portions, which should be ascending with later fractions, the one for the first and shortest gas portion was reported as the age of the mortar. However, the first gas portion might not be true age of the mortar, since it still might contain some “dead” carbon. Therefore, data extrapolation from the first two initial CO2 portions was also conducted on the results, but not reported to the intercomparison. Though in general, all the intercomparison reported dates fit the expected historical ages, for one sample, the extrapolated result showed a better match to the historical data.