The Taylor–Melcher leaky dielectric (LD) model is often used to study the physics of electrosprays operating in the cone-jet mode. Despite its success, there are electrospraying conditions in which the ion concentration fields must be retained, which requires an electrokinetic model. This article reproduces cone-jets with two electrokinetic formulations: the standard Poisson–Nernst–Planck (PNP) equations, and a modified electrokinetic (MEK) model that accounts for overscreening and overcrowding of electrolytes, which is important in fluids with high electrical conductivities such as ionic liquids (Kilic et al. 2007 Phys. Rev. E vol. 75, no. 2, 021502, 021503; Bazant et al. 2011 Phys. Rev. Lett. vol. 106, no. 4, 46102). In the case of liquids with low electrical conductivities, it is observed that the LD and PNP models agree under certain limiting conditions, but they are less restrictive than previously proposed (Baygents & Saville 1990 AIP Conf. Proc. vol. 197, 7–17; Schnitzer & Yariv 2015 Fluid Mech. vol. 773, 1–33); the effects of dissimilar ion diffusivities are also investigated. In the case of liquids with high electrical conductivities, in particular ionic liquids, overscreening and overcrowding effects are important, resulting in significant differences between the solutions of the PNP, MEK and LD models. In particular, the electrokinetic models yield increased dissipation and self-heating, leading to higher temperature variations and currents, in agreement with measurements. Furthermore, the MEK formulation describes the ion concentration fields with higher fidelity than the PNP equations.