The desorption of bubbles during solidification of a melt occurs in processes as
diverse as the making of ice cubes, the formation of igneous rocks and the casting of
metals. In both the metal casting and rock formation processes, careful observation of
the final solid suggests that the desorbed bubbles often form regular spatial patterns.
Understanding and quantifying the mechanisms by which such patterns arise is
important. In the geological context, comparison between field measurements and the
predictions of a model will allow geologists to estimate in-situ magma properties. In
the metal casting context, engineers would like to be able to specify mould geometries
and cooling conditions to ensure that the distribution of bubbles will not compromise
the strength of critical sections of the casting.
In the present study, we develop a detailed mathematical model to predict the
distribution of desorbed bubbles in a solidified melt. Our new model builds upon
previous knowledge on this phenomenon in the geological context (Toramaru et al.
1996, 1997). We describe desorption of a dissolved gas in a semi-infinite melt, solidified
by a one-dimensional heat flux. In the absence of convection, the transfer of heat and
solute occurs mainly by a diffusive mechanism and the crystallization proceeds most
rapidly near the cooled boundary. The crystals formed contain almost no dissolved
gas and hence the concentration of gas dissolved in the melt increases progressively
towards the cooled boundary. Diffusion of dissolved gas from the crystallizing zone is
slow and, as a result, the local melt becomes supersaturated and gas bubbles desorb.
The full equations for this coupled solidification and desorption processes are solved
numerically.
We find that bubbles desorb forming a sequence of layers parallel to the cooled
boundary. The spacing between these bubble layers increases geometrically from
the cooled boundary. We give a physical interpretation for this geometric pattern
and analyse the effect of physical parameters on the layer spacing. We show that
our theoretical model captures the important physical mechanisms involved in the
solidification and desorption processes by comparing its predictions with available
measurements from a geological formation.